Volume 10 Issue 5
May  2025
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Article Navigation >  Green Energy&Environment  > 2025  >  10(5): 1015-1026
Chao Jiang, Xiaoli Liu, Xingpeng Wang, Qihui Wang, Huiyu Li, Weiliang Tian, Saeed Ahmed, Yongjun Feng. Coupling adsorption and in-situ Fenton-like oxidation by iron-containing low-grade attapulgite clay towards organic pollutant removal: From batch experiment to continuous operation. Green Energy&Environment, 2025, 10(5): 1015-1026. doi: 10.1016/j.gee.2024.10.004
Citation: Chao Jiang, Xiaoli Liu, Xingpeng Wang, Qihui Wang, Huiyu Li, Weiliang Tian, Saeed Ahmed, Yongjun Feng. Coupling adsorption and in-situ Fenton-like oxidation by iron-containing low-grade attapulgite clay towards organic pollutant removal: From batch experiment to continuous operation. Green Energy&Environment, 2025, 10(5): 1015-1026. doi: 10.1016/j.gee.2024.10.004
shu

Coupling adsorption and in-situ Fenton-like oxidation by iron-containing low-grade attapulgite clay towards organic pollutant removal: From batch experiment to continuous operation

doi: 10.1016/j.gee.2024.10.004

  • a. State Key Laboratory of Chemical Resource Engineering, College of Chemistry, Beijing University of Chemical Technology, Beijing, 100029, China;

  • b. College of Chemistry and Chemical Engineering, Tarim University, Alar, 843300, China;

  • c. Department of Chemistry, University of Chakwal, Chakwal, 488000, Pakistan;

  • d. Gansu West Attapulgite Application Research Institute, Baiyin, Gansu, 730900, China

Funds:

This work was supported by Gansu Cuihua Technology Co., Ltd. (H2020292), Science and Technology Planning of Baiyin City, Fundamental Research Funds for the Central Universities (buctrc202208), Engineering Research Center of Non-metallic Minerals of Zhejiang Province and the Beijing Engineering Center for Hierarchical Catalysts. Central Government Guiding Funds for Local Science and Technology Development (2022ZY015), Nanjiang Technology Project (2023AB028), Open Laboratory of State Key Laboratory of Organic and Inorganic Composites (oic-202301006).

  • Received date 20 March 2024, Accepted date 09 October 2024, RevRecd date 24 July 2024, Publish date 12 October 2024,
    Abstract
  • Coupling adsorption and in-situ Fenton-like oxidation process was developed for Methylene blue (MB) using refined iron-containing low-grade attapulgite (ATP) clay, and the removal mechanism was investigated. The MB was initially adsorbed on the porous ATPs, and then the enriched MB was removed by the H2O2-assisted Fenton-like oxidation with the iron-containing ATP catalyst. Under optimal conditions, the ATP powder exhibits the maximum removal efficiency of 100% with negligible iron leaching (1.5 mg L-1) and no sludge formation. Furthermore, polysulfone/ATP (PSF/ATP) pellets were fabricated through a water-induced phase separation process to construct a fixed-bed reactor (FBR) for continuous contaminant removal. For the first cycle, the maximum adsorption capacity was 15.5 L with an outlet MB concentration of 1.973 mg L-1 (< 2 mg L-1, GB4287-2012) using the PSF/ATP pellets containing 50.0 g of ATP powders, and the maximum Fenton-like oxidation capacity was 35.5 L with the outlet concentration of 0.831 mg L-1. After five cycles, the total treated volume of the MB solution was ca. 255 L, and the efficiency remained above 99%. After 10 h of continuous treatment towards practical resin industrial wastewater, the chemical oxygen demand (COD) removal efficiency was still measured at 83.05%, costing 0.398 $ m-3. These results demonstrate the practical applicability of iron-containing low-grade ATP clay for textile water treatment.

     

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