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Article Navigation >  Green Energy&Environment  > 2020  >  5(2): 138-146
Xin Wang, Sanguan Ma, Bihua Chen, Jingshun Zhang, Yongya Zhang, Guohua Gao. Swelling acidic poly(ionic liquid)s as efficient catalysts for the esterification of cyclohexene and formic acid. Green Energy&Environment, 2020, 5(2): 138-146. doi: 10.1016/j.gee.2020.04.013
Citation: Xin Wang, Sanguan Ma, Bihua Chen, Jingshun Zhang, Yongya Zhang, Guohua Gao. Swelling acidic poly(ionic liquid)s as efficient catalysts for the esterification of cyclohexene and formic acid. Green Energy&Environment, 2020, 5(2): 138-146. doi: 10.1016/j.gee.2020.04.013
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Swelling acidic poly(ionic liquid)s as efficient catalysts for the esterification of cyclohexene and formic acid

doi: 10.1016/j.gee.2020.04.013

  • Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, 3663 North Zhongshan Road, Shanghai, 200062, China

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  • Corresponding author: E-mail address: ghgao@chem.ecnu.edu.cn (Guohua Gao)
  • Received date 18 February 2020, Accepted date 22 April 2020, RevRecd date 19 April 2020, Available online 01 May 2020, Publish date 30 April 2020,
    Abstract
  • Acidic poly(ionic liquid)s (PILs) with swelling ability were synthesized by free radical copolymerization of N-vinylimidazolium ionic liquids, divinylbenzene (DVB) and sodium acrylate (NaAA), and further acidification by sulfuric acid. The swelling ability of acidic PILs was greatly affected by cross-linker content and chain length of 3-alkyl-substituents on imidazolium. Cross-linked network structures could be observed from the cryogenic scanning electron microscopy (cryo-SEM) images of the swollen acidic PILs in formic acid. Acidic PILs with network structures in swollen state exhibited excellent activities in the esterification of cyclohexene and formic acid, and the catalytic activities were in positive correlation with their swelling abilities. Acidic PIL with 3-octyl-substituent and 2.5 mol% DVB (PIL-C8-2.5DVB-HSO4) had the highest swelling ability in formic acid and exhibited comparable catalytic activities with homogeneous catalysts such as sulfuric acid and p-toluenesulfonic acid.

     

    • Xin Wang and Sanguan Ma contributed equally to this work.
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