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Article Navigation >  Green Energy&Environment  > 2022  >  7(6): 1253-1262
Jiexin Zhang, YangYang Lai, Peng Li, Yanxia Wang, Faping Zhong, Xiangming Feng, Weihua Chen, Jianjun Liu, Xinping Ai, Hanxi Yang, Yuliang Cao. Boosting rate and cycling performance of K-doped Na3V2(PO4)2F3 cathode for high-energy-density sodium-ion batteries. Green Energy&Environment, 2022, 7(6): 1253-1262. doi: 10.1016/j.gee.2021.01.001
Citation: Jiexin Zhang, YangYang Lai, Peng Li, Yanxia Wang, Faping Zhong, Xiangming Feng, Weihua Chen, Jianjun Liu, Xinping Ai, Hanxi Yang, Yuliang Cao. Boosting rate and cycling performance of K-doped Na3V2(PO4)2F3 cathode for high-energy-density sodium-ion batteries. Green Energy&Environment, 2022, 7(6): 1253-1262. doi: 10.1016/j.gee.2021.01.001
shu

Boosting rate and cycling performance of K-doped Na3V2(PO4)2F3 cathode for high-energy-density sodium-ion batteries

doi: 10.1016/j.gee.2021.01.001

  • a. Engineering Research Center of Organosilicon Compounds & Materials of Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, China;

  • b. National Engineering Research Center of Advanced Energy Storage Materials, Hunan, 410205, China;

  • c. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001, China;

  • d. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai, 200050, China

Funds:

This research was financially funded by the Regional Innovation and Development Joint Fund, National Natural Science Foundation of China (No. U20A20249) and National Key Research Program of China (No. 2016YFB0901500). The numerical calculations in this paper have been done on the supercomputing system in the Supercomputing Center of Wuhan University.

  • Received date 20 October 2020, Accepted date 06 January 2021, RevRecd date 31 December 2020, Publish date 31 December 2022,
    Abstract
  • As a promising cathode material, Na3V2(PO4)2F3 (NVPF) has attracted wide attention for sodium-ion batteries (SIBs) because of its high operating voltage and high structural stability. However, the low intrinsic electronic conductivity and insufficient Na ion mobility of NVPF limit its development. Herein, K-doping NVPF is prepared through a facile ball-milling combined calcination method. The effects of K-doping on the crystal structure, kinetic properties and electrochemical performance are investigated. The results demonstrate that the Na2.90K0.10V2(PO4)3F3 (K0.10-NVPF) exhibits a high capacity (120.8 mAh g-1 at 0.1 C), high rate capability (66 mAh g-1 at 30 C) and excellent cycling performance (a capacity retention of 97.5% at 1 C over 500 cycles). Also, the occupation site of K ions in the lattice, electronic band structure and Na-ion transport kinetic property in K-doped NVPF are investigated by density functional theory (DFT) calculations, which reveals that the K-doped NVPF exhibits improved electronic and ionic conductivities, and located K+ ions in the lattice to contribute to high reversible capacity, rate capability and cycling stability. Therefore, the K-doped NVPF serves as a promising cathode material for high-energy and high-power SIBs.

     

    • Jieixn Zhang and Yangyang Lai are the co-authors of this article.
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