Volume 7 Issue 2
Apr.  2022
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Article Navigation >  Green Energy&Environment  > 2022  >  7(2): 345-351
Shu Shi, Yu-Xia Li, Shuai-Shuai Li, Xiao-Qin Liu, Lin-Bing Sun. Fabrication of Cu+ sites in confined spaces for adsorptive desulfurization by series connection double-solvent strategy. Green Energy&Environment, 2022, 7(2): 345-351. doi: 10.1016/j.gee.2020.10.009
Citation: Shu Shi, Yu-Xia Li, Shuai-Shuai Li, Xiao-Qin Liu, Lin-Bing Sun. Fabrication of Cu+ sites in confined spaces for adsorptive desulfurization by series connection double-solvent strategy. Green Energy&Environment, 2022, 7(2): 345-351. doi: 10.1016/j.gee.2020.10.009
shu

Fabrication of Cu+ sites in confined spaces for adsorptive desulfurization by series connection double-solvent strategy

doi: 10.1016/j.gee.2020.10.009

  • State Key Laboratory of Materials-Oriented Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), College of Chemical Engineering, Nanjing Tech University, 30 South Puzhu Road, Nanjing 211816, China

Funds:

This work was supported by the National Natural Science Foundation of China (21722606, 21676138, 21576137, and 21878149), the China Postdoctoral Science Foundation (51201370), and the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions.

  • Received date 18 June 2020, Accepted date 10 October 2020, RevRecd date 08 September 2020, Publish date 14 October 2020,
    Abstract
  • Cu+-containing materials have shown various application prospects especially in adsorption and catalysis, because they are versatile, non-toxic and low cost. To date, developing a mild and controllable approach for the fabrication of Cu+ sites has remained a pronounced challenge. Herein, we report a series connection double-solvent strategy (SCDS) for fabricating Cu+ sites within MIL-101(Cr), a typical metal–organic framework. By employing the SCDS in which vitamin C is chosen as the environmentally benign reducing agent, Cu2+ was incorporated in the pores and then transformed to Cu+ in the confined spaces. Compared to the conventional high-temperature autoreduction method conducted under harsh environment (700 ℃ for 12 h) with a low Cu+ yield (less than 50%), SCDS can selectively reduce Cu2+ to Cu+ at room temperature without generating any Cu0. The resulting Cu+ modified MIL-101(Cr) exhibits good desulfurization performance in view of both uptake and recyclability.

     

    • These authors contribute equally to this work.
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