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Article Navigation >  Green Energy&Environment  > 2016  >  1(2): 144-148
Jiayu Xin, Dongxia Yan, Ruimei Cao, Xingmei Lu, Huixian Dong, Suojiang Zhang. Sub/supercritical carbon dioxide induced phase switching for the reaction and separation in ILs/methanol. Green Energy&Environment, 2016, 1(2): 144-148. doi: 10.1016/j.gee.2016.04.002
Citation: Jiayu Xin, Dongxia Yan, Ruimei Cao, Xingmei Lu, Huixian Dong, Suojiang Zhang. Sub/supercritical carbon dioxide induced phase switching for the reaction and separation in ILs/methanol. Green Energy&Environment, 2016, 1(2): 144-148. doi: 10.1016/j.gee.2016.04.002
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Sub/supercritical carbon dioxide induced phase switching for the reaction and separation in ILs/methanol

doi: 10.1016/j.gee.2016.04.002

  • Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex System, Institute of Process Engineering, Chinese Academy of Sciences, Zhongguancun, Beiertiao, Haidian, Beijing 100190, China

More Information
  • Corresponding author: E-mail address: sjzhang@ipe.ac.cn (Suojiang Zhang)
  • Received date 04 March 2016, Accepted date 01 April 2016, RevRecd date 29 March 2016, Available online 20 April 2016, Publish date 31 July 2016,
    Abstract
  • Separation of products from ionic liquid (IL) solvents is one of the main challenges that hinder their utilizations. In this study, the production of γ-valerolactone (GVL) by selective hydrogenation of α-angelica lactone (AL) and separation of the products from the IL solvent were carried out by using subcritical CO2 as a “switch” at room temperature. After the mixture was separated into two phases by subcritical CO2, AL and nano Pd/C catalyst were only found in the lower IL-rich phase, GVL was produced with quantitative yield and enriched in the upper methanol-rich phase. Pure GVL can be obtained by depressurizing to release CO2 and evaporation to remove methanol of the upper phase, the lower phase containing IL, catalyst and methanol can be recycled for the next reaction. The strategy may provide a new approach to produce and separate products from IL solvents at mild conditions.

     

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