Volume 7 Issue 5
Oct.  2022
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Jiaqi Wu, Lei Zhang, Jinxing Long, Qiang Zeng, Biaolin Yin, Xuehui Li. Synthesis and fluorescent properties of quinoxaline derived ionic liquids. Green Energy&Environment, 2022, 7(5): 996-1005. doi: 10.1016/j.gee.2020.12.018
Citation: Jiaqi Wu, Lei Zhang, Jinxing Long, Qiang Zeng, Biaolin Yin, Xuehui Li. Synthesis and fluorescent properties of quinoxaline derived ionic liquids. Green Energy&Environment, 2022, 7(5): 996-1005. doi: 10.1016/j.gee.2020.12.018
shu

Synthesis and fluorescent properties of quinoxaline derived ionic liquids

doi: 10.1016/j.gee.2020.12.018

  • School of Chemistry and Chemical Engineering, Guangdong Provincial Key Lab of Green Chemical Product Technology, State Key Laboratory of Pulp & Paper Engineering, South China University of Technology, Guangzhou, 510640, China

Funds:

The authors gratefully acknowledge the financial support of the Natural Science Foundation of Guangdong Province (Grant No. 2020A0505100008) and the Science and Technology Program of Guangzhou, China (202206010024).

  • Received date 29 September 2020, Accepted date 22 December 2020, RevRecd date 03 December 2020, Publish date 24 December 2020,
    Abstract
  • Ionic liquids (ILs) have attracted increasing attention since last few decades due to their high molecular design abilities and wide applications in different fields. In this study, four novel fluorescent isoquinolino [2,1-a]quinoxalin-5-ium ILs were designed and synthesized via a two-step process including a simple dual Schiff's base formation and a subsequent [RhCp*Cl2]2-catalyzed oxidative C–H activation/annulation reaction. The as-synthesized ILs were extensively characterized using FT-IR, 1H-NMR, 13C-NMR, 19F-NMR, HSQC-NMR, HMBC-NMR and HR-MS. Their photophysical properties were determined by steady-state fluorescence spectroscopy. The results demonstrate that all these ILs showed dual or triple emissions, large stokes shift (90 nm) and mechanochromic behaviors. Basing on solvatochromism and titration experiments, it is thought that the emission bands of the ILs are raised from their local excited states, charge transfer states or excited state proton transfer of cations, while the substitute effect of these quinoxaline derived ILs on their stokes shifts is negligible.

     

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