Volume 7 Issue 2
Apr.  2022
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Article Navigation >  Green Energy&Environment  > 2022  >  7(2): 266-274
Haifeng Yu, Shouliang Wang, Yanjie Hu, Guanjie He, Le Quoc Bao, Ivan P. Parkin, Hao Jiang. Lithium-conductive LiNbO3 coated high-voltage LiNi0.5Co0.2Mn0.3O2 cathode with enhanced rate and cyclability. Green Energy&Environment, 2022, 7(2): 266-274. doi: 10.1016/j.gee.2020.09.011
Citation: Haifeng Yu, Shouliang Wang, Yanjie Hu, Guanjie He, Le Quoc Bao, Ivan P. Parkin, Hao Jiang. Lithium-conductive LiNbO3 coated high-voltage LiNi0.5Co0.2Mn0.3O2 cathode with enhanced rate and cyclability. Green Energy&Environment, 2022, 7(2): 266-274. doi: 10.1016/j.gee.2020.09.011
shu

Lithium-conductive LiNbO3 coated high-voltage LiNi0.5Co0.2Mn0.3O2 cathode with enhanced rate and cyclability

doi: 10.1016/j.gee.2020.09.011

  • a Key Laboratory for Ultrafine Materials of Ministry of Education, Shanghai Engineering Research Center of Hierarchical Nanomaterials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China;

  • b Christopher Ingold Laboratory, Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, UK;

  • c Faculty of Applied Sciences, Ton Duc Thang University, 19 Nguyen Huu Tho, District 7, Ho Chi Minh City, Viet Nam

Funds:

This work was supported by the National Natural Science Foundation of China (21975074, 91534202, and 91834301), the Shanghai Scientific and Technological Innovation Project (18JC1410500), and the Fundamental Research Funds for the Central Universities (222201718002).

  • Received date 09 July 2020, Accepted date 20 September 2020, RevRecd date 19 August 2020, Publish date 23 September 2020,
    Abstract
  • LiNi0.5Co0.2Mn0.3O2 (NCM523) cathode materials can operate at extremely high voltages and have exceptional energy density. However, their use is limited by inherent structure instability during charge/discharge and exceptionally oxidizing Ni4+ at the surface. Herein, we have developed a citrate-assisted deposition concept to achieve a uniform lithium-conductive LiNbO3 coating layer on the NCM523 surface that avoids self-nucleation of Nb-contained compounds in solution reaction. The electrode–electrolyte interface is therefore stabilized by physically blocking the detrimental parasitic reactions and Ni4+ dissolution whilst still maintaining high Li+ conductivity. Consequently, the modified NCM523 exhibits an encouraging Li-storage specific capacity of 207.4 mAh g-1 at 0.2 C and 128.9 mAh g-1 at 10 C over the range 3.0–4.5 V. Additionally, a 92% capacity retention was obtained after 100 cycles at 1 C, much higher than that of the pristine NCM523 (73%). This surface engineering strategy can be extended to modify other Ni-rich cathode materials with durable electrochemical performances.

     

    • These authors contributed equally to this work.
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