Volume 7 Issue 1
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Article Navigation >  Green Energy&Environment  > 2022  >  7(1): 165-171
Yinhua Yan, Huiqin Guo, Kexin Li, Liushui Yan. Fabrication of supported acid catalytic composite fibers by a simple and low-cost method and their application on the synthesis of liquid biofuel 5-ethoxymethylfurfural. Green Energy&Environment, 2022, 7(1): 165-171. doi: 10.1016/j.gee.2020.06.028
Citation: Yinhua Yan, Huiqin Guo, Kexin Li, Liushui Yan. Fabrication of supported acid catalytic composite fibers by a simple and low-cost method and their application on the synthesis of liquid biofuel 5-ethoxymethylfurfural. Green Energy&Environment, 2022, 7(1): 165-171. doi: 10.1016/j.gee.2020.06.028
shu

Fabrication of supported acid catalytic composite fibers by a simple and low-cost method and their application on the synthesis of liquid biofuel 5-ethoxymethylfurfural

doi: 10.1016/j.gee.2020.06.028

  • a Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, NanChang Hangkong University, NanChang, 330063, China;

  • b National-Local Joint Engineering Research Center of Heavy Metals Polluants Control and Resource Utilization, NanChang Hangkong University, NanChang, 330063, China

  • Received date 05 January 2020, Accepted date 15 June 2020, RevRecd date 15 June 2020, Publish date 15 August 2020,
    Abstract
  • In this paper, sulfonic groups functionalized annealed bio-based carbon microspheres loaded polytetrafluoroethylene (A-BCMSs-SO3H@PTFE) fibers with high activity, high stability, and easy regeneration were successfully fabricated by a simple method using low-cost raw materials. The characterization results showed that the annealed biomass carbon microspheres derived from waste Camellia oleifera shells were evenly distributed on the polytetrafluoroethylene fibers and the sulfonic groups can be successfully loaded on the surface of annealed biomass carbon microspheres by room temperature sulfonation. Subsequently, the as-prepared A-BCMSs-SO3H@PTFE fibers were applied to the acidcatalyzed synthesis of liquid biofuel 5-ethoxymethylfurfural. The catalytic experiment results indicated that the annealing temperature and time during catalyst preparation have a significant effect on the activity and selectivity of A-BCMSs-SO3H@PTFE fibers. The results of catalytic reaction kinetics showed that the yield of 5-ethoxymethylfurfural can reach more than 60% after 72 h of acid-catalyzed reaction. The stability test showed that the as-prepared A-BCMSs-SO3H@PTFE fibers still maintained a stable acid catalytic activity after four recycles.

     

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