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Article Navigation >  Green Energy&Environment  > 2020  >  5(2): 232-239
Jiake Wang, Yan Wang, Zhongzheng Ma, Lifeng Yan. Dissolution of highly molecular weight cellulose isolated from wheat straw in deep eutectic solvent of Choline/l-Lysine hydrochloride. Green Energy&Environment, 2020, 5(2): 232-239. doi: 10.1016/j.gee.2020.03.010
Citation: Jiake Wang, Yan Wang, Zhongzheng Ma, Lifeng Yan. Dissolution of highly molecular weight cellulose isolated from wheat straw in deep eutectic solvent of Choline/l-Lysine hydrochloride. Green Energy&Environment, 2020, 5(2): 232-239. doi: 10.1016/j.gee.2020.03.010
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Dissolution of highly molecular weight cellulose isolated from wheat straw in deep eutectic solvent of Choline/l-Lysine hydrochloride

doi: 10.1016/j.gee.2020.03.010

  • CAS Key Laboratory of Soft Matter Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemical Physics, iCHEM, University of Science and Technology of China, Hefei, 230026, China

More Information
  • Corresponding author: E-mail address: lfyan@ustc.edu.cn (Lifeng Yan)
  • Received date 20 January 2020, Accepted date 13 March 2020, RevRecd date 29 February 2020, Available online 31 March 2020, Publish date 30 April 2020,
    Abstract
  • Green solvents for cellulose dissolution is a key topic for green chemistry, especially natural cellulose with high molecular weight, and there are scarce solvents reported. Deep eutectic solvent (DES) is a typical kind of green solvent that has been attracted much attention recently. Here, high molecular weight natural cellulose (DP > 3000) was first isolated from wheat straw and then be directly dissolved in the choline/l-lysine (Ch/Lys) DES. The solution owns excellent stability, and the solubility reaches ∼5%. Rheological studies revealed that the natural cellulose can be well dispersed in the DES solution and showed gelation at high concentrations. The dissolved cellulose can be regenerated when the dilute acid aqueous solution was added into the solution. It provides an energy conversation and an environmentally friendly route to prepare a cellulose solution, which makes it possible to convert cellulose to valuable chemicals and materials in its homogeneous solution.

     

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