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Article Navigation >  Green Energy&Environment  > 2017  >  2(4): 419-427
Peng Wang, Xia Chen, Dong-Liang Wang, Yong-Qi Li, Ye Liu. Efficient and recyclable Rh-catalytic system with involvement of phosphine-functionalized phosphonium-based ionic liquids for tandem hydroformylation–acetalization. Green Energy&Environment, 2017, 2(4): 419-427. doi: 10.1016/j.gee.2017.01.003
Citation: Peng Wang, Xia Chen, Dong-Liang Wang, Yong-Qi Li, Ye Liu. Efficient and recyclable Rh-catalytic system with involvement of phosphine-functionalized phosphonium-based ionic liquids for tandem hydroformylation–acetalization. Green Energy&Environment, 2017, 2(4): 419-427. doi: 10.1016/j.gee.2017.01.003
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Efficient and recyclable Rh-catalytic system with involvement of phosphine-functionalized phosphonium-based ionic liquids for tandem hydroformylation–acetalization

doi: 10.1016/j.gee.2017.01.003

  • Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, PR China

More Information
  • Corresponding author: E-mail address: yliu@chem.ecnu.edu.cn (Ye Liu)
  • Received date 30 November 2016, Accepted date 09 January 2017, RevRecd date 09 January 2017, Available online 18 January 2017, Publish date 31 October 2017,
    Abstract
  • The phosphine-functionalized phosphonium-based ionic liquids ( dppm-Q , dppe-Q , dppp-Q and dppb-Q ) as the bi-functional ligands enable the efficient one-pot tandem hydroformylation–acetalization. It was found that, in dppm-Q , dppe-Q , dppp-Q and dppb-Q , the incorporated phosphino-fragments were responsible for Rh-catalyzed hydroformylation and the phosphoniums were in charge of the subsequent acetalization as the Lewis acid catalysts. Moreover, the diphosphonium-based ionic liquid of dppb-DQ could be applied as a co-solvent to immobilize the Rh/ dppb-Q catalytic system with the advantages of the improved catalytic performance, the available catalyst recyclability, and the wide generality for the substrates.

     

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