Volume 6 Issue 1
Feb.  2021
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Article Navigation >  Green Energy&Environment  > 2021  >  6(1): 91-101
Yanyan Liu, Kang Sun, Jianchun Jiang, Wenshu Zhou, Yuan Shang, Chenxia Du, Baojun Li. Metallurgical pyrolysis toward Co@Nitrogen-doped carbon composite for lithium storage. Green Energy&Environment, 2021, 6(1): 91-101. doi: 10.1016/j.gee.2020.03.003
Citation: Yanyan Liu, Kang Sun, Jianchun Jiang, Wenshu Zhou, Yuan Shang, Chenxia Du, Baojun Li. Metallurgical pyrolysis toward Co@Nitrogen-doped carbon composite for lithium storage. Green Energy&Environment, 2021, 6(1): 91-101. doi: 10.1016/j.gee.2020.03.003
shu

Metallurgical pyrolysis toward Co@Nitrogen-doped carbon composite for lithium storage

doi: 10.1016/j.gee.2020.03.003
  • a.

    Institute of Chemical Industry of Forest Products, CAF, National Engineering Lab. for Biomass Chemical Utilization, Key Lab. of Chemical Engineering of Forest Products, National Forestry and Grassland Administration, Key Lab. of Biomass Energy and Material, Jiangsu Province, Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing, 210042, China

  • b.

    College of Chemistry, Zhengzhou University, Zhengzhou, 450001, China

  • c.

    Supercomputer Center in ZZU, Zhengzhou University, Zhengzhou, 450052, China

More Information
  • Corresponding author: E-mail address: jiangjc@icifp.cn (Jianchun Jiang)
  • Received date 11 November 2019, Accepted date 06 March 2020, RevRecd date 15 February 2020, Available online 15 March 2020, Publish date 28 February 2021,
    Abstract
  • Elemental state matter-heteroatom-doped carbon composites are of great importance for the development of anode in lithium ion batteries (LIBs). In this article, metal–organic frameworks (MOFs) are adopted as precursor to prepare Co composites via metallurgical pyrolysis under controllable conditions. The obtained nitrogen-doped porous carbon-Co nanocomposite possesses core–shell structure (Co@C–N). Co@C–N exhibits the best Li storage performances as anode active matter. After the 200th cycles at current density of 0.2 A g−1, a reversible capacity of 870 mAh g−1 is retained. A reversible capacity of 275 mAh g−1 still maintains with 5 A g−1. Co@C–N presents a high reversible capacity with excellent cycle stability. Considering the corresponding experimental and theoretical results, the Co0-based N-doped porous carbon composite is proposed to work as LIBs anode matter. These results provide a new design idea for electrode matters of metallic ion battery, and demonstrate that MOFs pyrolysis is an effective method for the construction of elemental state anode materials.

     

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