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Article Navigation >  Green Energy&Environment  > 2020  >  5(4): 405-413
Hao Pang, Guoju Yang, Lin Li, Jihong Yu. Efficient transesterification over two-dimensional zeolites for sustainable biodiesel production. Green Energy&Environment, 2020, 5(4): 405-413. doi: 10.1016/j.gee.2020.10.024
Citation: Hao Pang, Guoju Yang, Lin Li, Jihong Yu. Efficient transesterification over two-dimensional zeolites for sustainable biodiesel production. Green Energy&Environment, 2020, 5(4): 405-413. doi: 10.1016/j.gee.2020.10.024
shu

Efficient transesterification over two-dimensional zeolites for sustainable biodiesel production

doi: 10.1016/j.gee.2020.10.024
  • a.

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, China

  • b.

    International Center of Future Science, Jilin University, 2699 Qianjin Street, Changchun 130012, China

  • c.

    Electron Microscopy Center, Jilin University, 2699 Qianjin Street, Changchun 130012, China

More Information
  • Corresponding author: E-mail address: yanggj@jlu.edu.cn (Guoju Yang); E-mail address: jihong@jlu.edu.cn (Jihong Yu)
  • Received date 28 July 2020, Accepted date 28 October 2020, RevRecd date 07 October 2020, Available online 29 October 2020, Publish date 31 October 2020,
    Abstract
  • Basic zeolites have shown great potential as efficient catalysts for biodiesel production in the transesterification reactions. However, conventional three-dimensional (3D) basic zeolites generally suffer from limited base sites and severe mass-transfer restriction, thereby suppressing their catalytic activity. Herein, 2D basic zeolites with large external surface areas, hierarchical characteristics, and abundant accessible and stable base sites are prepared by expansion, delamination and subsequent solid-state ion-exchange (SSIE) approach. The facile SSIE method provides more advantages in stabilizing and dispersing high concentration of strong basic sites than the conventional liquid-phase ion-exchange (LIE) approach. Due to the excellent mass transportation and stable basic sites, the 2D Na/ITQ-2 prepared by the SSIE approach shows remarkably enhanced activity and recyclability in the transesterification of triglycerides to produce biodiesel, compared to 3D zeolites and other reported basic zeolites. This work will open the boulevard to the rational design of 2D basic catalysts and expand the potential application of 2D zeolites to biodiesel production and other industrial reactions involving bulky molecules.

     

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    • References(45)
  • [1]
    R. Luque, J.C. Lovett, B. Datta, J. Clancy, J.M. Campelo, A.A. Romero, Energy Environ. Sci. 3 (2010) 1706-1721.
    [2]
    L. Lin, C. Zhou, V. Saritporn, X. Shen, M. Dong, Appl. Energy 88 (2011) 1020-1031.
    [3]
    F. Su, Y.H. Guo, Green Chem.. 16 (2014) 2934-2957.
    [4]
    J.A. Melero, J. Iglesias, G. Morales, Green Chem.. 11 (2009) 1285-1308.
    [5]
    A.F. Lee, J.A. Bennett, J.C. Manayil, K. Wilson, Chem. Soc. Rev. 43 (2014) 7887-7916.
    [6]
    M. Fan, H. Wu, M. Shi, P. Zhang, P. Jiang, Green Energy Environ. 4 (2019) 322-327.
    [7]
    Z.I. Ishak, N.A. Sairi, Y. Alias, M.K.T. Aroua, R. Yusoff, Catal. Rev. 59 (2017) 44-93.
    [8]
    A. Gog, M. Roman, M. Tosa, C. Paizs, F.D. Irimie, Renew. Energy 39 (2012) 10-16.
    [9]
    Z. Amini, Z. Ilham, H.C. Ong, H. Mazaheri, W.-H. Chen, Energy Convers. Manag. 141 (2017) 339-353.
    [10]
    A. Demirbas, Energy Convers. Manag. 50 (2009) 14-34.
    [11]
    Z. Helwani, M.R. Othman, N. Aziz, J. Kim, W.J.N. Fernando, Appl. Catal., A 363 (2009) 1-10.
    [12]
    H. Hattori, Chem. Rev. 95 (1995) 537-558.
    [13]
    L.-B. Sun, X.-Q. Liu, H.-C. Zhou, Chem. Soc. Rev. 44 (2015) 5092-5147.
    [14]
    Y. Li, J. Yu, Chem. Rev. 114 (2014) 7268-7316.
    [15]
    Z. Wang, J. Yu, R. Xu, Chem. Soc. Rev. 41 (2012) 1729-1741.
    [16]
    N. Wang, Q. Sun, J. Yu, Adv. Mater. 31 (2019) 1803966.
    [17]
    G. Yang, S.A. Akhade, X. Chen, Y. Liu, M.-S. Lee, V.-A. Glezakou, R. Rousseau, J.A. Lercher, Angew. Chem. Int. Ed. 58 (2019) 3527-3532.
    [18]
    T. Ennaert, J. Van Aelst, J. Dijkmans, R. De Clercq, W. Schutyser, M. Dusselier, D. Verboekend, B.F. Sels, Chem. Soc. Rev. 45 (2016) 584-611.
    [19]
    P.A. Jacobs, M. Dusselier, B.F. Sels, Angew. Chem. Int. Ed. 53 (2014) 8621-8626.
    [20]
    P. Sudarsanam, E. Peeters, E.V. Makshina, V.I. Parvulescu, B.F. Sels, Chem. Soc. Rev. 48 (2019) 2366-2421.
    [21]
    Y. Wang, H. Chou, B. Chen, D. Lee, Bioresour. Technol. 145 (2013) 248-253.
    [22]
    Y. Wang, T. Dang, B. Chen, D. Lee, Ind. Eng. Chem. Res. 51 (2012) 9959-9965.
    [23]
    G.J. Suppes, M.A. Dasari, E.J. Doskocil, P.J. Mankidy, M.J. Goff, Appl. Catal., A 257 (2004) 213-223.
    [24]
    Z. Li, S. Ding, C. Chen, S. Qu, L. Du, J. Lu, J. Ding, Energy Convers. Manage. 192 (2019) 335-345.
    [25]
    L. Du, S. Ding, Z. Li, E. Lv, J. Lu, J. Ding, Energy Convers. Manage. 173 (2018) 728-734.
    [26]
    Y. Wang, B. Chen, Catal. Today 278 (2016) 335-343.
    [27]
    I. Lawan, Z.N. Garba, W. Zhou, M. Zhang, Z. Yuan, Renew. Energy 145 (2020) 2550-2560.
    [28]
    J. Prech, P. Pizarro, D.P. Serrano, J. Cejka, Chem. Soc. Rev. 47 (2018) 8263-8306.
    [29]
    D. Kerstens, B. Smeyers, J. Van Waeyenberg, Q. Zhang, J. Yu, B.F. Sels, Adv. Mater. (2020) https://doi.org/10.1002/adma.202004690.
    [30]
    P. Peng, Z.-F. Yan, S. Mintova, X.-H. Gao, Natl. Sci. Rev. (2020) https://doi.org/10.1093/nsr/nwaa1184.
    [31]
    A. Corma, V. Fornes, S.B. Pergher, T.L.M. Maesen, J.G. Buglass, Nature 396 (1998) 353.
    [32]
    W.J. Roth, P. Nachtigall, R.E. Morris, J. Cejka, Chem. Rev. 114 (2014) 4807-4837.
    [33]
    A. Corma, U. Diaz, M.E. Domine, V. Fornes, J. Am. Chem. Soc. 122 (2000) 2804-2809.
    [34]
    A. Macario, G. Giordano, B. Onida, D. Cocina, A. Tagarelli, A.M. Giuffre, Appl. Catal., A 378 (2010) 160-168.
    [35]
    C. Jia, P. Beaunier, P. Massiani, Microporous Mesoporous Mater. 24 (1998) 69-82.
    [36]
    H.G. Karge, H.K. Beyer, Stud. Surf. Sci. Catal. 69 (1991) 43-64.
    [37]
    M.K. De Pietre, F.A. Bonk, C. Rettori, F.A. Garcia, H.O. Pastore, Microporous Mesoporous Mater.. 145 (2011) 108-117.
    [38]
    M.D. Oleksiak, K. Muraoka, M.-F. Hsieh, M.T. Conato, A. Shimojima, T. Okubo, W. Chaikittisilp, J.D. Rimer, Angew. Chem. Int. Ed. 56 (2017) 13366-13371.
    [39]
    R.A. Beyerlein, C. Choi-Feng, J.B. Hall, B.J. Huggins, G.J. Ray, Top. Catal. 4 (1997) 27-42.
    [40]
    S. Rakmae, C. Keawkumay, N. Osakoo, K.D. Montalbo, R.L. De Leon, P. Kidkhunthod, N. Chanlek, F. Roessner, S. Prayoonpokarach, J. Wittayakun, Fuel 184 (2016) 512-517.
    [41]
    M. Afzal, P.K. Butt, H. Ahmad, J. Therm. Anal. 37 (1991) 1015-1023.
    [42]
    G. Yang, J. Han, Z. Qiu, X. Chen, Z. Feng, J. Yu, Inorg. Chem. Front. 7 (2020) 1975-1980.
    [43]
    R. Oord, I.C. Ten Have, J.M. Arends, F.C. Hendriks, J. Schmidt, I. Lezcano-Gonzalez, B.M. Weckhuysen, Catal Sci Technol 7 (2017) 3851-3862.
    [44]
    Z. Zhao, R. Yu, C. Shi, H. Gies, F.-S. Xiao, D. De Vos, T. Yokoi, X. Bao, U. Kolb, R. Mcguire, A.-N. Parvulescu, S. Maurer, U. Muller, W. Zhang, Catal Sci Technol 9 (2019) 241-251.
    [45]
    O. Klepel, B. Hunger, J. Therm. Anal. Calorim. 80 (2005) 201-206.
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