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Article Navigation >  Green Energy&Environment  > 2020  >  5(2): 195-202
Lu Gan, Jiachen Guo, Siying Che, Qiaoxin Xiao, Mingyang Wang, Jienan You, Congmin Wang. Design of functionalized fluorescent ionic liquid and its application for achieving significant improvements in Al3+ detecting. Green Energy&Environment, 2020, 5(2): 195-202. doi: 10.1016/j.gee.2020.03.006
Citation: Lu Gan, Jiachen Guo, Siying Che, Qiaoxin Xiao, Mingyang Wang, Jienan You, Congmin Wang. Design of functionalized fluorescent ionic liquid and its application for achieving significant improvements in Al3+ detecting. Green Energy&Environment, 2020, 5(2): 195-202. doi: 10.1016/j.gee.2020.03.006
shu

Design of functionalized fluorescent ionic liquid and its application for achieving significant improvements in Al3+ detecting

doi: 10.1016/j.gee.2020.03.006
  • a.

    School of Chemistry, Zhejiang University, Hangzhou, 310027, China

  • b.

    Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Zhejiang University, Hangzhou, 310027, China

More Information
  • Corresponding author: E-mail address: chewcm@zju.edu.cn (Congmin Wang)
  • Received date 30 November 2019, Accepted date 10 March 2020, RevRecd date 26 February 2020, Available online 20 March 2020, Publish date 30 April 2020,
    Abstract
  • Specific fluorophore was introduced into ionic liquid based on its tunability, thus a kind of novel fluorescent ionic liquid probe [P66614][HQS] was designed, synthesized and characterized. Compared with non-fluorescent HQS, ionic liquid [P66614][HQS] emitted a certain amount of fluorescence, which could be attributed to the well-delocalized frontier orbitals and its charge transfer character, as demonstrated by quantum chemical calculation. Considering the interaction of [P66614][HQS] with metal ions, the application for detecting specific substance as a chemical sensor, such as Al3+ was investigated. Compared with the traditional probe HQS, significant improvements in Al3+ detecting was achieved by [P66614][HQS] with stronger binding ability, better sensitivity and selectivity. The better performance of [P66614][HQS] was contributed to the changed charge distribution, leading to the stronger binding interaction. We believe that this new fluorescent ionic liquid exhibited unique properties in detecting Al3+ in aqueous solution, which would broaden the application of ionic liquids.

     

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