Volume 5 Issue 4
. 
Turn off MathJax
Article Contents
Article Navigation >  Green Energy&Environment  > 2020  >  5(4): 414-422
Peng Zhou, Feng Cheng, Gang Nie, Yangyang Yang, Kunsheng Hu, Xiaoguang Duan, Yongli Zhang, Shaobin Wang. Boron carbide boosted Fenton-like oxidation: A novel Fe(III)/Fe(II) circulation. Green Energy&Environment, 2020, 5(4): 414-422. doi: 10.1016/j.gee.2020.09.007
Citation: Peng Zhou, Feng Cheng, Gang Nie, Yangyang Yang, Kunsheng Hu, Xiaoguang Duan, Yongli Zhang, Shaobin Wang. Boron carbide boosted Fenton-like oxidation: A novel Fe(III)/Fe(II) circulation. Green Energy&Environment, 2020, 5(4): 414-422. doi: 10.1016/j.gee.2020.09.007
shu

Boron carbide boosted Fenton-like oxidation: A novel Fe(III)/Fe(II) circulation

doi: 10.1016/j.gee.2020.09.007
  • a.

    College of Architecture & Environment, Sichuan University, Chengdu, 610065, China

  • b.

    School of Chemical Engineering and Advanced Materials, The University of Adelaide, Adelaide, SA, 5005, Australia

More Information
  • Corresponding author: E-mail address: xiaoguang.duan@adelaide.edu.au (Xiaoguang Duan); E-mail address: shaobin.wang@adelaide.edu.au (Shaobin Wang)
  • Received date 13 July 2020, Accepted date 20 September 2020, RevRecd date 22 August 2020, Available online 23 September 2020, Publish date 31 October 2020,
    Abstract
  • The sluggish kinetics of Fe(Ⅱ) recovery in Fenton/Fenton-like reactions significantly limits the oxidation efficiency. In this study, we for the first time use boron carbide (BC) as a green and stable promotor to enhance the reaction of Fe(Ⅲ)/H2O2 for degradation of diverse organic pollutants. Electron paramagnetic resonance analysis and chemical quenching/capturing experiments demonstrate that hydroxyl radicals (•OH) are the primary reactive species in the BC/Fe(Ⅲ)/H2O2 system. In situ electrochemical analysis indicates that BC remarkably boosts the Fe(Ⅲ)/Fe(Ⅱ) redox cycles, where the adsorbed Fe(Ⅲ) cations were transformed to more active Fe(Ⅲ) species with a higher oxidative potential to react with H2O2 to produce Fe(Ⅱ). Thus, the recovery of Fe(Ⅱ) from Fe(Ⅲ) is facilitated over BC surface, which enhances •OH generation via Fenton reactions. Moreover, BC exhibits outstanding reusability and stability in successive cycles and avoids the secondary pollution caused by conventional organic and metalliferous promotors. Therefore, metal-free BC boosting Fe(Ⅲ)/H2O2 oxidation of organics provides a green and advanced strategy for water decontamination.

     

    • FullText(HTML)
  • loading
    • References(50)
  • [1]
    Y. Zhu, R. Zhu, Y. Xi, J. Zhu, G. Zhu, H. He, Appl. Catal. B: Environ. 255 (2019) 117739.
    [2]
    Y. Zhang, M.H. Zhou, J. Hazard. Mater. 362 (2019) 436-450.
    [3]
    G.V. Buxton, C.L. Greenstock, W.P. Helman, A.B. Ross, J. Phys. Chem. Ref. Data 17 (1988) 513-886.
    [4]
    A.V. Vorontsov, J. Hazard. Mater. 372 (2019) 103-112.
    [5]
    A. Babuponnusami, K. Muthukumar, J. Environ. Chem. Eng. 2 (2014) 557-572.
    [6]
    J.J. Pignatello, E. Oliveros, A. MacKay, Crit. Rev. Env. Sci. Tec. 36 (2006) 1-84.
    [7]
    P. Zhou, X. Huo, J. Zhang, Y. Liu, F. Cheng, X. Cheng, Y. Wang, Y. Zhang, Chem. Eng. J. 387 (2020) 124126.
    [8]
    N. Wang, T. Zheng, G. Zhang, P. Wang, J. Environ. Chem. Eng. 4 (2016) 762-787.
    [9]
    T.X.H. Le, M. Bechelany, S. Lacour, N. Oturan, M.A. Oturan, M. Cretin, Carbon 94 (2015) 1003-1011.
    [10]
    Y.S. Ma, C.F. Sung, J.G. Lin, J. Hazard. Mater. 178 (2010) 320-325.
    [11]
    Z.C. Yang, A.Q. Yu, C. Shan, G.D. Gao, B.C. Pan, Water Res. 137 (2018) 37-46.
    [12]
    P. Zhou, J. Zhang, Z. Xiong, Y. Liu, X. Huo, X. Cheng, W. Li, F. Cheng, Y. Zhang, Appl. Catal. B: Environ. 265 (2020) 118264.
    [13]
    L.W. Chen, J. Ma, X.C. Li, J. Zhang, J.Y. Fang, Y.H. Guan, P.C. Xie, Environ. Sci. Technol. 45 (2011) 3925-3930.
    [14]
    Y.X. Qin, F.H. Song, Z.H. Ai, P.P. Zhang, L.Z. Zhang, Environ. Sci. Technol. 49 (2015) 7948-7956.
    [15]
    M. Xing, W. Xu, C. Dong, Y. Bai, J. Zeng, Y. Zhou, J. Zhang, Y. Yin, Chem 4 (2018) 1359-1372.
    [16]
    C.C. Dong, J.H. Ji, B. Shen, M.Y. Xing, J.L. Zhang, Environ. Sci. Technol. 52 (2018) 11297-11308.
    [17]
    J. Bolobajev, M. Trapido, A. Goi, Chem. Eng. J. 281 (2015) 566-574.
    [18]
    T. Li, Z.W. Zhao, Q. Wang, P.F. Xie, J.H. Ma, Water Res. 105 (2016) 479-486.
    [19]
    X.G. Duan, H.Q. Sun, S.B. Wang, Accounts Chem. Res. 51 (2018) 678-687.
    [20]
    P.W. Wu, Q.D. Jia, J. He, L.J. Lu, L.L. Chen, J. Zhu, C. Peng, M.Q. He, J. Xiong, W.S. Zhu, H.M. Li, J. Hazard. Mater. 391 (2020) 122183.
    [21]
    X.W. Li, B. Wang, Y.H. Huang, J. Di, J.X. Xia, W.S. Zhu, H.M. Li, Green Energy Environ. 4 (2019) 198-206.
    [22]
    P.W. Wu, L.J. Lu, J. He, L.L. Chen, Y.H. Chao, M.Q. He, F.X. Zhu, X.Z. Chu, H.M. Li, W.S. Zhu, Green Energy Environ. 5 (2020) 166-172.
    [23]
    A.K. Suri, C. Subramanian, J.K. Sonber, T.S.R.C. Murthy, Int. Mater. Rev. 55 (2010) 4-40.
    [24]
    S. Sasaki, M. Takeda, K. Yokoyama, T. Miura, T. Suzuki, H. Suematsu, W.H. Jiang, K. Yatsui, Sci. Technol. Adv. Mat. 6 (2005) 181-184.
    [25]
    C. Dominguez, N. Cocuaud, D. Drouan, A. Constant, D. Jacquemain, J. Nucl. Mater. 374 (2008) 473-481.
    [26]
    P. Singh, G. Kaur, K. Singh, M. Kaur, M. Kumar, R. Meena, R. Bala, A. Kumar, Materialia 1 (2018) 258-264.
    [27]
    X.F. Qian, M. Ren, M.Y. Fang, M. Kan, D.T. Yue, Z.F. Bian, H.X. Li, J.P. Jia, Y.X. Zhao, Appl. Catal. B: Environ. 231 (2018) 108-114.
    [28]
    H. Bataineh, O. Pestovsky, A. Bakac, Chem. Sci. 3 (2012) 1594-1599.
    [29]
    Z. Wang, J. Jiang, S.Y. Pang, Y. Zhou, C.T. Guan, Y. Gao, J. Li, Y. Yang, W. Qu, C.C. Jiang, Environ. Sci. Technol. 52 (2018) 11276-11284.
    [30]
    H.Y. Dong, Y. Li, S.C. Wang, W.F. Liu, G.M. Zhou, Y.F. Xie, X.H. Guan, Environ. Sci. Technol. Let. 7 (2020) 219-224.
    [31]
    S.Y. Pang, J. Jiang, J. Ma, Environ. Sci. Technol. 45 (2011) 307-312.
    [32]
    O. Pestovsky, S. Stoian, E.L. Bominaar, X.P. Shan, E. Munck, L. Que, A. Bakac, Angew. Chem. Int. Ed. 44 (2005) 6871-6874.
    [33]
    O. Pestovsky, A. Bakac, Inorg. Chem. 45 (2006) 814-820.
    [34]
    H. Gallard, J. De Laat, Water Res. 34 (2000) 3107-3116.
    [35]
    L. Xu, J. Wang, J. Hazard. Mater. 186 (2011) 256-264.
    [36]
    S. Karthikeyan, V.K. Gupta, R. Boopathy, A. Titus, G. Sekaran, J. Mol. Liq. 173 (2012) 153-163.
    [37]
    S.J. Hug, O. Leupin, Environ. Sci. Technol. 37 (2003) 2734-2742.
    [38]
    S. Bang, S. Park, Y.M. Lee, S. Hong, K.B. Cho, W. Nam, Angew. Chem. Int. Ed. 53 (2014) 7843-7847.
    [39]
    X. Duan, W. Li, Z. Ao, J. Kang, W. Tian, H. Zhang, S.-H. Ho, H. Sun, S. Wang, J. Mater. Chem. A 7 (2019) 23904-23913.
    [40]
    P.H. Shao, J.Y. Tian, B.R. Liu, W.X. Shi, S.S. Gao, Y.L. Song, M. Ling, F.Y. Cui, Nanoscale 7 (2015) 14254-14263.
    [41]
    S.H. Bossmann, E. Oliveros, S. Gob, S. Siegwart, E.P. Dahlen, L. Payawan, M. Straub, M. Worner, A.M. Braun, J. Phys. Chem. A 102 (1998) 5542-5550.
    [42]
    O. Pestovsky, A. Bakac, J. Am. Chem. Soc. 126 (2004) 13757-13764.
    [43]
    P. Zhou, W. Ren, G. Nie, X. Li, X. Duan, Y. Zhang, S. Wang, Angew. Chem. Int. Ed. (2020) DOI: 10.1002/anie.202007046.
    [44]
    J. Zou, J. Ma, L.W. Chen, X.C. Li, Y.H. Guan, P.C. Xie, C. Pan, Environ. Sci. Technol. 47 (2013) 11685-11691.
    [45]
    P. Zhou, J. Zhang, Y.L. Zhang, Y. Liu, J. Liang, B. Liu, W. Zhang, RSC Adv. 6 (2016) 38541-38547.
    [46]
    S.Q. Zhou, Y.H. Yu, W.Q. Zhang, X.Y. Meng, J.M. Luo, L. Deng, Z. Shi, J. Crittenden, Environ. Sci. Technol. 52 (2018) 4305-4312.
    [47]
    C.K. Duesteberg, T.D. Waite, Environ. Sci. Technol. 41 (2007) 4103-4110.
    [48]
    L.L. Zhu, J.H. Ji, J. Liu, S.Y. Mine, M. Matsuoka, J.L. Zhang, M.Y. Xing, Angew. Chem. Int. Ed. 59 (2020) 13968-13976.
    [49]
    Y. Chen, G. Zhang, H.J. Liu, J.H. Qu, Angew. Chem. Int. Ed. 58 (2019) 8134-8138.
    [50]
    B. Sheng, F. Yang, Y.H. Wang, Z.H. Wang, Q. Li, Y.G. Guo, X.Y. Lou, J.S. Liu, Chem. Eng. J. 375 (2019) 121989.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (231) PDF downloads(98) Cited by()
    Proportional views

    Publish With GEE

    Contact

    • Email：gee@ipe.ac.cn
    • Tel：010-82627075
    • Address：North 2nd street, Zhongguancun, Haidian District, Beijing, China

    Links

    京ICP备10002620号-1京公网安备 11010802039050号

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return