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Article Navigation >  Green Energy&Environment  > 2020  >  5(1): 105-113
Jianguo Qian, Ruiyi Yan, Xiaomin Liu, Chunshan Li, Xiangping Zhang. Modification to solution-diffusion model for performance prediction of nanofiltration of long-alkyl-chain ionic liquids aqueous solutions based on ion cluster. Green Energy&Environment, 2020, 5(1): 105-113. doi: 10.1016/j.gee.2018.10.001
Citation: Jianguo Qian, Ruiyi Yan, Xiaomin Liu, Chunshan Li, Xiangping Zhang. Modification to solution-diffusion model for performance prediction of nanofiltration of long-alkyl-chain ionic liquids aqueous solutions based on ion cluster. Green Energy&Environment, 2020, 5(1): 105-113. doi: 10.1016/j.gee.2018.10.001
shu

Modification to solution-diffusion model for performance prediction of nanofiltration of long-alkyl-chain ionic liquids aqueous solutions based on ion cluster

doi: 10.1016/j.gee.2018.10.001
  • a.

    Key Laboratory of Green Process and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

  • b.

    College of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China

More Information
  • Corresponding author: E-mail address: csli@ipe.ac.cn (Chunshan Li); E-mail address: xpzhang@ipe.ac.cn (Xiangping Zhang)
  • Received date 05 September 2018, Accepted date 08 October 2018, RevRecd date 29 September 2018, Available online 16 October 2018, Publish date 31 January 2020,
    Abstract
  • Mathematical modeling for nanofiltration of ionic liquids (ILs) solutions could assist to understand transfer mechanism and predict experimental values. In this work, modeling by solution-diffusion model for nanofiltration of long-alkyl-chain ILs aqueous solutions was proposed. Molecular simulations were performed to validate the existence of ion cluster in long-alkyl-chain ILs aqueous solution. Based on the results of simulations, parameters used in the solution-diffusion model were modified, such as concentration of ILs and diameter of ion cluster. The modeling process was developed for three long-alkyl-chain ILs aqueous solutions with different concentrations (1-alkyl-3-methylimidazolium chloride: [C 6mim]Cl, [C8mim]Cl, [C10mim]Cl). The calculated values obtained from modified solution-diffusion model could well match the experimental values.

     

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