Volume 7 Issue 2
Apr.  2022
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Article Navigation >  Green Energy&Environment  > 2022  >  7(2): 352-359
Jiadi Liu, Minghuan Liu, Shaoyun Chen, Bingqing Wang, Jin Chen, Da-Peng Yang, Shangzhou Zhang, Wenxiao Du. Conversion of Au(III)-polluted waste eggshell into functional CaO/Au nanocatalyst for biodiesel production. Green Energy&Environment, 2022, 7(2): 352-359. doi: 10.1016/j.gee.2020.07.019
Citation: Jiadi Liu, Minghuan Liu, Shaoyun Chen, Bingqing Wang, Jin Chen, Da-Peng Yang, Shangzhou Zhang, Wenxiao Du. Conversion of Au(III)-polluted waste eggshell into functional CaO/Au nanocatalyst for biodiesel production. Green Energy&Environment, 2022, 7(2): 352-359. doi: 10.1016/j.gee.2020.07.019
shu

Conversion of Au(III)-polluted waste eggshell into functional CaO/Au nanocatalyst for biodiesel production

doi: 10.1016/j.gee.2020.07.019

  • a College of Life Science, Yantai University, Yantai, Shandong Province, 264005, China;

  • b School of Nuclear Equipment and Nuclear Engineering, Yantai University, Yantai, Shandong Province, 264005, China;

  • c College of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou, Fujian Province, 362000, China;

  • d Clinical Center for Molecular Diagnosis and Therapy, The Second Affiliated Hospital of Fujian Medical University, Quanzhou, Shandong Province, 362000, China

Funds:

This work was supported by the Orientative project funded by Fujian Provincial Science and Technology Department (2019H0023), Quanzhou City Science & Technology Program of China (2017G023), Fujian Educational Committee (JAT160402) and Natural Science Foundation of Shandong Province, China (No. ZR2019MEM012).

  • Received date 19 March 2020, Accepted date 22 July 2020, RevRecd date 14 July 2020, Publish date 29 July 2020,
    Abstract
  • Developing an environmental-friendly and highly active catalyst in transesterification for biodiesel production is of great importance for a more economic biodisel process. Herein, we reported that waste eggshells were used to adsorb Au(III) in water and convert the Au(III)-polluted eggshells into the functional nanocatalyst-CaO/Au for the transesterification reaction between soybean oil and methanol to the preparation of biodiesel. By coupling of CaO and Au nanoparticles, CaO/Au nanoparticles showed superior catalytic activity for the transesterification reaction between soybean oil and methanol. An optimum performance was observed over CaO/Au nanocomposites in a methanol-oil molar ratio at 12 : 1 with catalyst content of 1.0 wt% at 70 ℃ for 3 h. Besides, the catalytic activity of CaO/Au nanocatalyst was almost unchanged after recycling for 5 times and the yield of biodiesel still kept at 88.9%. The proof-of concept study provided us a sustainable method for utilization of waste eggshells to remedy the metal ions-polluted wastewater and the synthesis of functional nanocomposite for biodiesel production, show great potential application of waste eggshell in adsorption and catalytic reactions.

     

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    • References(41)
  • [1]
    Y. Liu, P. Zhang, M. Fan, P. Jiang, Fuel 164(2016) 314-321.
    [2]
    E. Bet-Moushoul, K. Farhadi, Y. Mansourpanah, A.M. Nikbakht, R. Molaei, M. Forough, Fuel 164(2016) 119-127.
    [3]
    P. Zhang, M. Shi, Y. Liu, M. Fan, P. Jiang, Y. Dong, Fuel 186(2016) 787-791.
    [4]
    S.H. Teo, A. Islam, H.R.F. Masoumi, Y.H. Taufiq-Yap, J. Janaun, E.-S. Chan, M.A. Khaleque, Renew. Energy 111(2017) 892-905.
    [5]
    A.S. Yusuff, O.D. Adeniyi, S.O. Azeez, M.A. Olutoye, U.G. Akpan, Biofuels Bioprod. Biorefining 13(2019) 37-47.
    [6]
    J. Zhang, F. Cui, L. Xu, X. Pan, X. Wang, X. Zhang, T. Cui, Nanoscale 9(2017) 15990-15997.
    [7]
    K. Seffati, B. Honarvar, H. Esmaeili, N. Esfandiari, Fuel 235(2019) 1238-1244.
    [8]
    B. Narowska, M. Kułazżyński, M. Łukaszewicz, E. Burchacka, Renew. Energy 135(2019) 176-185.
    [9]
    I.B. Banković-Ilić, M.R. Miladinović, O.S. Stamenković, V.B. Veljković, Renew. Sustain. Energy Rev. 72(2017) 746-760.
    [10]
    L.M. Correia, R.M.A. Saboya, N.D.S. Campelo, J.A. Cecilia, E. Rodríguez-Castellón, C.L. Cavalcante, R.S. Vieira, Bioresour. Technol. 151(2014) 207-213.
    [11]
    F. Yasar, Fuel 255(2019) 115828.
    [12]
    K.N. Krishnamurthy, S.N. Sridhara, C.S.A. Kumar, Renew. Energy 146(2020) 280-296.
    [13]
    K. Seffati, H. Esmaeili, B. Honarvar, N. Esfandiari, Renew. Energy 147(2020) 25-34.
    [14]
    C. Chingakham, A. David, V. Sajith, Chin. J. Chem. Eng. 27(2019) 2835-2843.
    [15]
    Y.H. Tan, M.O. Abdullah, C. Nolasco-Hipolito, N.S.A. Zauzi, Renew. Energy 114(2017) 437-447.
    [16]
    S.W. Won, P. Kotte, W. Wei, A. Lim, Y.S. Yun, Bioresour. Technol. 160(2014) 203-212.
    [17]
    A. Laca, A. Laca, M. Diaz, J. Environ. Manag. 197(2017) 351-359.
    [18]
    J. Goli, O. Sahu, Renew. Energy 128(2018) 142-154.
    [19]
    K. Dayanidhi, P. Vadivel, S. Jothi, N.S. Eusuff, ACS Appl. Mater. Interfaces 12(2020) 1746-1756.
    [20]
    K. Ronan, M.B. Kannan, ACS Sustain. Chem. Eng. 5(2017) 2237-2245.
    [21]
    J.R. Dodson, H.L. Parker, A.M. García, A. Hicken, K. Asemave, T.J. Farmer, H. He, J.H. Clark, A.J. Hunt, Green Chem. 17(2015) 1951-1965.
    [22]
    Q. Ding, Z. Kang, L. Cao, M. Lin, H. Lin, D.-P. Yang, Appl. Surf. Sci. 510(2020) 145526.
    [23]
    X. Huang, L. Chang, Y. Lu, Z. Li, Z. Kang, X. Zhang, M. Liu, D.P. Yang, Mater. Sci. Eng. C-Mater. Biol. Appl. 113(2020) 111015.
    [24]
    M.S. El-Shahawi, A.S. Bashammakh, S.O. Bahaffi, Talanta 72(2007) 1494-1499.
    [25]
    X. Chen, K.F. Lam, S.F. Mak, K.L. Yeung, J. Hazard. Mater. 186(2011) 902-910.
    [26]
    T. Zhang, Z. Tu, G. Lu, X. Duan, X. Yi, C. Guo, Z. Dang, J. Environ. Manag. 188(2017) 1-8.
    [27]
    X. Zhang, X. He, Z. Kang, M. Cui, D.-P. Yang, R. Luque, ACS Sustain. Chem. Eng. 7(2019) 15762-15771.
    [28]
    Y. Guo, D.-P. Yang, M. Liu, X. Zhang, Y. Chen, J. Huang, Q. Li, R. Luque, J. Mater. Chem. A 7(2019) 8832-8844.
    [29]
    Y.C. Sharma, B. Singh, J. Korstad, Fuel 90(2011) 1309-1324.
    [30]
    E.R. Sacia, S. Ramkumar, N. Phalak, L.-S. Fan, ACS Sustain. Chem. Eng. 1(2013) 903-909.
    [31]
    G. Joshi, D.S. Rawat, B.Y. Lamba, K.K. Bisht, P. Kumar, N. Kumar, S. Kumar, Energy Convers. Manag. 96(2015) 258-267.
    [32]
    M.A.Z. Abidin, A.A. Jalil, S. Triwahyono, S.H. Adam, N.H. Nazirah Kamarudin, Biochem. Eng. J. 54(2011) 124-131.
    [33]
    T. Ishida, T. Murayama, A. Taketoshi, M. Haruta, Chem. Rev. 120(2020) 464-525.
    [34]
    D.K. Dumbre, V.R. Choudhary, N.S. Patil, B.S. Uphade, S.K. Bhargava, J. Colloid Interface Sci. 415(2014) 111-116.
    [35]
    G.G. Muciño, R. Romero, A. Ramírez, S.L. Martínez, R. Baeza-Jiménez, R. Natividad, Fuel 138(2014) 143-148.
    [36]
    H.H. Abdelhady, H.A. Elazab, E.M. Ewais, M. Saber, M.S. El-Deab, Fuel 261(2020) 116481.
    [37]
    G. Chen, R. Shan, S. Li, J. Shi, Fuel 153(2015) 48-55.
    [38]
    P. Jaggernauth-Ali, E. John, P. Bridgemohan, Fuel 158(2015) 372-378.
    [39]
    M. Mohamad, N. Ngadi, S.L. Wong, M. Jusoh, N.Y. Yahya, Fuel 190(2017) 104-112.
    [40]
    I. Reyero, F. Bimbela, A. Navajas, G. Arzamendi, L.M. Gandía, Fuel 158(2015) 558-564.
    [41]
    J.M. Rubio-Caballero, J. Santamaría-González, J. Mérida-Robles, R. Moreno-Tost, M.L. Alonso-Castillo, E. Vereda-Alonso, A. JiménezLópez, P. Maireles-Torres, Fuel 105(2013) 518-522.
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