Volume 7 Issue 3
Jun.  2022
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Article Navigation >  Green Energy&Environment  > 2022  >  7(3): 485-491
Xiao Yu, Xinyi Zhang, Yongjian Lai, Donghai Wang, Yong Liu. In-situ growth of TiO2 film on carbonized eggshell membrane as 3D electrode for high-performance lithium storage. Green Energy&Environment, 2022, 7(3): 485-491. doi: 10.1016/j.gee.2020.10.018
Citation: Xiao Yu, Xinyi Zhang, Yongjian Lai, Donghai Wang, Yong Liu. In-situ growth of TiO2 film on carbonized eggshell membrane as 3D electrode for high-performance lithium storage. Green Energy&Environment, 2022, 7(3): 485-491. doi: 10.1016/j.gee.2020.10.018
shu

In-situ growth of TiO2 film on carbonized eggshell membrane as 3D electrode for high-performance lithium storage

doi: 10.1016/j.gee.2020.10.018

  • a School of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275, China;

  • b School of Electronics and Information Technology, Sun Yat-sen University, Guangzhou, 510275, China

Funds:

The financial support from National Natural Science Foundation of China (No. 51772337), Fund for Fostering Talents in State Key Laboratory of Optoelectronic Materials and Technologies of China (No. OEMT-2017-ZY-09) and Fundamental Research Funds for the Central Universities in China (No. 19lgpy03) is greatly acknowledged.

  • Received date 12 June 2020, Accepted date 14 October 2020, RevRecd date 19 August 2020, Publish date 20 October 2020,
    Abstract
  • 3D electrodes have shown extraordinary promise for electrochemical energy storage devices in wearable electronics. However, it is still a significant challenge to rationally design 3D electrode that has the characteristics of lightweight, flexibility, low cost, high performance and miniaturization. In this work, we present a novel design of 3D electrode by directly growing the nanocrystalline TiO2 film on carbonized eggshell membrane. The unique architecture can supply not only a continuous electron transport pathway through an interconnected carbon fibrous network but also an efficient electrolyte flux via an interpenetrating porous network. Besides, nanocrystalline TiO2 film on carbonized eggshell membrane offers a short ion diffusion path in the solid-phase, leading to a rapid kinetic of electrochemical reaction. When tested as an anode for Li-ion battery, TiO2 film in 3D electrode demonstrated excellent electrochemical performance with a large reversible capacity, excellent rate capacity and long life cycling property.

     

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