Removal of V and Fe from spent denitrification catalyst by using oxalic acid: Study of dissolution kinetics and toxicity

Wenfen Wu; Chenye Wang; Xingrui Wang; Huiquan Li

doi:10.1016/j.gee.2020.03.011

Volume 6 Issue 5

Oct. 2021

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Article Navigation > Green Energy&Environment > 2021 > 6(5): 660-669

Wenfen Wu, Chenye Wang, Xingrui Wang, Huiquan Li. Removal of V and Fe from spent denitrification catalyst by using oxalic acid: Study of dissolution kinetics and toxicity. Green Energy&Environment, 2021, 6(5): 660-669. doi: 10.1016/j.gee.2020.03.011

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Wenfen Wu, Chenye Wang, Xingrui Wang, Huiquan Li. Removal of V and Fe from spent denitrification catalyst by using oxalic acid: Study of dissolution kinetics and toxicity. Green Energy&Environment, 2021, 6(5): 660-669. doi: 10.1016/j.gee.2020.03.011

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Removal of V and Fe from spent denitrification catalyst by using oxalic acid: Study of dissolution kinetics and toxicity

doi: 10.1016/j.gee.2020.03.011

Abstract

Abstract

The selective dissolution of V and Fe from spent denitrification catalyst (SDC) with oxalic acid was investigated to minimise their environmental effects. The dissolution kinetics of different elements from SDC by using 0.1-1.5 mol L^-1 oxalic acid concentration was studied at 60℃-90℃. V and Fe were preferentially released (65% and 81%) compared with Al, Ti and W within 5 min due to the redox reactions of oxalic acid. The dissolved fractions of Fe, V, Al, W and Ti increased with the increase of oxalic acid concentration and reaction temperature. The dissolution kinetic experiments were analysed and controlled diffusion with n < 0.5 according to the Avrami dissolve reaction model (R² > 0.92). The Arrhenius parameters of the E_a values of Ti, W, V, Fe and Al from SDC with oxalic acid were 30, 26, 20, 19 and 11 kJ mol^-1, respectively. The obtained Avrami equation of V and Fe was successfully used to predict their leaching behaviour in oxalic acid. Toxicity characteristic leaching procedure revealed that the toxicity risk of V and Fe metals from SDC after leaching with oxalic acid decreased to below 5 mg kg^-1 residua. Overall, the leaching residua by oxalic acid indicated its safety for the environment.
- Spent denitrification catalyst,
- Oxalic acid,
- Dissolution kinetic,
- Avrami model

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Removal of V and Fe from spent denitrification catalyst by using oxalic acid: Study of dissolution kinetics and toxicity

doi: 10.1016/j.gee.2020.03.011

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Removal of V and Fe from spent denitrification catalyst by using oxalic acid: Study of dissolution kinetics and toxicity

doi: 10.1016/j.gee.2020.03.011

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