Volume 6 Issue 5
Oct.  2021
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Shenghong Dong, Mingzhe Chen, Jiarui Zhang, Jinzhu Chen, Yisheng Xu. Visible-light-induced hydrogenation of biomass-based aldehydes by graphitic carbon nitride supported metal catalysts. Green Energy&Environment, 2021, 6(5): 715-724. doi: 10.1016/j.gee.2020.07.004
Citation: Shenghong Dong, Mingzhe Chen, Jiarui Zhang, Jinzhu Chen, Yisheng Xu. Visible-light-induced hydrogenation of biomass-based aldehydes by graphitic carbon nitride supported metal catalysts. Green Energy&Environment, 2021, 6(5): 715-724. doi: 10.1016/j.gee.2020.07.004
shu

Visible-light-induced hydrogenation of biomass-based aldehydes by graphitic carbon nitride supported metal catalysts

doi: 10.1016/j.gee.2020.07.004

  • a. State Key Laboratory of Chemical Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China;

  • b. Department of Chemistry, College of Chemistry and Materials Science, Jinan University, No. 855 East Xingye Avenue, Panyu District, Guangzhou, 511443, China;

  • c. Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, China

Funds:

We are grateful for the financial support from National Natural Science Foundation of China (U1810111, 21676089), Natural Science Foundation of Guangdong Province, China (2018B030311010), Youth Science and Technology Innovation Talent of Guangdong TeZhi Plan (2019TQ05L111), and Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Zhejiang University (2018BCE002).

  • Received date 04 April 2020, Accepted date 07 July 2020, RevRecd date 27 June 2020, Publish date 31 October 2021,
    Abstract

  • The plasmonic photocatalyst of Pd supported on graphitic carbon nitride (Pd/g-C3N4) exhibits excellent catalytic activity in photo-induced hydrogenation of biomass-based aldehydes with environmental benign reagents of formic acid (HCOOH) as proton source and triethylamine (TEA) as sacrificial electron donator. The chemical and configurational properties of the Pd/g-C3N4 were systematically analyzed with XRD, TEM and XPS. Under optimized conditions, 27% yield of furfuryl alcohol with the corresponding turnover frequency (TOF) around 3.72 h-1 were obtained from furfural and TEA-HCOOH under visible-light irradiation by using Pd/g-C3N4. Our research additionally reveals that Pd atom is the true catalytic active site for the hydrogenation and the photo-promoted reduction mainly occurs through noble metal nanoparticles (NPs)-induced effect of surface plasmon resonance (SPR). The photo-catalytic system of Pd/g-C3N4 thus demonstrates a green and effective method for the hydrogenation of biomass-based aldehydes with sustainable solar energy as a driven force.

     

    • S.D. and M.C. contributed equally to this work.
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