Volume 5 Issue 1
. 
Turn off MathJax
Article Contents
Article Navigation >  Green Energy&Environment  > 2020  >  5(1): 69-75
Zhiwei Lu, Xiaochao Xu, Yujuan Chen, Xiaohui Wang, Li Sun, Kelei Zhuo. Nitrogen and sulfur co-doped graphene aerogel with hierarchically porous structure for high-performance supercapacitors. Green Energy&Environment, 2020, 5(1): 69-75. doi: 10.1016/j.gee.2019.06.001
Citation: Zhiwei Lu, Xiaochao Xu, Yujuan Chen, Xiaohui Wang, Li Sun, Kelei Zhuo. Nitrogen and sulfur co-doped graphene aerogel with hierarchically porous structure for high-performance supercapacitors. Green Energy&Environment, 2020, 5(1): 69-75. doi: 10.1016/j.gee.2019.06.001
shu

Nitrogen and sulfur co-doped graphene aerogel with hierarchically porous structure for high-performance supercapacitors

doi: 10.1016/j.gee.2019.06.001

  • Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan, 453007, China

More Information
  • Corresponding author: E-mail address: klzhuo@263.net (Kelei Zhuo)
  • Received date 30 December 2018, Accepted date 11 June 2019, RevRecd date 26 April 2019, Available online 10 September 2019, Publish date 31 January 2020,
    Abstract
  • Supercapacitors with unique performance have been widely utilized in many fields. Herein, we report a nitrogen and sulfur co-doped graphene aerogel (N/S-GA-2) prepared using a low toxic precursor for high-performance supercapacitors. The as-obtained material possesses a hierarchically porous structure and a large number of electrochemical active sites. At a current density of 1 A g−1, the specific capacitance of the N/S-GA-2 for supercapacitors with the ionic liquid as the electrolyte is 169.4 F g−1, and the corresponding energy density is 84.5 Wh kg−1. At a power density of 8.9 kW kg−1, the energy density can reach up to 75.7 Wh kg−1, showing that the N/S-GA-2 has an excellent electrochemical performance. Consequently, the N/S-GA-2 can be used as a promising candidate of electrode materials for supercapacitors with high power density and high energy density.

     

    • These authors contributed equally to this work.
    FullText(HTML)
  • loading
    • References(47)
  • [1]
    Q. Wang, J. Yan, Z. Fan, Energy & Environmental Science 9 (2016) 729-762.
    [2]
    C. Liu, F. Li, L.P. Ma, H.M. Cheng, Advanced Materials 22 (2010) E28-E62.
    [3]
    Q. Long, W. Chen, H. Xu, X. Xiong, Y. Jiang, F. Zou, X. Hu, Y. Xin, Z. Zhang, Y. Huang, Energy & Environmental Science 6 (2013) 2497-2504.
    [4]
    G.A. Snook, P. Kao, A.S. Best, Journal of Power Sources 196 (2011) 1-12.
    [5]
    K. Zhang, L.L. Zhang, X.S. Zhao, J. Wu, Chemistry of Materials 22 (2010) 1392-1401.
    [6]
    P. Simon, Y. Gogotsi, Nature Materials 7 (2008) 845-854.
    [7]
    J.R. Miller, P. Simon, Science 321 (2008) 651-652.
    [8]
    B. Ding, D. Guo, Y. Wang, X. Wu, Z. Fan, Journal of Power Sources 398 (2018) 113-119.
    [9]
    Z. Yanwu, M. Shanthi, M.D. Stoller, K.J. Ganesh, C. Weiwei, P.J. Ferreira, P. Adam, R.M. Wallace, K.A. Cychosz, T. Matthias, Science 332 (2011) 1537-1541.
    [10]
    Y. Sun, Q. Wu, G. Shi, Energy & Environmental Science 4 (2011) 1113-1132.
    [11]
    Y. Huang, W. Chen, H. Li, M. Zhu, F. Liu, Q. Xue, Z. Pei, Z. Wang, L. Wang, Y. Huang, Green Energy & Environment 3 (2018) 86-96.
    [12]
    J. Kim, L.J. Cote, J. Huang, Accounts of Chemical Research 45 (2012) 1356-1364.
    [13]
    C. Cheng, D. Li, Advanced Materials 25 (2013) 13-30.
    [14]
    C. Liu, Z. Yu, D. Neff, A. Zhamu, B.Z. Jang, Nano Letters 10 (2010) 4863-4868.
    [15]
    F. Liu, S. Song, D. Xue, H. Zhang, Advanced Materials 24 (2012) 1089-1094.
    [16]
    Z. Niu, J. Chen, H.H. Hng, J. Ma, X. Chen, Advanced Materials 24 (2012) 4144-4150.
    [17]
    J.J. Yoo, K. Balakrishnan, J. Huang, V. Meunier, B.G. Sumpter, A. Srivastava, M. Conway, A.L.M. Reddy, J. Yu, R. Vajtai, Nano Letters 11 (2011) 1423-1427.
    [18]
    Y. Yoon, K. Lee, S. Kwon, S. Seo, H. Yoo, S. Kim, Y. Shin, Y. Park, D. Kim, J.Y. Choi, Acs Nano 8 (2014) 4580-4590.
    [19]
    Q. Shao, T. Jie, Y. Lin, L. Jing, F. Qin, J. Yuan, L.C. Qin, Journal of Power Sources 278 (2015) 751-759.
    [20]
    Y. Xu, K. Sheng, C. Li, G. Shi, Acs Nano 4 (2010) 4324-4330.
    [21]
    W. Zhang, C. Xu, C. Ma, G. Li, Y. Wang, K. Zhang, F. Li, C. Liu, H.M. Cheng, Y. Du, Advanced Materials 29 (2017) 1701677.
    [22]
    L. Yan, J. Yu, J. Houston, N. Flores, H. Luo, Green Energy & Environment 2 (2017) 84-99.
    [23]
    C. Long, D. Qi, T. Wei, J. Yan, L. Jiang, Z. Fan, Advanced Functional Materials 24 (2014) 3953-3961.
    [24]
    X. Yu, H.S. Park, Carbon 77 (2014) 59-65.
    [25]
    J. Han, L.L. Zhang, S. Lee, J. Oh, K.S. Lee, J.R. Potts, J. Ji, X. Zhao, R.S. Ruoff, S. Park, Acs Nano 7 (2013) 19-26.
    [26]
    L.F. Chen, Z.H. Huang, H.W. Liang, H.L. Gao, S.H. Yu, Advanced Functional Materials 24 (2015) 5104-5111.
    [27]
    P.F. Fulvio, J.S. Lee, R.T. Mayes, X. Wang, S.M. Mahurin, S. Dai, Physical Chemistry Chemical Physics Pccp 13 (2011) 13486-13491.
    [28]
    S. Wang, E. Iyyamperumal, A. Roy, Y. Xue, D. Yu, L. Dai, Angewandte Chemie International Edition 50 (2011) 11756-11760.
    [29]
    D. Hulicova-Jurcakova, M. Seredych, G.Q. Lu, N.K. Kodiweera, P.E. Stallworth, S. Greenbaum, T.J. Bandosz, Carbon 47 (2009) 1576-1584.
    [30]
    X. Yu, Y. Kang, H.S. Park, Carbon 101 (2016) 49-56.
    [31]
    N. Phattharasupakun, J. Wutthiprom, N. Ma, P. Suktha, M. Sawangphruk, Journal of the Electrochemical Society 165 (2018) A1430-A1439.
    [32]
    X.L. Su, L. Fu, M.Y. Cheng, J.H. Yang, X.X. Guan, X.C. Zheng, Applied Surface Science 426 (2017) 924-932.
    [33]
    Z. Cheng, D. Yida, H. Wenbin, Q. Jinli, Z. Lei, Z. Jiujun, Chemical Society Reviews 44 (2015) 7484-7539.
    [34]
    Y. Shao, M.F. El-Kady, J. Sun, Y. Li, Q. Zhang, M. Zhu, H. Wang, B. Dunn, R.B. Kaner, Chemical Reviews 118 (2018) 9233-9280.
    [35]
    S. Pohlmann, C. Ramirez-Castro, A. Balducci, Journal of The Electrochemical Society 162 (2015) A5020-A5030.
    [36]
    M. Watanabe, M.L. Thomas, S. Zhang, K. Ueno, T. Yasuda, K. Dokko, Chemical Reviews 117 (2017) 7190 -7239.
    [37]
    Z. Lu, Y. Chen, Z. Liu, A. Li, D. Sun, K. Zhuo, RSC Advances 8 (2018) 18966-18971.
    [38]
    C. Qing, H. Yue, H. Chuangang, C. Huhu, Z. Zhipan, S. Huibo, Q. Liangti, Physical Chemistry Chemical Physics 16 (2014) 19307-19313.
    [39]
    M. Armand, F. Endres, D.R. Macfarlane, H. Ohno, B. Scrosati, Nature Materials 8 (2009) 621-629.
    [40]
    T. Wang, L.X. Wang, D.L. Wu, W. Xia, D.Z. Jia, Scientific Reports 5 (2015) 9591.
    [41]
    L. Cheng, Y. Hu, D. Qiao, Y. Zhu, H. Wang, Z. Jiao, Electrochimica Acta 259 (2018) 587-597.
    [42]
    H.L. Poh, P. Simek, Z. Sofer, M. Pumera, ACS Nano 6 (2013) 5262-5272.
    [43]
    E. Bi, H. Chen, X. Yang, W. Peng, M. Gratzel, L. Han, Energy & Environmental Science 7 (2014) 2637-2641.
    [44]
    Y. Li, G. Wang, T. Wei, Z. Fan, P. Yan, Nano Energy 19 (2016) 165-175.
    [45]
    M.-C. Hsiao, S.-H. Liao, M.-Y. Yen, P.-I. Liu, N.-W. Pu, C.-A. Wang, C.-C.M. Ma, ACS Applied Materials & Interfaces 2 (2010) 3092-3099.
    [46]
    H. Su, H. Zhang, F. Liu, F. Chun, B. Zhang, X. Chu, H. Huang, W. Deng, B. Gu, H. Zhang, Chemical Engineering Journal (2017) 73-81.
    [47]
    Z. Long, Y. Xi, Z. Fan, L. Guankui, Z. Tengfei, L. Kai, Z. Yawei, H. Yi, M. Yanfeng, Z. Mingtao, Journal of the American Chemical Society 135 (2013) 5921-5929.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (181) PDF downloads(27) Cited by()
    Proportional views

    Publish With GEE

    Contact

    • Email：gee@ipe.ac.cn
    • Tel：010-82627075
    • Address：North 2nd street, Zhongguancun, Haidian District, Beijing, China

    Links

    京ICP备10002620号-1京公网安备 11010802039050号

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return