Volume 6 Issue 6
Dec.  2021
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Article Navigation >  Green Energy&Environment  > 2021  >  6(6): 952-960
Xiangyang Zhu, Dong Qiao, Liangrong Yang, Qinling Bi, Huifang Xing, Shan Ni, Menglei Yuan, Huizhou Liu, Luhai Wang, An Ma. Novel magnetic carbon supported molybdenum disulfide catalyst and its application in residue upgrading. Green Energy&Environment, 2021, 6(6): 952-960. doi: 10.1016/j.gee.2020.06.025
Citation: Xiangyang Zhu, Dong Qiao, Liangrong Yang, Qinling Bi, Huifang Xing, Shan Ni, Menglei Yuan, Huizhou Liu, Luhai Wang, An Ma. Novel magnetic carbon supported molybdenum disulfide catalyst and its application in residue upgrading. Green Energy&Environment, 2021, 6(6): 952-960. doi: 10.1016/j.gee.2020.06.025
shu

Novel magnetic carbon supported molybdenum disulfide catalyst and its application in residue upgrading

doi: 10.1016/j.gee.2020.06.025

  • a CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, China;

  • b School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China;

  • c China University of Petroleum, Beijing, 102249, China;

  • d Petrochemical Research Institute, Petrochina, Beijing, 102206, China

  • Received date 10 April 2020, Accepted date 24 June 2020, RevRecd date 01 June 2020, Publish date 31 December 2021,
    Abstract
  • A novel hybrid material consisted of carbon covered Fe3O4 nanoparticles and MoS2 nanoflower (FCM) was designed and prepared by micelle-assisted hydrothermal methods. Multiple techniques, including X-Ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM) and X-ray photoelectron spectroscopy (XPS) were employed to characterize it. The results show that FCM has a flower-like morphology with a 330 nm Fe3O4 core as well as 70 nm highly crystalline MoS2 shell. FCM is superparamagnetic with a saturation magnetization of 35 emu g-1. Then hydrocracking of Canadian bitumen residue (CBR) was applied to estimate its catalytic activity. The results show that FCM exhibits superior catalytic hydrocracking activity compared to bulk MoS2 and commercial oil-dispersed Mo(CO)6 by the same Mo loading. Further measurement by elemental analysis, XPS and XRD reveals that the MoS2 nanoflower with abundant catalytic active sites and covered carbon layer with anti-coke ability donate to the superior upgrading performance. Besides, the catalysts can be easily recovered by the external magnetic field. This work provides a novel kind magnetic nanocatalyst which is potential for slurry-phase hydrocracking applications.

     

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