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Article Navigation >  Green Energy&Environment  > 2020  >  5(4): 433-443
Dong Lin, Xiuhui Zheng, Xiang Feng, Nan Sheng, Zhaoning Song, Yibin Liu, Xiaobo Chen, Zhenping Cai, De Chen, Chaohe Yang. Enhancing the dynamic electron transfer of Au species on wormhole-like TS-1 for boosting propene epoxidation performance with H2 and O2. Green Energy&Environment, 2020, 5(4): 433-443. doi: 10.1016/j.gee.2020.10.021
Citation: Dong Lin, Xiuhui Zheng, Xiang Feng, Nan Sheng, Zhaoning Song, Yibin Liu, Xiaobo Chen, Zhenping Cai, De Chen, Chaohe Yang. Enhancing the dynamic electron transfer of Au species on wormhole-like TS-1 for boosting propene epoxidation performance with H2 and O2. Green Energy&Environment, 2020, 5(4): 433-443. doi: 10.1016/j.gee.2020.10.021
shu

Enhancing the dynamic electron transfer of Au species on wormhole-like TS-1 for boosting propene epoxidation performance with H2 and O2

doi: 10.1016/j.gee.2020.10.021
  • a.

    State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao, 266580, China

  • b.

    Department of Chemical Engineering, Norwegian University of Science and Technology, Trondheim, 7491, Norway

More Information
  • Corresponding author: E-mail address: xiangfeng@upc.edu.cn (Xiang Feng); E-mail address: zhenping.cai@ntnu.no (Zhenping Cai)
  • Received date 06 July 2020, Accepted date 20 October 2020, RevRecd date 16 October 2020, Available online 21 October 2020, Publish date 31 October 2020,
    Abstract
  • Engineering unique electronic structure of catalyst to boost catalytic performance is of prime scientific and industrial importance. Herein, the identification of intrinsic electronic sensitivity for direct propene epoxidation was first achieved over highly stable Au/wormhole-like TS-1 catalyst. Results show that the electron transfer of Au species can be regulated by manipulating the dynamic evolutions and contents of Au valence states, thus resulting in different catalytic performance in 100 h time-on-stream. By DFT calculations, kinetic analysis and multi-characterizations, it is found that the Au0 species with higher electronic population can easily transfer more electrons to activate surface O2 compared with Au1+ and Au3+ species. Moreover, there is a positive correlation between Au0 content and activity. Based on this correlation, a facile strategy is further proposed to boost Au0 percentage, resulting in the reported highest PO formation rate without adding promoters. This work harbors tremendous guiding significance to the design of highly efficient Au/Ti-containing catalyst for propene epoxidation with H2 and O2.

     

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