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Article Navigation >  Green Energy&Environment  > 2018  >  3(4): 352-359
Chunjie Li, You Xu, Yinghao Li, Hongjie Yu, Shuli Yin, Hairong Xue, Xiaonian Li, Hongjing Wang, Liang Wang. Engineering porosity into trimetallic PtPdNi nanospheres for enhanced electrocatalytic oxygen reduction activity. Green Energy&Environment, 2018, 3(4): 352-359. doi: 10.1016/j.gee.2018.07.004
Citation: Chunjie Li, You Xu, Yinghao Li, Hongjie Yu, Shuli Yin, Hairong Xue, Xiaonian Li, Hongjing Wang, Liang Wang. Engineering porosity into trimetallic PtPdNi nanospheres for enhanced electrocatalytic oxygen reduction activity. Green Energy&Environment, 2018, 3(4): 352-359. doi: 10.1016/j.gee.2018.07.004
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Engineering porosity into trimetallic PtPdNi nanospheres for enhanced electrocatalytic oxygen reduction activity

doi: 10.1016/j.gee.2018.07.004

  • State Key Laboratory Breeding Base of Green-Chemical Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China

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  • Corresponding author: E-mail address: yxu@zjut.edu.cn (You Xu); E-mail address: hjw@zjut.edu.cn (Hongjing Wang); E-mail address: wangliang@zjut.edu.cn (Liang Wang)
  • Received date 06 June 2018, Accepted date 08 July 2018, RevRecd date 06 July 2018, Available online 14 August 2018, Publish date 31 October 2018,
    Abstract
  • Platinum (Pt)-based multi-metallic nanostructures show great promise as electrocatalysts for the oxygen reduction reaction (ORR) in fuel cell cathodes. Herein, we report a simple, one-step surfactant-directed synthetic strategy to directly synthesize tri-metallic PtPdNi mesoporous nanospheres (PtPdNi MNs) in a high yield. The synthesis could be accomplished in aqueous solution at mild reaction temperature (40 °C) without needing any organic solvent, yielding well-dispersed PtPdNi MNs with uniform shape and narrow size distribution. Benefitting from their unique mesoporous and highly open structure and tri-metallic composition, the as-synthesized PtPdNi MNs demonstrate superior catalytic activity and stability for ORR in acidic solution in comparison with PtPdNi nanodendrites (PtPdNi NDs), PtPd MNs and commercial Pt/C catalyst. The present approach may open a reliable path to the design of advanced electrocatalysts with desired performance.

     

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    • References(41)
  • [1]
    I.E.L.Stephens, J.Rossmeisl, I.Chorkendorff Science, 354 (2016),pp. 1378-1379
    [2]
    B.Cai, S.Henning, J.Herranz, et al. Adv. Energy Mater., 7 (2017),p. 1700548
    [3]
    M.Li, Z.Zhao, T.Cheng, et al. Science, 354 (2016),pp. 1414-1419
    [4]
    Y.Nie, L.Li, Z.Wei Chem. Soc. Rev., 44 (2015),pp. 2168-2201
    [5]
    G.-R.Xu, C.-C.Han, Y.-Y.Zhu, et al. Adv. Mater. Interfaces, 5 (2018),p. 1701322
    [6]
    Q.Xue, G.Xu, R.Mao, et al. J. Energy Chem., 26 (2017),pp. 1153-1159
    [7]
    L.Bu, N.Zhang, S.Guo, et al. Science, 354 (2016),pp. 1410-1414
    [8]
    K.Jiang, D.Zhao, S.Guo, et al. Sci. Adv., 3 (2017)
    [9]
    M.Shao, Q.Chang, J.P.Dodelet, et al. Chem. Rev., 116 (2016),pp. 3594-3657
    [10]
    G.-R.Xu, B.Wang, J.-Y.Zhu, et al. ACS Catal., 6 (2016),pp. 5260-5267
    [11]
    Z.W.Seh, J.Kibsgaard, C.F.Dickens, et al. Science, 355 (2017)
    [12]
    M.Escudero-Escribano, P.Malacrida, M.H.Hansen, et al. Science, 352 (2016),pp. 73-76
    [13]
    S.Guo, S.Zhang, S.Sun Angew. Chem. Int. Ed., 52 (2013),pp. 8526-8544
    [14]
    Y.Jiao, Y.Zheng, M.Jaroniec, et al. Chem. Soc. Rev., 44 (2015),pp. 2060-2086
    [15]
    G.-R.Xu, S.-H.Han, Z.-H.Liu, et al. J. Power Sources, 306 (2016),pp. 587-592
    [16]
    Y.Xu, B.Zhang Chem. Soc. Rev., 43 (2014),pp. 2439-2450
    [17]
    C.Zhu, D.Du, A.Eychmuller, et al. Chem. Rev., 115 (2015),pp. 8896-8943
    [18]
    V.Malgras, H.Ataee-Esfahani, H.Wang, et al. Adv. Mater., 28 (2016),pp. 993-1010
    [19]
    H.Duan, C.Xu Electrochim. Acta, 152 (2015),pp. 417-424
    [20]
    Y.Zhang, L.Zhao, J.Walton, et al. Int. J. Hydrogen Energy, 42 (2017),pp. 17112-17121
    [21]
    K.Cai, J.Liu, H.Zhang, et al. Chem. Eur J., 21 (2015),pp. 7556-7561
    [22]
    P.Song, L.-P.Mei, A.-J.Wang, et al. Int. J. Hydrogen Energy, 41 (2016),pp. 1645-1653
    [23]
    A.-J.Wang, L.Liu, X.-X.Lin, et al. Electrochim. Acta, 245 (2017),pp. 883-892
    [24]
    X.Yang, L.T.Roling, M.Vara, et al. Nano Lett., 16 (2016),pp. 6644-6649
    [25]
    M.Luo, Y.Sun, X.Zhang, et al. Adv. Mater., 30 (2018),p. 1705515
    [26]
    D.Y.Chung, S.W.Jun, G.Yoon, et al. J. Am. Chem. Soc., 137 (2015),pp. 15478-15485
    [27]
    X.Zhao, S.Chen, Z.Fang, et al. J. Am. Chem. Soc., 137 (2015),pp. 2804-2807
    [28]
    X.Huang, Z.Zhao, L.Cao, et al. Science, 348 (2015),pp. 1230-1234
    [29]
    V.Beermann, M.Gocyla, S.Kuhl, et al. J. Am. Chem. Soc., 139 (2017),pp. 16536-16547
    [30]
    D.Wang, H.L.Xin, R.Hovden, et al. Nat. Mater., 12 (2012),p. 81
    [31]
    E.Pizzutilo, J.Knossalla, S.Geiger, et al. Adv. Energy Mater., 7 (2017),p. 1700835
    [32]
    Z.Zhang, Z.Luo, B.Chen, et al. Adv. Mater., 28 (2016),pp. 8712-8717
    [33]
    B.-A.Lu, T.Sheng, N.Tian, et al. Nano Energy, 33 (2017),pp. 65-71
    [34]
    J.Lai, S.Guo Small, 13 (2017),p. 1702156
    [35]
    J.Li, H.-M.Yin, X.-B.Li, et al. Nat. Energy, 2 (2017),p. 17111
    [36]
    H.Zhu, S.Zhang, S.Guo, et al. J. Am. Chem. Soc., 135 (2013),pp. 7130-7133
    [37]
    Y.W.Lee, M.Im, J.W.Hong, et al. ACS Appl. Mater. Interfaces, 9 (2017),pp. 44018-44026
    [38]
    J.Park, M.Kanti Kabiraz, H.Kwon, et al. ACS Nano, 11 (2017),pp. 10844-10851
    [39]
    M.Lokanathan, I.M.Patil, M.Navaneethan, et al. Nano Energy, 43 (2018),pp. 219-227
    [40]
    B.Jiang, C.Li, M.Imura, et al. Adv. Sci., 2 (2015),p. 1500112
    [41]
    B.Jiang, C.Li, V.Malgras, et al. J. Mater. Chem. A, 3 (2015),pp. 18053-18058
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