Volume 7 Issue 3
Jun.  2022
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Article Navigation >  Green Energy&Environment  > 2022  >  7(3): 512-518
Zhuizhui Su, Bingxing Zhang, Xiuyan Cheng, Fanyu Zhang, Qiang Wan, Lifei Liu, Xiuniang Tan, Dongxing Tan, Lirong Zheng, Jianling Zhang. Ultra-small UiO-66-NH2 nanoparticles immobilized on g-C3N4 nanosheets for enhanced catalytic activity. Green Energy&Environment, 2022, 7(3): 512-518. doi: 10.1016/j.gee.2020.10.023
Citation: Zhuizhui Su, Bingxing Zhang, Xiuyan Cheng, Fanyu Zhang, Qiang Wan, Lifei Liu, Xiuniang Tan, Dongxing Tan, Lirong Zheng, Jianling Zhang. Ultra-small UiO-66-NH2 nanoparticles immobilized on g-C3N4 nanosheets for enhanced catalytic activity. Green Energy&Environment, 2022, 7(3): 512-518. doi: 10.1016/j.gee.2020.10.023
shu

Ultra-small UiO-66-NH2 nanoparticles immobilized on g-C3N4 nanosheets for enhanced catalytic activity

doi: 10.1016/j.gee.2020.10.023

  • a Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China;

  • b School of Chemical Sciences, University of Chinese Academy of Sciences, Physical Science Laboratory, Huairou National Comprehensive, Science Center, Beijing, 100190, China;

  • c Beijing Synchrotron Radiation Facility (BSRF), Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049, China

Funds:

The authors thank the financial supports from National Natural Science Foundation of China (21525316, 21673254), Ministry of Science and Technology of China (2017YFA0403003), Chinese Academy of Sciences (QYZDY-SSW-SLH013) and Beijing Municipal Science &

Technology Commission (Z191100007219009).

  • Received date 07 August 2020, Accepted date 26 October 2020, RevRecd date 22 September 2020, Publish date 03 November 2020,
    Abstract
  • UiO-66-NH2, an important metal-organic framework, is usually synthesized by solvothermal method and the particle size is generally larger than 200 nm, which limits its catalytic applications in chemical reactions. It is very meaningful to produce UiO-66-NH2 nanoparticles with ultra-small size, but remains challenging. Herein, we synthesized UiO-66-NH2 nanoparticles in size of 8-15 nm that are immobilized on g-C3N4 nanosheets. Compared with the UiO-66-NH2 synthesized by the traditional solvothermal method (> 200 nm), the ultra-small UiO-66-NH2 nanoparticles immobilized on g-C3N4 have more unsaturated coordination positions and increased Lewis acidity. Owing to these combined advantages, the ultra-small UiO-66-NH2 nanoparticles exhibit greatly improved catalytic activity for Meerwein-Ponndorf-Verley reaction than larger UiO-66-NH2 particles.

     

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