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Article Navigation >  Green Energy&Environment  > 2019  >  4(2): 127-130
Kosuke Kuroda, Yumiko Shimada, Kenji Takahashi. Hand-holding and releasing between the anion and cation to change their macroscopic behavior in water. Green Energy&Environment, 2019, 4(2): 127-130. doi: 10.1016/j.gee.2018.12.004
Citation: Kosuke Kuroda, Yumiko Shimada, Kenji Takahashi. Hand-holding and releasing between the anion and cation to change their macroscopic behavior in water. Green Energy&Environment, 2019, 4(2): 127-130. doi: 10.1016/j.gee.2018.12.004
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Hand-holding and releasing between the anion and cation to change their macroscopic behavior in water

doi: 10.1016/j.gee.2018.12.004

  • Faculty of Biological Science and Technology, Institute of Science and Engineering, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan

More Information
  • Corresponding author: E-mail address: kkuroda@staff.kanazawa-u.ac.jp (Kosuke Kuroda)
  • Received date 30 November 2018, Accepted date 27 December 2018, Available online 08 January 2019, Publish date 30 April 2019,
    Abstract
  • Despite the similarity of ionic liquid and zwitterion, their some properties such as conductivity and hydrophobicity are different. Here we developed a novel phosphonium salt having a dynamic covalent bond between anion and cation, enabling reversible structural shift between free ion pair and zwitterion. With the phosphonium salt, control of the macroscopic phase behavior in aqueous solution, i.e. forming mono- or bi-phasic systems, upon exposure to an acid or base was reversibly achieved, based on the structural shift of the phosphonium salt. CO2/N2 bubbling reversibly changed the phase behavior as well as acid/base, leading to green separation systems.

     

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