Volume 7 Issue 3
Jun.  2022
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Article Navigation >  Green Energy&Environment  > 2022  >  7(3): 519-524
Yan-Bing Li, Hui-Ying Guo, Chen-Qiang Deng, Jin Deng. Synthesis of dihydrocapsaicin and dihydrocapsiate exclusively from lignocellulosic platform chemicals. Green Energy&Environment, 2022, 7(3): 519-524. doi: 10.1016/j.gee.2020.11.001
Citation: Yan-Bing Li, Hui-Ying Guo, Chen-Qiang Deng, Jin Deng. Synthesis of dihydrocapsaicin and dihydrocapsiate exclusively from lignocellulosic platform chemicals. Green Energy&Environment, 2022, 7(3): 519-524. doi: 10.1016/j.gee.2020.11.001
shu

Synthesis of dihydrocapsaicin and dihydrocapsiate exclusively from lignocellulosic platform chemicals

doi: 10.1016/j.gee.2020.11.001

  • a Hefei National Laboratory for Physical Sciences at the Microscale, IChem, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, China;

  • b CAS Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou, Guangdong, 510640, China

Funds:

This work was supported by the National Natural Science Foundation of China (21875239) and the Fundamental Research Funds for the Central Universities (WK3530000004). The authors thank the Hefei Leaf Biotech Co., Ltd and Anhui Kemi Machinery Technology Co., Ltd for free samples and equipment that benefited our ability to conduct this study.

  • Received date 08 July 2020, Accepted date 05 November 2020, RevRecd date 25 September 2020, Publish date 11 November 2020,
    Abstract
  • Biorefinery is pivotal to the sustainability of modern chemical industry. However, since biomass is oxygen-enriched, new and green chemical strategies are required for expanding the biomass derived chemical space. In this work, synthesis of natural products dihydrocapsaicin and dihydrocapsiate was achieved exclusively from lignocellulosic platform chemicals. Natural products dihydrocapsaicin and dihydrocapsiate were synthesized exclusively from lignocellulosic platform chemicals, using furfural (from hemicellulose) and methyl isopropyl ketone (from cellulose) through aldol condensation-hydrolysis-hydrodeoxygenation to synthesize 8-methylnonanoic acid and then combined with vanillin derivates (from lignin). This synthesis demonstrates the feasibility of constructing natural products entirely from renewable biomass platform through green processes. The utilization of inherent functional groups of biomass demonstrates their potential to open up chemical space.

     

    • These authors contributed equally to this work.
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