Volume 7 Issue 2
Apr.  2022
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Article Navigation >  Green Energy&Environment  > 2022  >  7(2): 314-323
Huanran Li, Xiaobo Han, Suyu Jiang, Lili Zhang, Wei Ma, Renzhi Ma, Zhen Zhou. Controllable fabrication and structure evolution of hierarchical 1T-MoS2 nanospheres for efficient hydrogen evolution. Green Energy&Environment, 2022, 7(2): 314-323. doi: 10.1016/j.gee.2020.09.003
Citation: Huanran Li, Xiaobo Han, Suyu Jiang, Lili Zhang, Wei Ma, Renzhi Ma, Zhen Zhou. Controllable fabrication and structure evolution of hierarchical 1T-MoS2 nanospheres for efficient hydrogen evolution. Green Energy&Environment, 2022, 7(2): 314-323. doi: 10.1016/j.gee.2020.09.003
shu

Controllable fabrication and structure evolution of hierarchical 1T-MoS2 nanospheres for efficient hydrogen evolution

doi: 10.1016/j.gee.2020.09.003

  • a Engineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education, School of Chemical Engineering, Zhengzhou University, Zhengzhou, 450001, China;

  • b State Key Laboratory of Powder Metallurgy, Central South University, Changsha, 410083, China;

  • c International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki, 305-0044, Japan;

  • d School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Nankai University, Tianjin, 300350, China

Funds:

This work was supported by National Natural Science Foundation of China (Grant no. 51702291), The National Science Foundation for Post-doctoral Scientists of China (Grant no. 2016M602261), Foundation of Henan Educational Committee (Grant no. 18A150016), State Key Laboratory of Powder Metallurgy, Central South University, Changsha, China and Development Fund for Outstanding Young Teachers of Zhengzhou University. We also gratefully acknowledge the help of Dr. Mengjia Li and Yang Zhang (Advanced Analysis & Computation Center, Zhengzhou University).

  • Received date 15 July 2020, Accepted date 15 September 2020, RevRecd date 30 August 2020, Publish date 10 October 2020,
    Abstract
  • The layered materials have demonstrated great prospects as cost-effective substitutes for precious electrocatalysts in hydrogen evolution reaction. Research efforts have been devoted to synthesizing highly conductive MoS2 with the substantial cardinal plane and edge active sites. Here, we successfully synthesized a hierarchical 1T/2H–MoS2 with sodium ion insertion via a facile hydrothermal method. The contents of the 1T-phase can be flexibly controlled by different hydrothermal temperatures (160 ~ 200 ℃). And the modified uniformly dispersed 1T/2H–MoS2 nanospheres with different d spacings were designed to enhance the electrocatalytic efficiency by adding SiO2 and through the ion exchange process of NaOH and HF solution. The as-synthesized Na+ intercalated 1T-MoS2 nanosphere with an expanded interlayer of 0.95 nm obtained at 160 ℃ exhibits a prominent electrocatalytic performance of hydrogen evolution reaction with a comparable overpotential of 255 mV and a remarkably small Tafel slope of 44 mV/decade. Therefore, this study provides a facile and controllable strategy to yield interlayer-expanded 1T-MoS2 nanospheres, making it a potentially competitive hydrogen evolution catalyst for the hydrogen cell.

     

    • These authors contributed equally to this paper.
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