Volume 7 Issue 3
Jun.  2022
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Article Navigation >  Green Energy&Environment  > 2022  >  7(3): 477-484
Ruhui Shi, Haiyang Cheng, Hongxiang Li, Peixuan Wu, Chao Zhang, Masahiko Arai, Fengyu Zhao. Cyclic oligourea synthesized from CO2: Purification, characterization and properties. Green Energy&Environment, 2022, 7(3): 477-484. doi: 10.1016/j.gee.2020.10.016
Citation: Ruhui Shi, Haiyang Cheng, Hongxiang Li, Peixuan Wu, Chao Zhang, Masahiko Arai, Fengyu Zhao. Cyclic oligourea synthesized from CO2: Purification, characterization and properties. Green Energy&Environment, 2022, 7(3): 477-484. doi: 10.1016/j.gee.2020.10.016
shu

Cyclic oligourea synthesized from CO2: Purification, characterization and properties

doi: 10.1016/j.gee.2020.10.016

  • a State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, No. 5625 Renmin Rd., Changchun, 130022, China;

  • b University of Science and Technology of China, No. 96 Jinzhai Rd., Hefei, 230026, China;

  • c Jilin Province Key Laboratory of Green Chemistry and Process, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, No. 5625 Renmin Rd., Changchun, 130022, China;

  • d State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, No. 5625 Renmin Rd., Changchun, 130022, China

Funds:

We acknowledge the financial support from the National Key Research and Development Program of China (2016YFA0602900), the National Natural Science Foundation of China (NSFC 21672204), the Youth Innovation Promotion Association CAS (2016206), and the Chinese Academy of Sciences President’s International Fellowship Initiative (2018VCA0012).

  • Received date 03 August 2020, Accepted date 13 October 2020, RevRecd date 12 October 2020, Publish date 17 October 2020,
    Abstract
  • Carbon dioxide (CO2) as a sustainable resource instead of toxic reagents has attracted considerable attention in synthesis of chemicals and polymeric materials. Herein, a kind of cyclic oligourea was synthesized via polycondensation of CO2 with 4,7,10-trioxa-1,13-tridecanediamine (TTD) followed by effective separation and purification processes. We developed an efficient separation strategy in which the linear oligourea molecules were selectively transformed to macromolecular polyurea molecules by a reaction of the -NH2 end group with 4,4′-diphenylmethane diisocyanate (MDI), followed by separation from cyclic oligourea using selected solvents. The structure and physicochemical properties were confirmed by MALDI-TOF mass spectra, NMR, Cryo-EM, thermal analysis and solubility measurement. The well-defined cyclic oligourea was produced with a high purity (99.4%) and the average-number molecular weight (Mn) of 1040 Da. It is semi-crystalline in structure with a melting point of 106 °C and glass transition point of −10 °C. The cyclic oligourea presented characteristically difference to its linear analogue. This work provides a new member to cyclic polymer family.

     

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