Volume 7 Issue 1
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Chen Xing, Daihui Yang, Yan Zhang, Tian Sun, Junfei Duan, Hussein A. Younus, Shiguo Zhang. Semi-closed synthesis of nitrogen and oxygen Co-doped mesoporous carbon for selective aqueous oxidation. Green Energy&Environment, 2022, 7(1): 43-52. doi: 10.1016/j.gee.2020.08.013
Citation: Chen Xing, Daihui Yang, Yan Zhang, Tian Sun, Junfei Duan, Hussein A. Younus, Shiguo Zhang. Semi-closed synthesis of nitrogen and oxygen Co-doped mesoporous carbon for selective aqueous oxidation. Green Energy&Environment, 2022, 7(1): 43-52. doi: 10.1016/j.gee.2020.08.013
shu

Semi-closed synthesis of nitrogen and oxygen Co-doped mesoporous carbon for selective aqueous oxidation

doi: 10.1016/j.gee.2020.08.013

  • a College of Materials Science and Engineering, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha, 410082, China;

  • b School of Materials Science and Engineering, Changsha University of Science and Technology, Changsha, 410004, China;

  • c Chemistry Department, Faculty of Science, Fayoum University, Fayoum, 63514, Egypt

  • Received date 27 April 2020, Accepted date 31 August 2020, RevRecd date 20 August 2020, Publish date 05 September 2020,
    Abstract
  • eteroatom-doped meso/micro-porous carbon materials are conventionally produced by harsh carbonization under an inert atmosphere involving specific precursors, hard/soft templates, and heteroatom-containing agents. Herein, we report a facile synthesis of N and O co-doped meso/micro-porous carbon (NOMC) by template-free carbonization of a small-molecule precursor in a semi-closed system. The semi-closed carbonizaiton process yields hydrophilic NOMCs with large surface area in a high yield. The porous structure as well as the elemental composition of NOMCs can be modulated by changing the holding time at a particular temperature. NOMCs as metal-free heterogeneous catalysts can selectively oxidize benzyl alcohol and its derivatives into aldehydes/ketones with > 85% conversion in aqueous solution, which is much higher than that of the control sample obtained in tube furnace (21% conversion), mainly due to their high N content, high percentage of pyridinic N, and large surface area. The presence of O-containing moieties also helps to improve the hydrophilicity and dispersion ability of catalysts and thus facilitates the mass transfer process during aqueous oxidation. The NOMC catalysts also dispayed excellent activity for a wide range of substrates with a selectivity of > 99%.

     

    • • NOMCs are obtained by template-free carbonization of a single precursor in a semi-closed system, without any inert gas protection. • The NOMCs can be used as metal-free catalysts for highly selective aqueous oxidation of alcohols under mild conditions. • The NOMCs can be easily recycled and reused.
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