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Article Navigation >  Green Energy&Environment  > 2017  >  2(3): 174-185
Hu Zhao, Bao Qiu, Haocheng Guo, Kai Jia, Zhaoping Liu, Yonggao Xia. Characterization of Li-rich layered oxides by using transmission electron microscope. Green Energy&Environment, 2017, 2(3): 174-185. doi: 10.1016/j.gee.2017.05.005
Citation: Hu Zhao, Bao Qiu, Haocheng Guo, Kai Jia, Zhaoping Liu, Yonggao Xia. Characterization of Li-rich layered oxides by using transmission electron microscope. Green Energy&Environment, 2017, 2(3): 174-185. doi: 10.1016/j.gee.2017.05.005
shu

Characterization of Li-rich layered oxides by using transmission electron microscope

doi: 10.1016/j.gee.2017.05.005

  • Advanced Li-ion Battery Engineering Laboratory and Key Laboratory of Graphene Technologies and Applications of Zhejiang Province, Ningbo Institute of Materials Technology & Engineering (NIMTE), Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China

More Information
  • Corresponding author: E-mail address: liuzp@nimte.ac.cn (Zhaoping Liu); E-mail address: xiayg@nimte.ac.cn (Yonggao Xia)
  • Received date 21 April 2017, Accepted date 26 May 2017, RevRecd date 24 May 2017, Available online 06 June 2017, Publish date 31 July 2017,
    Abstract
  • Lithium-rich layered oxides (LrLOs) deliver extremely high specific capacities and are considered to be promising candidates for electric vehicle and smart grid applications. However, the application of LrLOs needs further understanding of the structural complexity and dynamic evolution of monoclinic and rhombohedral phases, in order to overcome the issues including voltage decay, poor rate capability, initial irreversible capacity loss and etc. The development of aberration correction for the transmission electron microscope and concurrent progress in electron spectroscopy, have fueled rapid progress in the understanding of the mechanism of such issues. New techniques based on the transmission electron microscope are first surveyed, and the applications of these techniques for the study of the structure, migration of transition metal, and the activation of oxygen of LrLOs are then explored in detail, with a particular focus on the mechanism of voltage decay.

     

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