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Article Navigation >  Green Energy&Environment  > 2017  >  2(4): 370-376
Shan Jiang, Ruhui Shi, Haiyang Cheng, Chao Zhang, Fengyu Zhao. Synthesis of polyurea from 1,6-hexanediamine with CO2 through a two-step polymerization. Green Energy&Environment, 2017, 2(4): 370-376. doi: 10.1016/j.gee.2017.05.001
Citation: Shan Jiang, Ruhui Shi, Haiyang Cheng, Chao Zhang, Fengyu Zhao. Synthesis of polyurea from 1,6-hexanediamine with CO2 through a two-step polymerization. Green Energy&Environment, 2017, 2(4): 370-376. doi: 10.1016/j.gee.2017.05.001
shu

Synthesis of polyurea from 1,6-hexanediamine with CO2 through a two-step polymerization

doi: 10.1016/j.gee.2017.05.001
  • a.

    School of Chemical Engineering, Changchun University of Technology, Changchun 130012, China

  • b.

    State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China

  • c.

    Jilin Province Key Laboratory of Green Chemistry and Process, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

More Information
  • Corresponding author: E-mail address: hycyl@ciac.ac.cn (Haiyang Cheng); E-mail address: zhaofy@ciac.ac.cn (Fengyu Zhao)
  • Received date 28 March 2017, Accepted date 09 May 2017, RevRecd date 02 May 2017, Available online 27 June 2017, Publish date 31 October 2017,
    Abstract
  • Activation and transformation of CO2 is one of the important issues in the field of green and sustainable chemistry. Herein, CO2 as a carbon-oxygen resource was converted to CO2-polyurea with 1,6-hexanediamine through a two-step polymerization. The reaction parameters such as temperature, pressure and reaction time were examined; and several kinds of catalysts were screened in the absence and presence of NMP solvent. The formed oligomer and the final polyurea were characterized by FT-IR, VT-DRIFTS, NMR, XRD, AFM and their thermal properties were examined by TGA and DSC. It was confirmed that the final polyurea has a high thermal stability; the melting temperature is 269 °C and the decomposition temperature is above 300 °C. It is a brittle polymer with a tensile strength of 18.35 MPa at break length of 1.64%. The polyurea has a stronger solvent resistance due to the ordered hydrogen bond in structure. The average molecular weight should be enhanced in the post-polymerization as the appearance, hydrogen bond intensity, crystallinity, melting point and the thermal stability changed largely compared to the oligomer. The present work provides a new kind of polyurea, it is expected to have a wide application in the field of polymer materials.

     

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