Volume 7 Issue 1
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Article Navigation >  Green Energy&Environment  > 2022  >  7(1): 137-144
Xiaomin Zhang, Wenjie Xiong, Zengyu Yin, Yongle Chen, Youting Wu, Xingbang Hu. A novel proton-gradient-transfer acid complexes as an efficient and reusable catalyst for fatty acid esterification. Green Energy&Environment, 2022, 7(1): 137-144. doi: 10.1016/j.gee.2020.08.009
Citation: Xiaomin Zhang, Wenjie Xiong, Zengyu Yin, Yongle Chen, Youting Wu, Xingbang Hu. A novel proton-gradient-transfer acid complexes as an efficient and reusable catalyst for fatty acid esterification. Green Energy&Environment, 2022, 7(1): 137-144. doi: 10.1016/j.gee.2020.08.009
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A novel proton-gradient-transfer acid complexes as an efficient and reusable catalyst for fatty acid esterification

doi: 10.1016/j.gee.2020.08.009

  • a Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China;

  • b Yuxiu Postdoctoral Institute, Nanjing University, Nanjing, 210023, China

  • Received date 25 May 2020, Accepted date 17 August 2020, RevRecd date 17 July 2020, Publish date 22 August 2020,
    Abstract
  • In this work, a series of novel proton-gradient-transfer acid complexes (PGTACs) were developed. Their physicochemical properties, including thermal stability, melting point, and Hammett acidity, were measured. The effects of catalyst loading, reaction temperature, and substrate expansion on the catalytic performance were systematically studied. It is found that the combination of bidentate N-heterocycle and H2SO4 (1:2 M ratio) could form simultaneously N-H covalent bond and N…H hydrogen bond, which makes the PGTACs excellent catalysts integrate the advantages of strong acids (high catalytic activity) and ionic liquids (phase separation) in the esterification reaction. Moreover, these PGTACs can be reused by convenient phase separation without obvious diminution of catalytic activity. It is concluded that these PGTACs are potential alternative candidates for esterification reaction in the process of industrial catalysis.

     

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