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Hao Qin, Xutao Hu, Jingwen Wang, Hongye Cheng, Lifang Chen, Zhiwen Qi. Overview of acidic deep eutectic solvents on synthesis, properties and applications. Green Energy&Environment, 2020, 5(1): 8-21. doi: 10.1016/j.gee.2019.03.002
Citation: Hao Qin, Xutao Hu, Jingwen Wang, Hongye Cheng, Lifang Chen, Zhiwen Qi. Overview of acidic deep eutectic solvents on synthesis, properties and applications. Green Energy&Environment, 2020, 5(1): 8-21. doi: 10.1016/j.gee.2019.03.002
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Overview of acidic deep eutectic solvents on synthesis, properties and applications

doi: 10.1016/j.gee.2019.03.002

  • Max Planck Partner Group at the State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China

More Information
  • Corresponding author: E-mail address: lchen@ecust.edu.cn (Lifang Chen); E-mail address: zwqi@ecust.edu.cn (Zhiwen Qi)
  • Received date 12 December 2018, Accepted date 11 March 2019, RevRecd date 31 January 2019, Available online 19 March 2019, Publish date 31 January 2020,
    Abstract
  • This review divides the acidic deep eutectic solvents (ADES) into Brønsted and Lewis DES according to their diversity of acidic character. The hydrogen bond donors and halide salts for formulating an ADES are classified, the synthesis methods are described, and the physicochemical properties including freezing point, acidity, density, viscosity and conductivity are presented. Furthermore, the applications of Brønsted acidic deep eutectic solvents (BADES) and Lewis acidic deep eutectic solvents (LADES) are overviewed, respectively, covering the fields in dissolution, extraction, organic reaction and metal electrodeposition. It is expected that the ADES has great potential to replace the pollutional mineral acid, expensive and unstable solid acid, and costly ionic liquid in many acid-employed chemical processes, thus meeting the demands of green chemistry.

     

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