Mao Mao, Shuowei Zhao, Zhigang Chen, Xiaojie She, Jianjian Yi, Kaixiang Xia, Hui Xu, Minqiang He, Huaming Li. Designing all-solid-state Z-Scheme 2D g-C3N4/Bi2WO6 for improved photocatalysis and photocatalytic mechanism insight. Green Energy&Environment, 2018, 3(3): 229-238. doi: 10.1016/j.gee.2017.11.001
Citation: Mao Mao, Shuowei Zhao, Zhigang Chen, Xiaojie She, Jianjian Yi, Kaixiang Xia, Hui Xu, Minqiang He, Huaming Li. Designing all-solid-state Z-Scheme 2D g-C3N4/Bi2WO6 for improved photocatalysis and photocatalytic mechanism insight. Green Energy&Environment, 2018, 3(3): 229-238. doi: 10.1016/j.gee.2017.11.001

Designing all-solid-state Z-Scheme 2D g-C3N4/Bi2WO6 for improved photocatalysis and photocatalytic mechanism insight

doi: 10.1016/j.gee.2017.11.001
  • Bi2WO6 was modified by two-dimensional g-C3N4 (2D g-C3N4) via a hydrothermal method. The structure, morphology, optical and electronic properties were investigated by multiple techniques, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy spectra (XPS), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Ultraviolet-visible diffuse reflection spectroscopy (DRS), photocurrent and electrochemical impedance spectroscopy (EIS), electron spin resonance (ESR), respectively. Rhodamine B (RhB) was used as the target organic pollutant to research the photocatalytic performance of as-prepared composites. The Bi2WO6/2D g-C3N4 exhibited a remarkable improvement compared with the pure Bi2WO6. The enhanced photocatalytic activity was because the photogenerated electrons and holes can quickly separate by Z-Scheme passageway in composites. The photocatalytic mechanism was also researched in detail through ESR analysis.

     

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  • [1]
    X.Y.Pan, M.Q.Yang, X.Z.Fu, et al. Nanoscale, 5 (2013),pp. 3601-3614
    [2]
    X.B.Chen, C.Burda J. Am. Chem. Soc., 130 (2008),pp. 5018-5019
    [3]
    G.K.Mor, O.K.Varghese, M.Paulose, et al. Sol. Energy Mater. Sol. Cells, 90 (2006),pp. 2011-2075
    [4]
    K.Y.Song, M.K.Park, Y.T.Kwon, et al. Chem. Mater., 13 (2001),pp. 2349-2355
    [5]
    X.C.Wang, K.Maeda, A.Thomas, et al. Nat. Mater., 8 (2009),pp. 76-80
    [6]
    D.W.Jing, L.J.Guo J. Phys. Chem. B, 110 (2006),pp. 11139-11145
    [7]
    L.L.Li, Y.Chu, Y.Liu, et al. J. Phys. Chem. C, 111 (2007),pp. 2123-2127
    [8]
    X.X.Hu, C.Hu J. Solid State Chem., 180 (2007),pp. 725-732
    [9]
    A.Kudo, S.Hijii Chem. Lett., 28 (1999),pp. 1103-1104
    [10]
    J.W.Tang, Z.G.Zou, J.H.Ye Catal. Lett., 92 (2004),pp. 53-56
    [11]
    G.K.Zhang, F.Lu, M.Li, et al. J. Phys. Chem. Solids, 71 (2010),pp. 579-582
    [12]
    L.S.Zhang, W.Z.Wang, L.Zhou, et al. Small, 3 (2007),pp. 1618-1625
    [13]
    H.W.Huang, R.R.Cao, S.X.Yu, et al. Appl. Catal. B, 219 (2017),pp. 526-537
    [14]
    Y.Y.Li, J.P.Liu, X.T.Huang, et al. Cryst. Growth Des., 7 (2007),pp. 1350-1355
    [15]
    M.Shang, W.Z.Wang, S.M.Sun, et al. J. Phys. Chem. C, 112 (2008),pp. 10407-10411
    [16]
    J.Ren, W.Z.Wang, S.M.Sun, et al. Appl. Catal. B, 92 (2009),pp. 50-55
    [17]
    Y.Y.Li, J.P.Liu, X.T.Huang, et al. Dalto Trans., 39 (2010),pp. 3420-3425
    [18]
    D.J.Wang, G.L.Xue, Y.Z.Zhen, et al. J. Mater. Chem., 22 (2012),pp. 4751-4758
    [19]
    X.C.Song, Y.F.Zheng, R.Ma, et al. J. Hazard. Mater., 192 (2011),pp. 186-191
    [20]
    H.Xu, J.J.Yi, X.J.She, et al. Appl. Catal. B, 220 (2018),pp. 379-385
    [21]
    S.B.Zhu, T.G.Xu, H.B.Fu, et al. Environ. Sci. Technol., 41 (2007),pp. 6234-6239
    [22]
    J.J.Yi, X.J.She, Y.H.Song, et al. Chem. Eng. J., 335 (2018),pp. 282-289
    [23]
    S.M.Sun, W.Z.Wang, L.Zhang J. Phys. Chem. C, 117 (2013),pp. 9113-9120
    [24]
    N.Tian, Y.H.Zhang, X.W.Li, et al. Nano Energy, 38 (2017),pp. 72-81
    [25]
    C.Y.Liu, Y.H.Zhang, F.Dong, et al. Appl. Catal. B, 203 (2017),pp. 465-474
    [26]
    J.J.Yi, X.J.She, Y.H.Song, et al. RSC Adv., 6 (2016),pp. 112420-112428
    [27]
    J.H.Wang, C.Zhang, Y.F.Shen, et al. J. Mater. Chem. A, 3 (2015),pp. 5126-5131
    [28]
    Y.Wang, X.C.Wang, M.Antonietti Angew. Chem. Int. Ed., 51 (2012),pp. 68-69
    [29]
    Y.Zheng, J.Liu, J.Liang, et al. Energy Environ. Sci., 5 (2012),pp. 6717-6731
    [30]
    F.Dong, L.W.Wu, Y.J.Sun, et al. J. Mater. Chem., 21 (2011),pp. 15171-15174
    [31]
    X.J.She, H.Xu, Y.G.Xu, et al. J. Mater. Chem. A, 2 (2014),pp. 2563-2570
    [32]
    H.Xu, J.Yan, Y.G.Xu, et al. Appl. Catal. B, 129 (2013),pp. 182-193
    [33]
    X.J.She, H.Xu, H.F.Wang, et al. Dalton Trans., 44 (2015),pp. 7021-7031
    [34]
    H.W.Huang, K.Xiao, N.Tian, et al. J. Mater. Chem. A, 5 (2017),pp. 17452-17463
    [35]
    H. Zhang ACS Nano, 9 (2015),pp. 9451-9469
    [36]
    M.Chhowalla, H.S.Shin, G.Eda, et al. Nat. Chem., 5 (2013),pp. 263-275
    [37]
    M.Bernardi, M.Palummo, J.C.Grossman Nano Lett., 13 (2013),pp. 3664-3670
    [38]
    X.L.Li, X.R.Wang, L.Zhang, et al. Science, 319 (2008),pp. 1229-1232
    [39]
    X.J.She, L.Liu, H.Y.Ji, et al. Appl. Catal. B, 187 (2016),pp. 144-153
    [40]
    X.J.She, J.J.Wu, H.Xu, et al. Appl. Catal. B, 202 (2017),pp. 112-117
    [41]
    X.J.She, J.J.Wu, J.Zhong, et al. Nano Energy, 27 (2016),pp. 138-146
    [42]
    H.Xu, J.Yan, X.J.She, et al. Nanoscale, 6 (2014),pp. 1406-1415
    [43]
    C.Zhang, Y.F.Zhu Chem. Mater., 17 (2005),pp. 3537-3545
    [44]
    L.Ge, C.C.Han, J.Liu Appl. Catal. B, 108 (2011),pp. 100-107
    [45]
    J.G.Yu, J.F.Xiong, B.Cheng, et al. J. Solid State Chem., 178 (2005),pp. 1968-1972
    [46]
    Y.G.Li, J.A.Zhang, Q.S.Wang, et al. J. Phy. Chem. B, 114 (2010),pp. 9429-9434
    [47]
    Y.Fu, C.Chang, P.Chen, et al. J. Hazard. Mater., 254 (2013),pp. 185-192
    [48]
    J.Tian, Y.H.Sang, G.W.Yu, et al. Adv. Mater., 25 (2013),pp. 5075-5080
    [49]
    J.H.Li, B.A.Shen, Z.H.Zhong, et al. Chem. Commun., 48 (2012),pp. 12017-12019
    [50]
    H.J.Li, B.W.Sun, L.Sui, et al. Phys. Chem. Chem. Phys., 17 (2015),pp. 3309-3315
    [51]
    L.Ge, F.Zuo, J.K.Liu, et al. J. Phy. Chem. C, 116 (2012),pp. 13708-13714
    [52]
    H.B.Fu, L.W.Zhang, W.Q.Yao, et al. Appl. Catal. B, 66 (2006),pp. 100-110
    [53]
    P.Zhou, J.G.Yu, M.Jaroniec Adv. Mater., 26 (2014),pp. 4920-4935
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