Volume 7 Issue 3
Jun.  2022
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Article Navigation >  Green Energy&Environment  > 2022  >  7(3): 554-565
Xin Liu, Liwen Yang, Guobao Xu, Juexian Cao. Pomegranate-like porous NiCo2Se4 spheres with N-doped carbon as advanced anode materials for Li/Na-ion batteries. Green Energy&Environment, 2022, 7(3): 554-565. doi: 10.1016/j.gee.2020.08.012
Citation: Xin Liu, Liwen Yang, Guobao Xu, Juexian Cao. Pomegranate-like porous NiCo2Se4 spheres with N-doped carbon as advanced anode materials for Li/Na-ion batteries. Green Energy&Environment, 2022, 7(3): 554-565. doi: 10.1016/j.gee.2020.08.012
shu

Pomegranate-like porous NiCo2Se4 spheres with N-doped carbon as advanced anode materials for Li/Na-ion batteries

doi: 10.1016/j.gee.2020.08.012

  • a School of Physics and Optoelectronics & Hunan Institute of Advanced Sensing and Information Technology, Xiangtan University, Xiangtan, 411105, China;

  • b School of Materials Science and Engineering, Xiangtan University, Xiangtan, 411105, China

Funds:

This work is supported by National Natural Science Foundation of China (No. 11772285, 12074327, 11474245, 11074212), Natural Science Foundation of Hunan Province (No. 2020JJ4088) and Scientific Research Fund of Hunan Provincial Education Department (No. 16A203, 18A064).

  • Received date 22 May 2020, Accepted date 31 August 2020, RevRecd date 24 August 2020, Publish date 09 September 2020,
    Abstract
  • Design and preparation of dual-role anode materials with extraordinary performance for rechargeable Li/Na-ion batteries (LIBs/NIBs) remains highly challenging. Herein, three-dimensional (3D) pomegranate-like porous bimetallic NiCo2Se4 spheres with N-doped carbon (termed as NC@NiCo2Se4) are synthesized by solvothermal method and annealing. Microstructure investigations reveal that the NC@NiCo2Se4 spheres include nano-sized NiCo2Se4 particles as inner core and NiCo2Se4 with the modification of thin-walled N-doped carbon layer as inner/outer shell. The bimetallic NC@NiCo2Se4 spheres possess synergistic interaction of Ni/Co atoms to enhance intrinsic conductivity and electrochemical activity, unique pomegranate-like structure with an inner void space and robust shell to mitigation volume expansion, and intimate contact of N-doped carbon layer to improve interface effect and accelerate conversion kinetics. As anode materials, the NC@NiCo2Se4 exhibits superior lithium/sodium storage performances (1401.6 and 794.8 mA h g−1 at current density of 0.5 and 5 A g−1 after 500 cycles for LIBs as well as 433.9 mA h g−1 at 3 A g−1 after 1000 cycles and a high capability of 306.6 mA h g−1 at 20 A g−1 for NIBs). This work represents an impressive strategy for future research of bimetallic selenides as anode materials for advanced high-performance LIBs/NIBs.

     

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