Volume 4 Issue 1
. 
Turn off MathJax
Article Contents
Article Navigation >  Green Energy&Environment  > 2019  >  4(1): 49-55
Wei Hui, Yan Zhou, Yan Dong, Zhi-Jun Cao, Fei-Qiang He, Min-Zhong Cai, Duan-Jian Tao. Efficient hydrolysis of hemicellulose to furfural by novel superacid SO4H-functionalized ionic liquids. Green Energy&Environment, 2019, 4(1): 49-55. doi: 10.1016/j.gee.2018.06.002
Citation: Wei Hui, Yan Zhou, Yan Dong, Zhi-Jun Cao, Fei-Qiang He, Min-Zhong Cai, Duan-Jian Tao. Efficient hydrolysis of hemicellulose to furfural by novel superacid SO4H-functionalized ionic liquids. Green Energy&Environment, 2019, 4(1): 49-55. doi: 10.1016/j.gee.2018.06.002
shu

Efficient hydrolysis of hemicellulose to furfural by novel superacid SO4H-functionalized ionic liquids

doi: 10.1016/j.gee.2018.06.002

  • College of Chemistry and Chemical Engineering, Institute of Advanced Materials, Jiangxi Normal University, Nanchang, 330022, China

More Information
  • Corresponding author: E-mail address: djtao@jxnu.edu.cn (Duan-Jian Tao)
  • Received date 11 February 2018, Accepted date 27 June 2018, RevRecd date 20 June 2018, Available online 02 July 2018, Publish date 31 January 2019,
    Abstract
  • Novel superacid SO4H-functionalized ionic liquids (SFILs) were designed and prepared in this work. The catalytic activities of SFILs were evaluated in xylan hydrolysis and xylose dehydration to produce furfural. Combined with the results of acid strength of SFILs characterized by solid-state 31P MAS NMR, it was found that the catalytic performance of SFILs was positively correlated to their acid strength. The superacid SFIL [Ch-SO4H][CF3SO3] displayed the best catalytic performance with more than 80% yield of furfural, and it was also obviously superior to usual SO3H-functionalized acidic ILs, mineral liquid acids, and acidic resin Amberlyst-15 catalysts in catalytic activity under optimized conditions. In addition, the superacid SFIL [Ch-SO4H][CF3SO3] could be easily separated from reaction system and reused at least five times without obvious decrease.

     

    • These authors contributed equally to this work.
    FullText(HTML)
  • loading
    • References(39)
  • [1]
    G.W.Huber, S.Iborra, A.Corma Chem. Rev., 106 (2006),pp. 4044-4098
    [2]
    A.Corma, S.Iborra, A.Velty Chem. Rev., 107 (2007),pp. 2411-2502
    [3]
    P.Gallezot Chem. Soc. Rev., 41 (2012),pp. 1538-1558
    [4]
    M.Besson, P.Gallezot, C.Pinel Chem. Rev., 114 (2014),pp. 1827-1870
    [5]
    S.Van den Bosch, W.Schutyser, S.F.Koelewijn, et al. Chem. Commun., 51 (2015),pp. 13158-13161
    [6]
    L.S.Ribeiro, J.J.de Melo Órfão, M.F.R.Pereira Bioresour. Technol., 244 (2017),pp. 1173-1177
    [7]
    D.S.Naidu, S.P.Hlangothi, M.J.John Carbohydr. Polym., 179 (2018),pp. 28-41
    [8]
    M.Besson, P.Gallezot, C.Pinel Chem. Rev., 114 (2013),pp. 1827-1870
    [9]
    S.H.Zhu, Y.F.Xue, J.Guo, et al. ACS Catal., 6 (2016),pp. 2035-2042
    [10]
    M.B.Fusaro, V.Chagnault, D.Postel Carbohydr. Res., 409 (2015),pp. 9-19
    [11]
    B.Danon, G.Marcotullio, W.de Jong Green Chem., 16 (2014),pp. 39-54
    [12]
    P.L.Dhepe, R.Sahu Green Chem., 12 (2010),pp. 2153-2156
    [13]
    D.J.Tao, Y.Dong, Z.J.Cao, et al. J. Ind. Eng. Chem., 41 (2016),pp. 122-129
    [14]
    A.S.Amarasekara Chem. Rev., 116 (2016),pp. 6133-6183
    [15]
    S.Zhang, Y.Wang, H.He, et al. Green Energy Environ, 2 (2017),pp. 329-330
    [16]
    K.Dong, X.Liu, H.Dong, et al. Chem. Rev., 117 (2017),pp. 6636-6695
    [17]
    J.B.Binder, J.J.Blank, A.V.Cefali, et al. ChemSusChem, 3 (2010),pp. 1268-1272
    [18]
    A.V.Carvalho, A.M.Costa, L.R.Bogel-Łukasik RSC Adv., 5 (2015),pp. 47153-47164
    [19]
    H.Z.Lin, J.P.Chen, Y.Zhao, et al. Energy Fuels, 31 (2017),pp. 3929-3934
    [20]
    E.Henon, F.Bohr, N.Sokolowski-Gomeza, et al. Phys. Chem. Chem. Phys., 34 (2003),pp. 5431-5437
    [21]
    D.J.Tao, Z.Cheng, F.F.Chen, et al. J. Chem. Eng. Data, 58 (2013),pp. 1542-1548
    [22]
    F.Liu, A.Zheng, I.Noshadi, et al. Appl. Catal. B Environ., 136 (2013),pp. 193-201
    [23]
    A.M.Zheng, S.J.Huang, S.B.Liu, et al. Phys. Chem. Chem. Phys., 13 (2011),pp. 14889-14901
    [24]
    A.M.Zheng, H.L.Zhang, X.Lu, et al. J. Phys. Chem. B, 112 (2008),pp. 4496-4505
    [25]
    C.C.Loi, H.C.Boo, A.S.Mohamed, et al. J. Am. Oil Chem. Soc., 87 (2010),pp. 607-613
    [26]
    R.E.Doerfler, L.D.Cain, F.W.Edens, et al. Poultry Sci., 79 (2000),pp. 656-660
    [27]
    A.M.Zheng, S.B.Liu, F.Deng Chem. Rev., 117 (2017),pp. 12475-12531
    [28]
    A.M.Zheng, G.Y.Gao, H.Huang, et al. Phys. Chem. Chem. Phys., 19 (2017),pp. 13650-13657
    [29]
    N.D.Feng, A.M.Zheng, S.J.Huang, et al. J. Phys. Chem. C, 114 (2010),pp. 15464-15472
    [30]
    J.Zhang, B.Xie, L.Wang, et al. ChemCatChem, 9 (2017),pp. 2661-2667
    [31]
    Y.T.Wang, T.Len, Y.K.Huang, et al. ACS Sustain. Chem. Eng., 5 (2017),pp. 392-398
    [32]
    P.Bhaumik, P.LaxmikantáDhepe RSC Adv., 4 (2014),pp. 26215-26221
    [33]
    R.Sahu, P.L.Dhepe ChemSusChem, 5 (2012),pp. 751-761
    [34]
    S.Lima, P.Neves, M.M.Antunes, et al. Appl. Catal. Gen., 363 (2009),pp. 93-99
    [35]
    Q.X.Lin, H.L.Li, X.H.Wang, et al. Catalysts, 7 (2017),pp. 118-132
    [36]
    A.S.Dias, M.Pillinger, A.A.Valente J. Catal., 229 (2005),pp. 414-423
    [37]
    J.C.Serrano-Ruiz, J.M.Campelo, M.Francavilla, et al. Catal. Sci. Technol, 2 (2012),pp. 1828-1832
    [38]
    S.R.Wang, Y.Zhao, H.Z.Lin, et al. Green Chem., 19 (2017),pp. 3869-3879
    [39]
    W.Mamo, Y.Chebude, C.Márquez-Álvarez, et al. Catal. Sci. Technol, 6 (2016),pp. 2766-2774
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (112) PDF downloads(13) Cited by()
    Proportional views

    Publish With GEE

    Contact

    • Email：gee@ipe.ac.cn
    • Tel：010-82627075
    • Address：North 2nd street, Zhongguancun, Haidian District, Beijing, China

    Links

    京ICP备10002620号-1京公网安备 11010802039050号

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return