Volume 4 Issue 4
. 
Turn off MathJax
Article Contents
Article Navigation >  Green Energy&Environment  > 2019  >  4(4): 382-390
Xiaolan Deng, Yuqi Jiang, Zengxi Wei, Minglei Mao, Ramyakrishna Pothu, Hongxia Wang, Caiyun Wang, Jinping Liu, Jianmin Ma. Flexible quasi-solid-state dual-ion asymmetric supercapacitor based on Ni(OH)2 and Nb2O5 nanosheet arrays. Green Energy&Environment, 2019, 4(4): 382-390. doi: 10.1016/j.gee.2019.02.001
Citation: Xiaolan Deng, Yuqi Jiang, Zengxi Wei, Minglei Mao, Ramyakrishna Pothu, Hongxia Wang, Caiyun Wang, Jinping Liu, Jianmin Ma. Flexible quasi-solid-state dual-ion asymmetric supercapacitor based on Ni(OH)2 and Nb2O5 nanosheet arrays. Green Energy&Environment, 2019, 4(4): 382-390. doi: 10.1016/j.gee.2019.02.001
shu

Flexible quasi-solid-state dual-ion asymmetric supercapacitor based on Ni(OH)2 and Nb2O5 nanosheet arrays

doi: 10.1016/j.gee.2019.02.001
  • a.

    School of Physics and Electronics, Hunan University, Changsha, 410082, China

  • b.

    School of Chemistry Chemical Engineering and Life Science, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China

  • c.

    School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology, Brisbane, QLD, 4001, Australia

  • d.

    ARC Centre of Excellence for Electromaterials Science, Intelligent Polymer Research Institute, AIIM, Innovation Campus, University of Wollongong, North Wollongong, NSW, Australia

  • e.

    Key Laboratory of Materials Processing and Mold (Zhengzhou University), Ministry of Education, Zhengzhou University, Zhengzhou, 450002, China

More Information
  • Corresponding author: E-mail address: liujp@whut.edu.cn (Jinping Liu); E-mail address: nanoelechem@hnu.edu.cn (Jianmin Ma)
  • Received date 26 December 2018, Accepted date 13 February 2019, RevRecd date 21 January 2019, Available online 20 February 2019, Publish date 31 October 2019,
    Abstract
  • Increasing the energy density, power density as well as widening the operation voltage are essential to electrochemical capacitors to meet the practical energy demands. Herein, a novel flexible quasi-solid-state dual-ion asymmetric supercapacitor (ASC) with Ni(OH)2 and Nb2O5 nanosheets directly grown on stainless steel mesh is developed. In the dual-ion ASC, Nb2O5 negative and Ni(OH)2 positive electrodes react with Li+ and OH− respectively in alkaline gel electrolyte to store energy, which is quite different from conventional alkali metal ion SCs and alkaline SCs. The as-assembled flexible device has an extended working voltage of 1.7 V and delivers a capacity of 5.37 mAh cm−2, a maximum energy density and power density of 0.52 mWh cm−3 and 170 mW cm−3, respectively. The device maintains around 60% capacity retention after long cycling up to 1000 cycles. Moreover, our device can light up a LED light efficiently upon fast charging. The proposed quasi-solid-state dual-ion ASC has potential applications in future portable electronics and flexible energy storage devices.

     

    • X. Deng and Y. Jiang contribute equally to this manuscript.
    FullText(HTML)
  • loading
    • References(55)
  • [1]
    J.D.Huang, Z.X.Wei, J.Q.Liao, et al. J. Energy Chem., 33 (2019),pp. 110-124
    [2]
    Z.X.Tai, Y.J.Liu, Q.Zhang, et al. Green Energy Environ., 2 (2017),pp. 278-284
    [3]
    Y.Han, Y.Ge, Y.F.Chao, et al. J. Energy Chem., 27 (2018),pp. 57-72
    [4]
    S.H.Zheng, Z.-S.Wu, S.Wang, et al. Energy Storage Mater., 6 (2017),pp. 70-97
    [5]
    L.Li, S.Peng, H.B.Wu, et al. Adv. Energy Mater., 5 (2015),p. 1500753
    [6]
    C.Zhou, Y.Zhang, Y.Li, et al. Nano Lett., 13 (2013),pp. 2078-2085
    [7]
    Y.Li, F.Tang, R.Wang, et al. ACS Appl. Mater. Interfaces, 8 (2016),pp. 30232-30238
    [8]
    J.Liu, L.Zhang, H.B.Wu, et al. Energy Environ. Sci., 7 (2014),pp. 3709-3719
    [9]
    X.Lu, M.Yu, T.Zhai, et al. Nano Lett., 13 (2013),pp. 2628-2633
    [10]
    C.Zhao, W.Zheng Front. Energy Res., 3 (2015),pp. 23-33
    [11]
    N.S.Palani, N.S.Kavitha, K.S.Venkatesh, et al. J. Solid State Electrochem., 22 (2018),pp. 3273-3287
    [12]
    Z.Q.Sun, H.M.Lin, F.Zhang, et al. J. Mater. Chem. A, 6 (2018),pp. 14956-14966
    [13]
    J.Zhao, H.Yang, C.Li, et al. Nano Energy, 45 (2018),pp. 420-431
    [14]
    Z.Zhou, Q.Zhang, J.Sun, et al. ACS Nano, 12 (2018),pp. 9333-9341
    [15]
    X.Y.He, R.M.Li, J.Y.Liu, et al. Chem. Eng. J., 334 (2018),pp. 1573-1583
    [16]
    Y.H.Zhao, X.Y.He, R.Chen, et al. Appl. Surf. Sci., 453 (2018),pp. 73-82
    [17]
    J.-X.Feng, S.-H.Ye, X.-F.Lu, et al. ACS Appl. Mater. Interfaces, 7 (2015),pp. 11444-11451
    [18]
    C.Guan, J.Liu, C.Cheng, et al. Energy Environ. Sci., 4 (2011),pp. 4496-4499
    [19]
    P.Yang, Y.Ding, Z.Lin, et al. Nano Lett., 14 (2014),pp. 731-736
    [20]
    J.Chang, M.Jin, F.Yao, et al. Adv. Funct. Mater., 23 (2013),pp. 5074-5083
    [21]
    R.R.Salunkhe, J.Tang, Y.Kamachi, et al. ACS Nano, 9 (2015),pp. 6288-6296
    [22]
    J.Huang, P.Xu, D.Cao, et al. J. Power Sources, 246 (2014),pp. 371-376
    [23]
    G.Sun, X.Zhang, R.Lin, et al. Angew. Chem. Int. Ed., 54 (2015),pp. 4651-4656
    [24]
    D.Zhang, M.Miao, H.Niu, et al. ACS Nano, 8 (2014),pp. 4571-4579
    [25]
    X.Lu, Y.Zeng, M.Yu, et al. Adv. Mater., 26 (2014),pp. 3148-3155
    [26]
    L.Kong, C.Zhang, S.Zhang, et al. J. Mater. Chem. A, 2 (2014),pp. 17962-17970
    [27]
    X.Wang, G.Li, R.Tjandra, et al. RSC Adv., 5 (2015),pp. 41179-41185
    [28]
    L.Wang, B.Y.Ruan, J.T.Xu, et al. RSC Adv., 5 (2015),pp. 36104-36107
    [29]
    Y.Cai, X.Li, L.Wang, et al. J. Mater. Chem. A, 3 (2015),pp. 1396-1399
    [30]
    H.Song, J.Fu, K.Ding, et al. J. Power Sources, 328 (2016),pp. 599-606
    [31]
    P.Qin, X.X.Li, B.Gao, et al. Nanoscale, 10 (2018),pp. 8728-8734
    [32]
    J.Ni, W.Wang, C.Wu, et al. Adv. Mater., 29 (2017),pp. 1605607-1605612
    [33]
    L.C.Wu, Y.J.Chen, M.L.Mao, et al. ACS Appl. Mater. Interfaces, 6 (2014),pp. 5168-5174
    [34]
    Z.Su, C.Yang, C.Xu, et al. J. Mater. Chem. A, 1 (2013),pp. 12432-12440
    [35]
    J.Liu, C.Guan, C.Zhou, et al. Adv. Mater., 28 (2016),pp. 8732-8739
    [36]
    J.S.Chen, J.Ren, M.Shalom, et al. ACS Appl. Mater. Interfaces, 8 (2016),pp. 5509-5516
    [37]
    M.L.Mao, C.Y.Cui, M.G.Wu, et al. Nano Energy, 45 (2018),pp. 346-352
    [38]
    J.J.Liang, C.C.Yuan, H.H.Li, et al. Nano-Micro Lett., 10 (2018),pp. 21-29
    [39]
    S.-Q.Guo, X.Zhang, Z.Zhou, et al. J. Mater. Chem. A, 2 (2014),pp. 9236-9243
    [40]
    C.Zhou, Y.Zhao, L.Shang, et al. Chem. Commun., 50 (2014),pp. 9554-9556
    [41]
    Y.-Z.Su, K.Xiao, N.Li, et al. J. Mater. Chem. A, 2 (2014),pp. 13845-13853
    [42]
    Y.Xi, G.Wei, J.Li, et al. Electrochim. Acta, 233 (2017),pp. 26-35
    [43]
    L.Kong, C.Zhang, J.Wang, et al. ACS Nano, 9 (2015),pp. 11200-11208
    [44]
    L.Kong, C.Zhang, J.Wang, et al. Sci. Rep., 6 (2016),p. 21177
    [45]
    S.Zhu, Z.Wang, F.Huang, et al. J. Mater. Chem. A, 5 (2017),pp. 9960-9969
    [46]
    H.Yan, J.Bai, M.Liao, et al. Eur. J. Inorg. Chem., 8 (2017),pp. 1143-1152
    [47]
    Z.Tang, C.h.Tang, H.Gong Adv. Funct. Mater., 22 (2012),pp. 1272-1278
    [48]
    J.Ji, L.L.Zhang, H.Ji, et al. ACS Nano, 7 (2013),pp. 6237-6243
    [49]
    X.Lu, M.Yu, G.Wang, et al. Adv. Mater., 25 (2013),pp. 267-272
    [50]
    W.Z.Long, Z.Zhu, J.Qiu, et al. J. Mater. Chem. C., 2 (2014),pp. 1331-1336
    [51]
    L.Wang, H.Yang, X.Liu, et al. Angew. Chem. Int. Ed., 56 (2017),pp. 1105-1110
    [52]
    S.Khalid, C.Cao, L.Wang, et al. RSC Adv., 6 (2016),pp. 70292-70302
    [53]
    J.Zhao, M.Zheng, Z.Run, et al. J. Power Sources, 285 (2015),pp. 385-392
    [54]
    X.Tang, R.Jia, T.Zhai, et al. ACS Appl. Mater. Interfaces, 7 (2015),pp. 27518-27525
    [55]
    R.Li, Y.Wang, C.Zhou, et al. Adv. Funct. Mater., 25 (2015),pp. 5384-5394
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (190) PDF downloads(13) Cited by()
    Proportional views

    Publish With GEE

    Contact

    • Email：gee@ipe.ac.cn
    • Tel：010-82627075
    • Address：North 2nd street, Zhongguancun, Haidian District, Beijing, China

    Links

    京ICP备10002620号-1京公网安备 11010802039050号

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return