Volume 6 Issue 4
Aug.  2021
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Article Navigation >  Green Energy&Environment  > 2021  >  6(4): 585-596
Ragne Marie Lilleby Helberg, Jonathan Ø. Torstensen, Zhongde Dai, Saravanan Janakiram, Gary Chinga-Carrasco, Øyvind W. Gregersen, Kristin Syverud, Liyuan Deng. Nanocomposite membranes with high-charge and size-screened phosphorylated nanocellulose fibrils for CO2 separation. Green Energy&Environment, 2021, 6(4): 585-596. doi: 10.1016/j.gee.2020.08.004
Citation: Ragne Marie Lilleby Helberg, Jonathan Ø. Torstensen, Zhongde Dai, Saravanan Janakiram, Gary Chinga-Carrasco, Øyvind W. Gregersen, Kristin Syverud, Liyuan Deng. Nanocomposite membranes with high-charge and size-screened phosphorylated nanocellulose fibrils for CO2 separation. Green Energy&Environment, 2021, 6(4): 585-596. doi: 10.1016/j.gee.2020.08.004
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Nanocomposite membranes with high-charge and size-screened phosphorylated nanocellulose fibrils for CO2 separation

doi: 10.1016/j.gee.2020.08.004

  • a Department of Chemical Engineering, Norwegian University of Science and Technology, Trondheim, 7491, Norway;

  • b RISE PFI, Trondheim, 7491, Norway

Funds:

The authors want to thank the Research Council of Norway for the financial support to the work through the Nano 2021 program (NanoMBE project, number 239172). We thank Södra Cell for supplying the cellulose pulp and Ingebjørg Leirset, Johnny Kvakland Melbø and Anne Reitan for support in the lab.

  • Received date 17 January 2020, Accepted date 16 August 2020, RevRecd date 30 July 2020, Publish date 31 August 2021,
    Abstract

  • In this study, cellulose nanofibrils (CNF) of high charge (H-P-CNF) and screened size (H-P-CNF-S) were fabricated by increasing the charge of phosphorylated cellulose nanofibrils (P-CNFs) during the pre-treatment step of CNF production. Results show that the H-P-CNF have a significantly higher charge (3.41 mmol g-1) compared with P-CNF (1.86 mmol g-1). Centrifugation of H-P-CNF gave a supernatant with higher charge (5.4 mmol g-1) and a reduced size (H-P-CNF-S). These tailored nanocelluloses were added to polyvinyl alcohol (PVA) solutions and the suspensions were successfully coated on porous polysulfone (PSf) supports to produce thin-film nanocomposite membranes. The humid mixed gas permeation tests show that CO2 permeability increases for membranes with the addition of H-P-CNF-S by 52% and 160%, compared with the P-CNF/PVA membrane and neat PVA membrane, respectively.

     

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