Volume 6 Issue 1
Feb.  2021
Turn off MathJax
Article Contents
Abstract
References
Article Navigation >  Green Energy&Environment  > 2021  >  6(1): 102-113
Pei Xiong, Peng He, Yixin Qu, Liguo Wang, Yan Cao, Shuang Xu, Jiaqiang Chen, Muhammad Ammar, Huiquan Li. The adsorption properties of NaY zeolite for separation of ethylene glycol and 1,2-butanediol: Experiment and molecular modelling. Green Energy&Environment, 2021, 6(1): 102-113. doi: 10.1016/j.gee.2019.12.006
Citation: Pei Xiong, Peng He, Yixin Qu, Liguo Wang, Yan Cao, Shuang Xu, Jiaqiang Chen, Muhammad Ammar, Huiquan Li. The adsorption properties of NaY zeolite for separation of ethylene glycol and 1,2-butanediol: Experiment and molecular modelling. Green Energy&Environment, 2021, 6(1): 102-113. doi: 10.1016/j.gee.2019.12.006
shu

The adsorption properties of NaY zeolite for separation of ethylene glycol and 1,2-butanediol: Experiment and molecular modelling

doi: 10.1016/j.gee.2019.12.006
  • a.

    College of Chemical Engineering, Beijing University of Chemical Technology, Beijing, 100029, China

  • b.

    CAS Key Laboratory of Green Process and Engineering, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, China

  • c.

    Sino-Danish College, University of Chinese Academy of Sciences, Beijing, 100049, China

  • d.

    Sino-Danish Center for Education and Research, University of Chinese Academy of Sciences, Beijing, 10049, China

  • e.

    School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China

  • f.

    Dalian National Laboratory for Clean Energy, Dalian, 116023, China

  • g.

    Department of Chemical Engineering Technology, Government College University, Faisalabad 38000, Pakistan

More Information
  • Corresponding author: E-mail address: phe@ipe.ac.cn (Peng He); E-mail address: lgwang@ipe.ac.cn (Liguo Wang); E-mail address: hqli@ipe.ac.cn (Huiquan Li)
  • Received date 13 November 2019, Accepted date 25 December 2019, RevRecd date 24 December 2019, Available online 25 January 2020, Publish date 28 February 2021,
    Abstract
  • The separation of ethylene glycol (EG) and 1,2-butanediol (1,2-BDO) azeotrope in the synthesis process of EG via coal and biomass is becoming of increasing commercial and environmental importance. Selective adsorption is deemed as the most promising methods because of energy saving and environment favorable. In this paper, NaY zeolite was used to separate 1,2-BDO from EG, and its adsorption properties was then investigated. The isotherms of EG and 1,2-BDO in vapor and liquid phases from 298 to 328 K indicated that they fitted Langmuir model quite well, and the NaY zeolite absorbent favored EG more than 1,2-BDO. The Grand Canonical Monte Carlo (GCMC) and molecular dynamics (MD) simulation techniques were conducted to investigate the competition adsorption and diffusion characteristics in different adsorption regions. It was observed that EG and 1,2-BDO molecules all have the most probable locations of the center of the 12-membered ring near the Na cations. The diffusivities of EG are lower than those of 1,2-BDO at the same adsorption concentration. At last, the breakthrough curves of the binary mixture regressed from the empirical Dose–Response model in fixed-bed column showed that the adsorption selectivity of EG could reach to as high as 2.43, verified that the NaY zeolite could effectively separate EG from 1,2-BDO. This work is also helpful for further separation of other dihydric alcohol mixtures from coal and biomass fermentation.

     

    • FullText(HTML)
    • References(48)
  • [1]
    Z.-Q. Wang; Z.-N. Xu; S.-Y. Peng; Z.-F. Zhou; P.-B. Pan; L. Lin; Y.-Y. Qin; G.-C. Guo; Y.-G. Yao, Chin. J. Chem. 35 (2017) 759-768.
    [2]
    B. Abbasi; H. Guo; H. Wu; H.N. Tailor; Z.-G. Ye, Can. J. Chem. 96 (2018) 255-259.
    [3]
    S. Wang; K.-H. Yin; Y.-C. Zhang; H.-C. Liu, ASC Catal. 3 (2013) 2112-2121.
    [4]
    Q.-C. Yang; S. Zhu; Q. Yang; W.-Q. Huang; P.-J. Yu; D.-W. Zhang; Z.-B. Wang, Energy Convers. Manag. 198 (2019) 111814.
    [5]
    R.-L. Jiang; W.-L. Chen; R.-X. Zhao; Q. Wang, J. China Univ. Min. Technol. 41 (2012) 811-816.
    [6]
    W.-D. Jin; S.-L. Zhu, Petrochem. Technol. 28 (1999) 27-31.
    [7]
    A.V. Orchilles; P.J. Miguel; V. Gonzalez-Alfaro; F.J. Llopis; A. Martinez-Andreu, J. Chem. Thermodyn. 110 (2017) 4875-4880.
    [8]
    J.E. Taylor.; Hitoshi Masui, J. Phys. Chem. 105 (2001) 3532-3535.
    [9]
    H. Li; Z.-Y. Zhao; J. Qin; R. Wang; X. Gao, Ind. Eng. Chem. Res. 57 (2018) 5083-5092.
    [10]
    Y.-C. Chen; S.-K. Hung; H.-Y. Lee; I.-L. Chien, Ind. Eng. Chem. Res. 54 (2015) 3828-3843.
    [11]
    X. Niu; L.-G. Wang; J.-Y. Cao; Y. Cao; P. He; J.-Y. Zhou; H.-Q. Li, RSC Adv.. 9 (2019) 10072-10080.
    [12]
    H.-M. Yang; G.-Z. Qiu, Multipur. Util. Miner. Resour. 5 (1996) 24-28.
    [13]
    X.-W. Liu, Mod. Chem. Ind. 36 (2016) 16-19.
    [14]
    R.S. Haszeldine, Science 325 (2009) 1647-1652.
    [15]
    Y. Zhao; D.-Z. Zhao; D.-H. Zhao; K. Wang, Appl. Chem. Ind. 47 (2018) 584-588.
    [16]
    M.-T. Liang; C.-H. Lin; P.-Y. Tsai; H.-P. Wang; H.-P. Wan; T.-Y. Yang, J. Taiwan Inst. Chem. Eng. 61 (2016) 12-19.
    [17]
    S.B. McCullen; J.C. Vartuli; C.T. Kresge; W.J. Roth; J.S. Beck; K.D. Schmitt; M.E. Leonowicz; J.L. Schlenker; S.S. Shih; J.D. Lutner, A New Family of Mesoporous Molecular Sieves, Springer, Boston, 2002.
    [18]
    C.T. Kresge; M.E. Leonowicz; W.J. Roth; J.C. Vartuli; J.S. Beck, Nature 359 (1992) 710-712.
    [19]
    J. Xiao; L.-P. Zhou; L. Chen, Method for Separating Ethylene Glycol, Propylene Glycol and Butanediol. CN102372601A, 2012-03-14, 2012.
    [20]
    J.-T. Liu; W.-M. Wang; G.-Q. Liu, A Method of Refining Ethylene Glycol. CN102219641A, 2011-10-19, 2011.
    [21]
    J.-L. Yu; Y. Yang; W.-T. Chen; D. Xu; H. Guo; K. Li; H.-Q. Liu, Green Energy Environ.. 1 (2016) 166-171.
    [22]
    I. Kuzniarska-Biernacka; P. Parpot; C. Oliveira; A.R. Silva; M.J. Alves; A.M. Fonseca; I.C.N.J.o.P.C. C, J. Phys. Chem. C 118 (2014) 19042-19050.
    [23]
    J. Thoret, P.P. Man, J. Fraissard, in: M.J. Comstock, M.J. Comstock (Eds.), Fluid Catalytic Cracking III, American Chemical Society, Washington, DC, 1994, pp. 147-159.
    [24]
    M.L. McGlashan, Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix Ii: Definitions, Terminology and Symbols in Colloid and Surface Chemistry, Walter de Gruyter GmbH, Berlin/Boston, 1972.
    [25]
    Y.-Y. Zhang. reportSynthesis of Microporous and Mesoporous Molecular Sieves Fron Husk. Master Thesis, Shandong University of Technology, 2015.
    [26]
    L.-J. Liu; Y.-F. Feng; Z.-H. Chen; J. Ju; A.-W. Zeng, Chem. Ind. Eng. Prog. 33 (2014) 2552-2556.
    [27]
    X.-X. Wei; Y. Wang; A.J. Hernandez-Maldonado; Z.-F. Chen, Green Energy Environ.. 2 (2017) 363-369.
    [28]
    B. Wang; L.-H. Xie; X.Q. Wang; X.-M. Liu; J.-P. Li; J.-R. Li, Green Energy Environ.. 3 (2018) 191-228.
    [29]
    L.-P. Zhong; J. Xiao; Y.-Y. Lu, Method for Ethylene Glycol and Butanediol Separation. CN102372598A, 2012-03-14, 2012.
    [30]
    M.M.A. Mohammed; J.A. Muthanna, J. Taiwan Inst. Chem. Eng. 81 (2017) 218-224.
    [31]
    D.F. Plant; G. Maurin; R.G. Bell, J. Phys. Chem. B 111 (2007) 2836-2844.
    [32]
    L.-J. Song; L.V.C. Rees, Microporous Mesoporous Mater. 35-36 (2000) 301-314.
    [33]
    Langmuir, J. Am. Chem. Soc. 38 (1916) 2221 -2295.
    [34]
    G. Bergerhoff; W.H. Baur; W. Nowacki, Neues Jahrb. Mineral. 13 (1958) 193-200.
    [35]
    Z. Zhou; L. Hui; Z. Jiqin; C. Biaohua; T. Huiping; H. Zhenfu, Chin. J. Chem. Eng. 17 (2009) 618-624.
    [36]
    I. Halasz; S. Kim; B. Marcus, J. Phys. Chem. B 105 (2001) 10788-10796.
    [37]
    D.F. Plant; G. Maurin; R.G. Bell, J. Phys. Chem. B 110 (2006) 15926-15931.
    [38]
    G. Maurin; D.F. Plant; F. Henn; R.G. Bell, J. Phys. Chem. B 110 (2006) 18447-18454.
    [39]
    L. Yang; S.I. Sandler; D.G. Vlachos; C. Peng; H. Liu; Y. Hu, Ind. Eng. Chem. Res. 50 (2011) 14084-14089.
    [40]
    W.-D. Jin; S.-L. Zhu, Chem. Eng. Technol. 23 (2000) 151-156.
    [41]
    J. Goel; K. Kadirvelu; C. Rajagopal; V.K. Garg, J. Hazard. Mater. B 125 (2005) 211-220.
    [42]
    F.J. Garcia-Mateos; R.Ruiz-Rosas; M.D. Marques; L.M. Cotoruelo; J. Rodriguez-Mirasol; T. Cordero, Chem. Eng. J. 279 (2015) 18-30.
    [43]
    Y.H. Zhang; F. Jin; Z.T. Shen; F. Wang; R. Lynch; A.-T. Abir, Chemosphere 220 (2018) 422-431.
    [44]
    R.M. Mohamed; I.A. Mkhalid; M.A. Barakat, Arab. J. Chem. 8 (2015) 48-53.
    [45]
    H.-Y. Sun; L.-P. Sun; F. Li; Long Zhang, Fuel Process. Technol. 134 (2015) 284-289.
    [46]
    X.-Q. Yao. reportSynthesis of Zsm-5 with Controllable Morphologies and Their Adsorption/desorption Studies Master Thesis, Beijing University of Chemical Technology, 2013.
    [47]
    O. Ozdemir; M. Turan; A. Z. Turan; A. Faki; A. B. Engin, J. Hazard. Mater. 166 (2009) 647-654
    [48]
    J.M. Salman; V.O. Njoku; B.H. Hameed, Chem. Eng. J. 174 (2011) 33-40.
    • Relative Articles

  • Relative Articles

    [1]Jianran Ren, Zhiliang Zhu, Yanling Qiu, Fei Yu, Tao Zhou, Jie Ma, Jianfu Zhao. Simultaneous Adsorption-Reduction Boosted by In-situ Magnetic Field.  Green Energy&Environment. doi: 10.1016/j.gee.2024.04.006
    [2]Peng Zhang, Mingming He, Wei Teng, Fukuan Li, Xinyuan Qiu, Kexun Li, Hao Wang. Ordered mesoporous materials for water pollution treatment: Adsorption and catalysis.  Green Energy&Environment, 2024, 9(8): 1239-1256. doi: 10.1016/j.gee.2023.11.001
    [3]Xiao Yu, Shilin Fan, Bin Zhu, Soliman I. El-Hout, Jian Zhang, Chunlin Chen. Recent progress on photothermal nanomaterials: Design, mechanism, and applications.  Green Energy&Environment. doi: 10.1016/j.gee.2024.09.002
    [4]Yuan Yao, Haodan Cheng, Guocai Zhong, Xiaolong Tang, Honghong Yi, Shunzheng Zhao, Fengyu Gao, Qingjun Yu. Progress in the construction strategy of noble metal active sites for zeolite-based PNA and VOCs catalysts.  Green Energy&Environment. doi: 10.1016/j.gee.2024.06.001
    [5]Haoyang Zhang, Binyu Wang, Wenfu Yan. The structure-directing role of heterologous seeds in the synthesis of zeolite.  Green Energy&Environment, 2024, 9(5): 792-801. doi: 10.1016/j.gee.2023.02.005
    [6]Rui Li, Qixuan Lin, Junli Ren, Xiaobao Yang, Yingxiong Wang, Lingzhao Kong. Dealuminated Hβ zeolite for selective conversion of fructose to furfural and formic acid.  Green Energy&Environment, 2024, 9(2): 311-320. doi: 10.1016/j.gee.2022.06.003
    [7]Bin Yue, Jianhua Wang, Shanshan Liu, Guangjun Wu, Bin Qin, Landong Li. Efficient nitric oxide capture and reduction on Ni-loaded CHA zeolites.  Green Energy&Environment. doi: 10.1016/j.gee.2023.12.005
    [8]Risheng Bai, Yue Song, Ge Tian, Fei Wang, Avelino Corma, Jihong Yu. Titanium-rich TS-1 zeolite for highly efficient oxidative desulfurization.  Green Energy&Environment, 2023, 8(1): 163-172. doi: 10.1016/j.gee.2021.03.006
    [9]Peisong Yang, Gang Lu, Qingyuan Yang, Lei Liu, Xin Lai, Duli Yu. Analyzing acetylene adsorption of metal–organic frameworks based on machine learning.  Green Energy&Environment, 2022, 7(5): 1062-1070. doi: 10.1016/j.gee.2021.01.006
    [10]Wanggang Zhang, Yiming Liu, Zhiyuan Song, Changwan Zhuang, Aili Wei. The storage mechanism difference between amorphous and anatase as supercapacitors.  Green Energy&Environment, 2022, 7(1): 156-164. doi: 10.1016/j.gee.2020.10.004
    [11]Wei Chen, Mian Li, Wen-Li Peng, Ling Huang, Chao Zhao, Dinesh Acharya, Wentao Liu, Anmin Zheng. Covalent organic framework shows high isobutene adsorption selectivity from C4 hydrocarbons: Mechanism of interpenetration isomerism and pedal motion.  Green Energy&Environment, 2022, 7(2): 296-306. doi: 10.1016/j.gee.2020.09.016
    [12]Qing-Shan Kong, Xing-Long Li, Hong-Bo Shen, Hua-Jian Xu, Yao Fu. Na-MnOx catalyzed aerobic oxidative cleavage of biomass-derived 1,2-diols to synthesis medium-chain furanic chemicals.  Green Energy&Environment, 2022, 7(5): 957-964. doi: 10.1016/j.gee.2020.12.007
    [13]Zheng Zhang, Kai Chen, Qiang Zhao, Mei Huang, Xiaoping Ouyang. Comparative adsorption of heavy metal ions in wastewater on monolayer molybdenum disulfide.  Green Energy&Environment, 2021, 6(5): 751-758. doi: 10.1016/j.gee.2020.06.019
    [14]Shangqing Chen, Jiayin Hu, Guoliang Mi, Yafei Guo, Tianlong Deng. Novel montmorillonite-sulfur composite for enhancement of selective adsorption toward cesium.  Green Energy&Environment, 2021, 6(6): 893-902. doi: 10.1016/j.gee.2020.07.016
    [15]Ye Song, Bo Peng, Xue Yang, Qiuqiao Jiang, Jun Liu, Wei Lin. Trail of sulfur during the desulfurization via reactive adsorption on Ni/ZnO.  Green Energy&Environment, 2021, 6(4): 597-606. doi: 10.1016/j.gee.2020.05.010
    [16]Shiru Lin, Kaitlyn A. Jacoby, Jinxing Gu, Dariana R. Vega-Santander, Arturo J. Hernández-Maldonado, Zhongfang Chen. Zeolite-templated carbons as effective sorbents to remove methylsiloxanes and derivatives: A computational screening.  Green Energy&Environment, 2021, 6(6): 884-892. doi: 10.1016/j.gee.2020.07.007
    [17]Lei Liu, Binit Lukose, Pablo Jaque, Bernd Ensing. Reaction mechanism of hydrogen activation by frustrated Lewis pairs.  Green Energy&Environment, 2019, 4(1): 20-28. doi: 10.1016/j.gee.2018.06.001
    [18]Xingling Zhao, Kai Wu, Weiping Liao, Yingxiong Wang, Xiaoning Hou, Mingshan Jin, Zhanghuai Suo, Hui Ge. Improvement of low temperature activity and stability of Ni catalysts with addition of Pt for hydrogen production via steam reforming of ethylene glycol.  Green Energy&Environment, 2019, 4(3): 300-310. doi: 10.1016/j.gee.2018.11.002
    [19]Jacqueline González González, Mónica Nájera-Lara, Varinia López-Ramírez, Juan Antonio Ramírez-Vázquez, José J.N. Segoviano-Garfias. Spectrophotometric determination of the formation constants of Calcium(II) complexes with 1,2-ethylenediamine, 1,3-propanediamine and 1,4-butanediamine in acetonitrile.  Green Energy&Environment, 2017, 2(1): 51-57. doi: 10.1016/j.gee.2017.01.002
    [20]Xiaoxuan Wei, Ya Wang, Arturo J. Hernández-Maldonado, Zhongfang Chen. Guidelines for rational design of high-performance absorbents: A case study of zeolite adsorbents for emerging pollutants in water.  Green Energy&Environment, 2017, 2(4): 363-369. doi: 10.1016/j.gee.2017.05.002
    • Supplements(0)
    • Cited By

  • Cited by

    Periodical cited type(14)

    1. Kim, K.J., Yoo, C.-Y., Park, J. et al. Zeolite-templated carbon synthesized with ion-exchanged FAU-zeolite using alkaline earth metal ions for the selective adsorption of C2 hydrocarbons over C1 hydrocarbon. Separation and Purification Technology, 2025. doi:10.1016/j.seppur.2024.129015
    2. Liang, J., Jiang, J., Cai, T. et al. Advances in selective conversion of carbohydrates into 5-hydroxymethylfurfural. Green Energy and Environment, 2024, 9(9): 1384-1406. doi:10.1016/j.gee.2023.11.005
    3. Hanh, N.T.D., Shih, J.-Y., Chen, K.-H. et al. Dynamic kinetic studies of CO2 capture using polyethyleneimine-modified cylindrical NaY zeolite in packed beds under ambient conditions. Journal of the Taiwan Institute of Chemical Engineers, 2024. doi:10.1016/j.jtice.2024.105366
    4. Zhang, L., Huang, S., Qiu, J. et al. Selective transformation of biomass-derived substrates to 1, 2-butanediol: A comprehensive review and new insights. Industrial Crops and Products, 2023. doi:10.1016/j.indcrop.2023.116984
    5. Wong, M.K., Lock, S.S.M., Chan, Y.H. et al. Towards sustainable production of bio-based ethylene glycol: Progress, perspective and challenges in catalytic conversion and purification. Chemical Engineering Journal, 2023. doi:10.1016/j.cej.2023.143699
    6. Wang, J., Shen, R., Cao, Y. et al. Separation of ethylene glycol, 1, 2-butanediol and 1, 2-propanediol with azeotropic distillation. Canadian Journal of Chemical Engineering, 2023, 101(7): 4217-4229. doi:10.1002/cjce.24771
    7. Dai, J., Feng, A., Mi, L. et al. Adsorption Mechanism of NaY Zeolite Molecular Adsorber Coating on Typical Space Contaminations | [NaY 沸石分子吸附涂层对典型空间污染物的吸附机制研究]. Wuji Cailiao Xuebao/Journal of Inorganic Materials, 2023, 38(10): 1237-1244. doi:10.15541/jim20230095
    8. Misturini, A., Rey, F., Sastre, G. Molecular Simulation of Biobutanol Recovery Using LTA and CHA Zeolite Nanosheets with an External Surface. Journal of Physical Chemistry C, 2022, 126(41): 17680-17691. doi:10.1021/acs.jpcc.2c04331
    9. Zhao, Y., Xu, C., Qi, Q. et al. Tailoring delicate pore environment of 2D Covalent organic frameworks for selective palladium recovery. Chemical Engineering Journal, 2022. doi:10.1016/j.cej.2022.136823
    10. Zhang, C., Wang, L., Han, Z. et al. Efficient hydrogenation of ethylene carbonate derived from CO2 to synthesize methanol and ethylene glycol over core-shell Cu@GO catalyst. Green Chemical Engineering, 2022, 3(3): 228-239. doi:10.1016/j.gce.2021.12.004
    11. Ma, Z., Xin, Z., Qin, S. et al. Highly Efficient Decarboxylation of L-Lysine to Cadaverine Catalyzed by RuO2 Encapsulated in FAU Zeolite. Catalysts, 2022, 12(7): 733. doi:10.3390/catal12070733
    12. Yi, F., He, P., Cao, J. et al. Study on adsorptive separation property of CaY zeolite for ethylene glycol and 1, 2-butanediol | [CaY分子筛对乙二醇和1, 2-丁二醇吸附分离性能的研究]. Guocheng Gongcheng Xuebao/The Chinese Journal of Process Engineering, 2022, 22(4): 448-457. doi:10.12034/j.issn.1009-606X.221007
    13. Fang, Y., Wakisaka, M. A review on the modified atmosphere preservation of fruits and vegetables with cutting-edge technologies. Agriculture (Switzerland), 2021, 11(10): 992. doi:10.3390/agriculture11100992
    14. Moradi, H., Azizpour, H., Bahmanyar, H. et al. Effect of Si/Al Ratio in the Faujasite Structure on Adsorption of Methane and Nitrogen: A Molecular Dynamics Study. Chemical Engineering and Technology, 2021, 44(7): 1221-1226. doi:10.1002/ceat.202000356

    Other cited types(3)

  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (233) PDF downloads(28) Cited by(17)
    Proportional views

    Publish With GEE

    Contact

    • Email：gee@ipe.ac.cn
    • Tel：010-82627075
    • Address：North 2nd street, Zhongguancun, Haidian District, Beijing, China

    Links

    京ICP备10002620号-1京公网安备 11010802039050号

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return