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Article Navigation >  Green Energy&Environment  > 2017  >  2(3): 285-293
Mingyan Wang, Qing Wang, Wei Zhu, Ying Yang, Huixian Zhou, Fan Zhang, Lihua Zhou, Joselito M. Razal, Gordon G. Wallace, Jun Chen. Metal porphyrin intercalated reduced graphene oxide nanocomposite utilized for electrocatalytic oxygen reduction. Green Energy&Environment, 2017, 2(3): 285-293. doi: 10.1016/j.gee.2017.06.001
Citation: Mingyan Wang, Qing Wang, Wei Zhu, Ying Yang, Huixian Zhou, Fan Zhang, Lihua Zhou, Joselito M. Razal, Gordon G. Wallace, Jun Chen. Metal porphyrin intercalated reduced graphene oxide nanocomposite utilized for electrocatalytic oxygen reduction. Green Energy&Environment, 2017, 2(3): 285-293. doi: 10.1016/j.gee.2017.06.001
shu

Metal porphyrin intercalated reduced graphene oxide nanocomposite utilized for electrocatalytic oxygen reduction

doi: 10.1016/j.gee.2017.06.001
  • a.

    Jiangsu Marine Resources Development Research Institute, Huaihai Institute of Technology, Lianyungang 222005, China

  • b.

    Institute of Frontier Materials, Deakin University, Geelong, VIC 3216, Australia

  • c.

    Intelligent Polymer Research Institute, ARC Centre of Excellence for Electromaterials Science, Australian Institute of Innovative Materials, University of Wollongong, Northfields Avenue, Wollongong, NSW 2522, Australia

More Information
  • Corresponding author: E-mail address: mingyanlyg@hotmail.com (Mingyan Wang); E-mail address: junc@uow.edu.au (Jun Chen)
  • Received date 07 February 2017, Accepted date 02 June 2017, RevRecd date 30 April 2017, Available online 09 June 2017, Publish date 31 July 2017,
    Abstract
  • In this paper, we report a simple and facile self-assembly method to successfully fabricate cationic metal porphyrin –MtTMPyP (Mt= Cobalt (II), Manganese (III), or Iron (III); TMPyP = 5, 10, 15, 20-tetrakis (N-methylpyridinium-4-yl) porphyrin) intercalated into the layer of graphene oxide (GO) by the cooperative effects of electrostatic and π–π stacking interaction between positively charged metal porphyrin and negatively charged GO sheets. Followed by reduction with hydrazine vapor, a series of novel 2D MtTMPyP/rGOn were fabricated. The as-prepared 2D hybrids were fully characterized and tested as non-noble metal catalysts for oxygen reduction reaction (ORR) in an alkaline medium. The MtTMPyP/rGOn hybrids, especially CoTMPyP/rGO5, demonstrated an improved electrocatalytic activity for ORR and a number of exchanged electrons close to 4-electron reaction, increased stability and excellent tolerance to methanol, showing a potential alternative catalyst for ORR in fuel cells and air batteries.

     

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