Volume 6 Issue 1
Feb.  2021
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Article Navigation >  Green Energy&Environment  > 2021  >  6(1): 75-82
Chen Hu, Kun Ma, Yanjie Hu, Aiping Chen, Petr Saha, Hao Jiang, Chunzhong Li. Confining MoS2 nanocrystals in MOF-derived carbon for high performance lithium and potassium storage. Green Energy&Environment, 2021, 6(1): 75-82. doi: 10.1016/j.gee.2020.02.001
Citation: Chen Hu, Kun Ma, Yanjie Hu, Aiping Chen, Petr Saha, Hao Jiang, Chunzhong Li. Confining MoS2 nanocrystals in MOF-derived carbon for high performance lithium and potassium storage. Green Energy&Environment, 2021, 6(1): 75-82. doi: 10.1016/j.gee.2020.02.001
shu

Confining MoS2 nanocrystals in MOF-derived carbon for high performance lithium and potassium storage

doi: 10.1016/j.gee.2020.02.001
  • a.

    Key Laboratory for Ultrafine Materials of Ministry of Education, Shanghai Engineering Research Center of Hierarchical Nanomaterials, School of Materials Science and Engineering, East China University of Science & Technology, Shanghai, 200237, China

  • b.

    Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, Trida T. Bati 5678, 760 01, Zlin, Czech Republic

More Information
  • Corresponding author: E-mail address: apchen@ecust.edu.cn (Aiping Chen); E-mail address: jianghao@ecust.edu.cn (Hao Jiang)
  • Received date 09 November 2019, Accepted date 03 February 2020, RevRecd date 30 December 2019, Available online 13 February 2020, Publish date 28 February 2021,
    Abstract
  • Developing an efficient synthesis protocol to simultaneously control 2D nanomaterials’ size and dispersion is the pivot to optimize their electrochemical performance. Herein, we report the synthesis of uniform MoS2 nanocrystals well-anchored into the void space of porous carbon (donated as MoS2⊂C hybrids) by a simple confined reaction in metal–organic framework (MOF) during carbonization process. The strong confinement effect refrain MoS2 growth and aggregation, generating abundant active centers and edges, which contribute fast lithium/potassium reaction kinetics. In addition to the hybridization with the derived carbon, the MoS2⊂C hybrids exhibit rapid Li+ transfer rate (∼10−9 cm2 s−1) and greatly improved electronic conductivity. Consequently, the MoS2⊂C hybrids show ultrafast rate performances and satisfactory cycling stabilities as anode materials for both lithium and potassium ion batteries. This work demonstrates a universal tactic to achieve high dispersive 2D nanomaterials with tailorable particle size.

     

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