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Article Navigation >  Green Energy&Environment  > 2020  >  5(3): 341-346
Songna Zhang, Xinyu Wang, Jia Yao, Haoran Li. Electron paramagnetic resonance studies of the chelate-based ionic liquid in different solvents. Green Energy&Environment, 2020, 5(3): 341-346. doi: 10.1016/j.gee.2020.06.018
Citation: Songna Zhang, Xinyu Wang, Jia Yao, Haoran Li. Electron paramagnetic resonance studies of the chelate-based ionic liquid in different solvents. Green Energy&Environment, 2020, 5(3): 341-346. doi: 10.1016/j.gee.2020.06.018
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Electron paramagnetic resonance studies of the chelate-based ionic liquid in different solvents

doi: 10.1016/j.gee.2020.06.018
  • a.

    Department of Chemistry, ZJU-NHU United R&D Center, Zhejiang University, Hangzhou, 310027, China

  • b.

    State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, China

More Information
  • Corresponding author: E-mail address: lihr@zju.edu.cn (Haoran Li)
  • Received date 08 April 2020, Accepted date 20 June 2020, RevRecd date 31 May 2020, Available online 24 June 2020, Publish date 31 July 2020,
    Abstract
  • The electron paramagnetic resonance spectra of the chelate-based ionic liquid [C10mim][Cu(F6-acac)3] in different solvents have been obtained at 120 K. It was found that the values of the63Cu hyperfine coupling constants (AIL) of [C10mim][Cu(F6-acac)3] in molecular solvents were from 116 to 180 Gauss. Moreover, theAIL values in general ionic liquids are more complicated, and two sets of peaks can often be observed in their electron paramagnetic resonance spectra. Based on the Kamlet–Taft parameters, relative permittivity, the experimental results were discussed in terms of solvation effect and coordination of the solvents.

     

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