Volume 6 Issue 4
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Article Navigation >  Green Energy&Environment  > 2021  >  6(4): 578-584
Yihuan Liu, Jiaqi Wu, Huan Liang, Zhao Jin, Lianzhu Sheng, Xin Hu, Ning Zhu, Kai Guo. Recyclable polymer functionalization via end-group modification and block/random copolymerization. Green Energy&Environment, 2021, 6(4): 578-584. doi: 10.1016/j.gee.2020.06.003
Citation: Yihuan Liu, Jiaqi Wu, Huan Liang, Zhao Jin, Lianzhu Sheng, Xin Hu, Ning Zhu, Kai Guo. Recyclable polymer functionalization via end-group modification and block/random copolymerization. Green Energy&Environment, 2021, 6(4): 578-584. doi: 10.1016/j.gee.2020.06.003
shu

Recyclable polymer functionalization via end-group modification and block/random copolymerization

doi: 10.1016/j.gee.2020.06.003

  • a College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing, Jiangsu 211800, China;

  • b College of Materials Science and Engineering, Nanjing Tech University, Nanjing, Jiangsu 211800, China;

  • c State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, Jiangsu 211800, China

Funds:

This work was supported by The National Natural Science Foundation of China (21504039).

  • Received date 03 March 2020, Accepted date 01 June 2020, RevRecd date 13 May 2020, Publish date 31 August 2021,
    Abstract

  • Recyclable polymers offer a great opportunity to address the environmental issues of plastics. Herein, functionalization of recyclable polymers, poly ((R)-3,4-trans six-membered ring-fused GBL) (P ((R)-   M  )), were reported via end-group modifications and block/random copolymerizations. Di-n-butylmagnesium was selected to catalyze ring-opening polymerization (ROP) of (R)-   M   in the presence of a series of functional alcohols as the initiators. Block/random copolymerizations of (R)-   M   and ε-caprolactone (ε-CL), L-lactide (L-LA) and trimethylene carbonate (TMC) were performed to control the onset decomposition temperature (Td), melting temperature (Tm) and glass transition temperature (Tg). These functionalized recyclable polymers would find broad applications as the sustainable plastics.

     

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