Volume 8 Issue 3
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Article Navigation >  Green Energy&Environment  > 2023  >  8(3): 619-625
Keng Sang, Ji Zuo, Xiangxue Zhang, Qianhong Wang, Wenyao Chen, Gang Qian, Xuezhi Duan. Towards a molecular understanding of the electronic metal-support interaction (EMSI) in heterogeneous catalysis. Green Energy&Environment, 2023, 8(3): 619-625. doi: 10.1016/j.gee.2022.12.006
Citation: Keng Sang, Ji Zuo, Xiangxue Zhang, Qianhong Wang, Wenyao Chen, Gang Qian, Xuezhi Duan. Towards a molecular understanding of the electronic metal-support interaction (EMSI) in heterogeneous catalysis. Green Energy&Environment, 2023, 8(3): 619-625. doi: 10.1016/j.gee.2022.12.006
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Towards a molecular understanding of the electronic metal-support interaction (EMSI) in heterogeneous catalysis

doi: 10.1016/j.gee.2022.12.006

  • State Key Laboratory of Chemical Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China

Funds:

This work was financially supported by the National Key R&D Program of China (2022YFA1503503 and 2022YFA1503504), the Natural Science Foundation of China (22038003, 22178100，22178101 and 22008066), the Innovation Program of Shanghai Municipal Education Commission, the Program of Shanghai Academic/Technology Research Leader (21XD1421000), the Shanghai Science and Technology Innovation Action Plan (22JC1403800).

  • Received date 03 November 2022, Accepted date 19 December 2022, RevRecd date 01 December 2022, Publish date 31 July 2023,
    Abstract
  • Tailoring the electronic metal-support interaction (EMSI) has attracted considerable interests as one of the most efficient approaches to improve both the activity and stability of metal catalysts in heterogeneous catalysis. In this viewpoint, we illustrate the methodology and relevant fundamentals on the disentanglement, characterization, and interpretation of EMSI. Under the choice of monometallic catalyst over inert support, a combination of optimal experiment design, multimodal techniques, in situ characterization, with a comprehensive understanding of the underlying measurement protocols is highly desirable for a reliable determination of EMSI. Accordingly, not only the d-band filling but also d-band energy within the EMSI should be taken into consideration for providing general principles to guide the electron-promoting catalytic reaction.

     

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