Volume 6 Issue 4
Aug.  2021
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Article Navigation >  Green Energy&Environment  > 2021  >  6(4): 567-577
Shuai Shao, Ying Yang, Shangwei Guo, Shijie Hao, Feng Yang, Suoying Zhang, Yang Ren, Yangchuan Ke. Highly active and stable Co nanoparticles embedded in nitrogen-doped mesoporous carbon nanofibers for aqueous-phase levulinic acid hydrogenation. Green Energy&Environment, 2021, 6(4): 567-577. doi: 10.1016/j.gee.2020.11.005
Citation: Shuai Shao, Ying Yang, Shangwei Guo, Shijie Hao, Feng Yang, Suoying Zhang, Yang Ren, Yangchuan Ke. Highly active and stable Co nanoparticles embedded in nitrogen-doped mesoporous carbon nanofibers for aqueous-phase levulinic acid hydrogenation. Green Energy&Environment, 2021, 6(4): 567-577. doi: 10.1016/j.gee.2020.11.005
shu

Highly active and stable Co nanoparticles embedded in nitrogen-doped mesoporous carbon nanofibers for aqueous-phase levulinic acid hydrogenation

doi: 10.1016/j.gee.2020.11.005

  • a State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Changping, Beijing, 102249, China;

  • b X-Ray Science Division, Argonne National Laboratory, 9700 S. Cass Ave., Argonne, Illinois, 60439, USA

Funds:

This work was financially supported by the National Key Research and Development Program of China (2018YFB1105100), the National Natural Science Foundation of China (51974339 and 51674270), and the funding from Science Foundation of China University of Petroleum, Beijing (24620188JC005). Use of the Advanced Photon Source, an Office of Science User Facility operated for the U.S. Department of Energy (DOE) Office of Science by Argonne National Laboratory, supported by the U.S. DOE under Contract No. DE-AC02-06CH11357, is also acknowledged.

  • Received date 03 July 2020, Accepted date 12 November 2020, RevRecd date 28 September 2020, Publish date 31 August 2021,
    Abstract

  • Developing a highly active and durable non-noble metal catalyst for aqueous-phase levulinic acid (LA) hydrogenation to γ-valerolactone (GVL) is an appealing yet challenging task. Herein, we report well-dispersed Co nanoparticles (NPs) embedded in nitrogen-doped mesoporous carbon nanofibers as an efficient catalyst for aqueous-phase LA hydrogenation to GVL. The Co zeolitic imidazolate framework (ZIF-67) nanocrystals were anchored on the sodium dodecyl sulfate modified wipe fiber (WF-S), yielding one-dimensional (1-D) structured composite (ZIF-67/WF-S). Subsequently, Co NPs were uniformly embedded in nitrogen-doped mesoporous carbon nanofibers (CoRNC/SMCNF) through a pyrolysis-reduction strategy using ZIF-67/WF-S as the precursor. Benefiting from introducing modified wipe fiber WF-S to enhance the dispersion of Co NPs, and Co0 with Co-Nx dual active sites, the resulting CoRNC/SMCNF catalyst shows brilliant catalytic activity (206 h-1 turnover frequency). Additionally, the strong metal–support interactions greatly inhibited the Co NPs from aggregation and leaching from the mesoporous carbon nanofibers, and thus increasing the reusability of the CoRNC/SMCNF catalyst (reusable nine times without notable activity loss).

     

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