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Article Navigation >  Green Energy&Environment  > 2018  >  3(4): 368-374
Shaoyu Yuan, Penglei Cui, Yunrui Zhang, Hong Zhang, Li Huo, Yongjun Gao. Popping of g-C3N4 mixed with cupric nitrate: Facile synthesis of Cu-based catalyst for construction of CN bond. Green Energy&Environment, 2018, 3(4): 368-374. doi: 10.1016/j.gee.2018.08.003
Citation: Shaoyu Yuan, Penglei Cui, Yunrui Zhang, Hong Zhang, Li Huo, Yongjun Gao. Popping of g-C3N4 mixed with cupric nitrate: Facile synthesis of Cu-based catalyst for construction of CN bond. Green Energy&Environment, 2018, 3(4): 368-374. doi: 10.1016/j.gee.2018.08.003
shu

Popping of g-C3N4 mixed with cupric nitrate: Facile synthesis of Cu-based catalyst for construction of CN bond

doi: 10.1016/j.gee.2018.08.003
  • a.

    College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China

  • b.

    College of Science, Agricultural University of Hebei, Baoding 071001, China

More Information
  • Corresponding author: E-mail address: zh820516@163.com (Hong Zhang); E-mail address: yjgao@hbu.edu.cn (Yongjun Gao)
  • Received date 10 June 2018, Accepted date 30 August 2018, RevRecd date 23 August 2018, Available online 07 September 2018, Publish date 31 October 2018,
    Abstract
  • A novel strategy to synthesize copper-based nanoparticles supported on carbon nitride (C3N4) was developed by popping of mixture containing C3N4 and cupric nitrate. Characterizations such as X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) indicate that the structure of g-C3N4 maintained although a popping process occurred. High resolution transmission electronic microscopy (HRTEM) characterization illustrated that copper-based nanoparticles with diameter of < 1 nm were well distributed on g-C 3N4. This kind of copper catalyst exhibits high catalytic activity and selectivity in arylation of pyrazole, a simple and effect strategy to construct CN bond in organic chemistry. According to the results of control experiments and characterizations, cuprous oxide should be the catalytic active phase in the supported coper-based catalyst.

     

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