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Article Navigation >  Green Energy&Environment  > 2019  >  4(3): 245-253
Huaifang Zhang, Jubing Zhang, Kunhao Liu, Yunqi Zhu, Xiaoyu Qiu, Dongmei Sun, Yawen Tang. Construction of highly-stable graphene hollow nanospheres and their application in supporting Pt as effective catalysts for oxygen reduction reaction. Green Energy&Environment, 2019, 4(3): 245-253. doi: 10.1016/j.gee.2018.12.002
Citation: Huaifang Zhang, Jubing Zhang, Kunhao Liu, Yunqi Zhu, Xiaoyu Qiu, Dongmei Sun, Yawen Tang. Construction of highly-stable graphene hollow nanospheres and their application in supporting Pt as effective catalysts for oxygen reduction reaction. Green Energy&Environment, 2019, 4(3): 245-253. doi: 10.1016/j.gee.2018.12.002
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Construction of highly-stable graphene hollow nanospheres and their application in supporting Pt as effective catalysts for oxygen reduction reaction

doi: 10.1016/j.gee.2018.12.002

  • Jiangsu Key Laboratory of New Power Batteries, Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023, China

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  • Corresponding author: E-mail address: qxy18251813615@163.com (Xiaoyu Qiu); E-mail address: tangyawen@njnu.edu.cn (Yawen Tang)
  • Received date 29 October 2018, Accepted date 24 December 2018, RevRecd date 21 December 2018, Available online 29 December 2018, Publish date 31 July 2019,
    Abstract
  • The construction and surface modification of three-dimensional (3D) graphene structures have been recognized as effective ways to prepare high-performance graphene-based composites in energy-related applications. Herein, on the basis of well-defined morphology and efficient electron conduction, the 3D highly-stable graphene hollow nanospheres have been synthesized by using sacrificial template method. The as-prepared 3D graphene nanospheres exhibit superior mechanical stability, electrochemical stability, and strong hydrophobicity, which may accelerate the emission of H2O in acidic medium-based ORR. Accordingly, the 3D highly-stable graphene nanospheres are used to confine tiny Pt nanoparticles (3D r-GO@Pt HNSs) for ORR in acidic medium, exhibiting superior activity with 4-electron-transfered pathway. Meanwhile, dramatically improved durability are achieved in terms of both ORR mass activity and electrochemically surface area compared to those of commercial Pt/C.

     

    • Huaifang Zhang and Jubing Zhang contributed equally to this work.
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