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Article Navigation >  Green Energy&Environment  > 2020  >  5(2): 124-129
Hao Qin, Yishan Zhou, Qian Zeng, Hongye Cheng, Lifang Chen, Bingjian Zhang, Zhiwen Qi. Efficient Knoevenagel condensation catalyzed by imidazole-based halogen-free deep eutectic solvent at room temperature. Green Energy&Environment, 2020, 5(2): 124-129. doi: 10.1016/j.gee.2019.11.002
Citation: Hao Qin, Yishan Zhou, Qian Zeng, Hongye Cheng, Lifang Chen, Bingjian Zhang, Zhiwen Qi. Efficient Knoevenagel condensation catalyzed by imidazole-based halogen-free deep eutectic solvent at room temperature. Green Energy&Environment, 2020, 5(2): 124-129. doi: 10.1016/j.gee.2019.11.002
shu

Efficient Knoevenagel condensation catalyzed by imidazole-based halogen-free deep eutectic solvent at room temperature

doi: 10.1016/j.gee.2019.11.002
  • a.

    Max Planck Partner Group at the State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China

  • b.

    School of Chemical Engineering and Technology, Sun Yat-Sen University, 135 Xingang West Road, Guangzhou, 510275, China

More Information
  • Corresponding author: E-mail address: zwqi@ecust.edu.cn (Zhiwen Qi)
  • Received date 11 June 2019, Accepted date 14 November 2019, RevRecd date 09 November 2019, Available online 03 December 2019, Publish date 30 April 2020,
    Abstract
  • For the first time, we employed the halogen-free deep eutectic solvent (DES) into the Knoevenagel condensation between aromatic aldehydes and active methylene compounds at room temperature. The DESs [3Im:PTSA] and [4Im:PTSA] were prepared by imidazole (Im) andp-toluenesulfonic acid (PTSA), which were experimentally screened from a series of organic acids with imidazole. α, β-Unsaturated carbonyl compounds were obtained in good to excellent yields under solvent-free conditions with fast reaction rate. These two DESs can be reused for multiple times with no loss of catalytic activity.

     

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