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Article Navigation >  Green Energy&Environment  > 2019  >  4(2): 146-153
Zheng Ma, Maria Forsyth, Douglas R. MacFarlane, Mega Kar. Ionic liquid/tetraglyme hybrid Mg[TFSI]2 electrolytes for rechargeable Mg batteries. Green Energy&Environment, 2019, 4(2): 146-153. doi: 10.1016/j.gee.2018.10.003
Citation: Zheng Ma, Maria Forsyth, Douglas R. MacFarlane, Mega Kar. Ionic liquid/tetraglyme hybrid Mg[TFSI]2 electrolytes for rechargeable Mg batteries. Green Energy&Environment, 2019, 4(2): 146-153. doi: 10.1016/j.gee.2018.10.003
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Ionic liquid/tetraglyme hybrid Mg[TFSI]2 electrolytes for rechargeable Mg batteries

doi: 10.1016/j.gee.2018.10.003
  • a.

    School of Chemistry, Faculty of Science, Monash University, VIC 3800, Australia

  • b.

    ARC Centre of Excellence for Electromaterials Science, IFM – Institute for Frontier Materials, Deakin University, Burwood VIC 3125, Australia

More Information
  • Corresponding author: E-mail address: mega.kar@monash.edu (Mega Kar)
  • Received date 10 September 2018, Accepted date 10 October 2018, Available online 17 October 2018, Publish date 30 April 2019,
    Abstract
  • The electrochemical reversibility of Mg in hybrid electrolytes based on mixtures of ionic liquid and glyme based organic solvents was investigated for applications in rechargeable magnesium batteries (RMBs). The electrolytes demonstrate reversible reduction and oxidation of Mg only after being pre-treated with the dehydrating agent, magnesium borohydride, Mg[BH4]2, highlighting the importance of removing water in Mg based electrolytes. The addition magnesium di[bis(trifluoromethanesulfonyl)imide] (Mg[TFSI]2) (0.3 M) to N-butyl-n-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide [C4mpyr][TFSI]/tetraglyme at a mole ratio of 1:2 showed stable CV cycling over almost 300 cycles while scanning electron microscopy (SEM) and X-ray diffraction (XRD) confirmed Mg deposition, showing non-dendritic morphology and a well-aligned growth. Further thermogravimetric analysis (TGA) demonstrated a mass retention of 79% at 250 °C for this electrolyte suggesting that the presence of the ionic liquid increases thermal stability substantially making these hybrid electrolytes compatible for RMBs.

     

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    • References(47)
  • [1]
    J.M.Tarascon, M.Armand Nature, 414 (2001),pp. 359-367
    [2]
    R.Zhang, C.Ling MRS Energy Sustain., 3 (2016),p. E1
    [3]
    D.Aurbach, Z.Lu, A.Schechter, et al. Nature, 407 (2000),pp. 724-727
    [4]
    Y.Viestfrid, M.D.Levi, Y.Gofer, et al. J. Electroanal. Chem., 576 (2005),pp. 183-195
    [5]
    O.Mizrahi, N.Amir, E.Pollak, et al. J. Electrochem. Soc., 155 (2008),pp. A103-A109
    [6]
    H.S.Kim, T.S.Arthur, G.D.Allred, et al. Nat. Commun., 2 (2011),p. 427
    [7]
    Q.S.Zhao, Y.N.Nuli, Y.S.Guo, et al. Electrochim. Acta, 56 (2011),pp. 6530-6535
    [8]
    R.Mohtadi, M.Matsui, T.S.Arthur, et al. Angew. Chem. Int. Ed., 51 (2012),pp. 9780-9783
    [9]
    C.J.Barile, E.C.Barile, K.R.Zavadil, et al. J. Phys. Chem. C, 118 (2014),pp. 27623-27630
    [10]
    O.Tutusaus, R.Mohtadi, T.S.Arthur, et al. Angew. Chem. Int. Ed., 54 (2015),pp. 7900-7904
    [11]
    Z.-B.Zhou, H.Matsumoto, K.Tatsumi Chem. Eur. J., 12 (2006),pp. 2196-2212
    [12]
    G.B.Appetecchi, M.Montanino, A.Balducci, et al. J. Power Sources, 192 (2009),pp. 599-605
    [13]
    D.R.Macfarlane, M.Forsyth, P.Howlett, et al. Nat. Rev. Mater., 1 (2016),p. 15005
    [14]
    T.Watkins, A.Kumar, D.A.Buttry J. Am. Chem. Soc., 38 (2015),pp. 641-650
    [15]
    M.Kar, Z.Ma, L.M.Azofra, et al. Chem. Commun., 52 (2016),pp. 4033-4036
    [16]
    Z.Ma, M.Kar, C.Xiao, et al. Electrochem. Commun., 78 (2017),pp. 29-32
    [17]
    I.Shterenberg, M.Salama, Y.Gofer, et al. MRS Bull., 39 (2014),pp. 453-460
    [18]
    G.T.Cheek, W.E.O'grady, S.Z.El Abedin, et al. J. Electrochem. Soc., 155 (2008),pp. D91-D95
    [19]
    Y.Nuli, J.Yang, R.Wu Electrochem. Commun., 7 (2005),pp. 1105-1110
    [20]
    N.Amir, Y.Vestfrid, O.Chusid, et al. J. Power Sources, 174 (2007),pp. 1234-1240
    [21]
    G.Vardar, A.E.S.Sleightholme, J.Naruse, et al. ACS Appl. Mater. Interf., 6 (2014),pp. 18033-18039
    [22]
    A.Kitada, Y.Kang, Y.Uchimoto, et al. J. Electrochem. Soc., 161 (2014),pp. D102-D106
    [23]
    A.Kitada, Y.Kang, K.Matsumoto, et al. J. Electrochem. Soc., 162 (2015),pp. D389-D396
    [24]
    M.M.Huie, C.A.Cama, P.F.Smith, et al. Electrochim. Acta, 219 (2016),pp. 267-276
    [25]
    L.Xue, D.D.Desmarteau, W.T.Pennington Solid State Sci., 7 (2005),pp. 311-318
    [26]
    S.Terada, T.Mandai, S.Suzuki, et al. J. Phys. Chem. C, 120 (2016),pp. 1353-1365
    [27]
    I.Shterenberg, M.Salama, H.D.Yoo, et al. J. Electrochem. Soc., 162 (2015),pp. A7118-A7128
    [28]
    K.Shimokawa, H.Matsumoto, T.Ichitsubo J. Phys. Chem. Lett., 9 (2018),pp. 4732-4737
    [29]
    S.Hebié, F.Alloin, C.Iojoiu, et al. ACS Appl. Mater. Interf., 10 (2018),pp. 5527-5533
    [30]
    B.Lee, J.-H.Cho, H.R.Seo, et al. J. Mater. Chem. A, 6 (2018),pp. 3126-3133
    [31]
    L.Zhou, Q.Liu, Z.Zhang, et al. Adv. Mater., 30 (2018),p. 1801984
    [32]
    S.-B.Son, T.Gao, S.P.Harvey, et al. Nat. Chem., 10 (2018),pp. 532-539
    [33]
    H.Yoon, H.Zhu, A.Hervault, et al. Phys. Chem. Chem. Phys., 16 (2014),pp. 12350-12355
    [34]
    S.Theivaprakasam, D.R.Macfarlane, S.Mitra Electrochim. Acta, 180 (2015),pp. 737-745
    [35]
    D.R.Macfarlane, P.Meakin, J.Sun, et al. J. Phys. Chem. B, 103 (1999),pp. 4164-4170
    [36]
    S.Randström, G.B.Appetecchi, C.Lagergren, et al. Electrochim. Acta, 53 (2007),pp. 1837-1842
    [37]
    A.I.Bhatt, A.S.Best, J.Huang, et al. J. Electrochem. Soc., 157 (2010),pp. A66-A74
    [38]
    C.Liao, N.Sa, B.Key, et al. J. Mater. Chem. A, 3 (2015),pp. 6082-6087
    [39]
    M.Kar, B.Winther-Jensen, M.Forsyth, et al. Phys. Chem. Chem. Phys., 15 (2013),pp. 7191-7197
    [40]
    J.J.Fillion, J.E.Bennett, J.F.Brennecke J. Chem. Eng., 62 (2017),pp. 608-622
    [41]
    D.R.Macfarlane, M.Kar, J.M.Pringle
    [42]
    J.Wang, Y.Yamada, K.Sodeyama, et al. Nat. Commun., 7 (2016),p. 12032
    [43]
    D.Macfarlane, A.L.Chong, M.Forsyth, et al. Faraday Discuss., 206 (2018),pp. 9-28
    [44]
    O.Aschenbrenner, S.Supasitmongkol, M.Taylor, et al. Green Chem., 11 (2009),pp. 1217-1221
    [45]
    M.Matsui J. Power Sources, 196 (2011),pp. 7048-7055
    [46]
    J.G.Connell, B.Genorio, P.P.Lopes, et al. Chem. Mater., 28 (2016),pp. 8268-8277
    [47]
    C.Ling, D.Banerjee, M.Matsui Electrochim. Acta, 76 (2012),pp. 270-274
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