Volume 8 Issue 3
Jul.  2023
Turn off MathJax
Article Contents
Article Navigation >  Green Energy&Environment  > 2023  >  8(3): 812-819
Qiuyan Jin, Hao Cui, Chengxin Wang. A fast and in-depth self-reconstruction of anion ligands optimized CoFe-based pre-catalysts for water oxidation. Green Energy&Environment, 2023, 8(3): 812-819. doi: 10.1016/j.gee.2021.10.002
Citation: Qiuyan Jin, Hao Cui, Chengxin Wang. A fast and in-depth self-reconstruction of anion ligands optimized CoFe-based pre-catalysts for water oxidation. Green Energy&Environment, 2023, 8(3): 812-819. doi: 10.1016/j.gee.2021.10.002
shu

A fast and in-depth self-reconstruction of anion ligands optimized CoFe-based pre-catalysts for water oxidation

doi: 10.1016/j.gee.2021.10.002

  • School of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Key Laboratory of Low-Carbon Chemistry & Energy Conservation of Guangdong Province, Sun Yat-sen University, Guangzhou, 510275, China

Funds:

This work was financially supported by the National Natural Science Foundation of China (Grants Nos. 51772338, 51972349, 91963210 and U1801255).

  • Received date 25 August 2021, Accepted date 18 October 2021, RevRecd date 29 September 2021, Publish date 31 July 2023,
    Abstract
  • The design of efficient and robust non-precious metal electrocatalysts towards oxygen evolution reaction (OER) is of great value for developing green energy technologies. The in-situ formed high-valence (oxy)hydroxides species during the reconstruction process of pre-catalysts are recognized as the real contributing sites for OER. However, pre-catalysts generally undergo a slow and inadequate self-reconstruction. Herein, we reported a PO43- optimized CoFe-based OER catalysts with amorphous structure, which enables a fast and deep reconstruction during the OER process. The amorphous structure induced by ligands PO43- is prone to evolution and further form active species for OER. The electron interaction between metal sites can be modulated by electron-rich PO43-, which promotes generation of high active CoOOH. Simultaneously, the etching of PO43- from the pre-catalysts during the catalytic process is in favor of accelerating the self-reconstruction. As a result, as-prepared pre-catalyst can generate high active CoOOH at a low potential of 1.4 V and achieve an in-depth reconstructed nanosheet structure with abundant OER active sites. Our work provides a promising design of pre-catalysts for realizing efficient catalysis of water oxidation.

     

    • FullText(HTML)
  • loading
    • References(52)
  • [1]
    C. Liang, P. Zou, A. Nairan, Y. Zhang, J. Liu, K. Liu, S. Hu, F. Kang, H.J. Fan, C. Yang, Energy Environ. Sci., 13 (2020), pp. 86-95.
    [2]
    X. Wang, J. Sunarso, Q. Lu, Z. Zhou, J. Dai, D. Guan, W. Zhou, Z. Shao, Adv. Energy Mater., 10 (2020), e1903271.
    [3]
    X. Liu, R. Guo, K. Ni, F. Xia, C. Niu, B. Wen, J. Meng, P. Wu, J. Wu, X. Wu, L. Mai, Adv. Mater., 32 (2020), e2001136.
    [4]
    A. Moysiadou, S. Lee, C.-S. Hsu, H.M. Chen, X. Hu, J. Am. Chem. Soc., 142 (2020), pp. 11901-11914.
    [5]
    Y. Gershinsky, D. Zitoun, ACS Catal., 8 (2018), pp. 8715-8725.
    [6]
    T. Reier, M. Oezaslan, P. Strasser, ACS Catal., 2 (2012), pp. 1765-1772.
    [7]
    B.S. Yeo, A.T. Bell, J. Am. Chem. Soc., 133 (2011), pp. 5587-5593.
    [8]
    X. Hu, S. Zhang, J. Sun, L. Yu, X. Qian, R. Hu, Y. Wang, H. Zhao, J. Zhu, Nano Energy, 56 (2019), pp. 109-117.
    [9]
    A. Indra, P.W. Menezes, N.R. Sahraie, A. Bergmann, C. Das, M. Tallarida, D. Schmeisser, P. Strasser, M. Driess, J. Am. Chem. Soc., 136 (2014), pp. 17530-17536.
    [10]
    J. Zhou, Y. Wang, X. Su, S. Gu, R. Liu, Y. Huang, S. Yan, J. Li, S. Zhang, Energy Environ. Sci., 12 (2019), pp. 739-746.
    [11]
    C. Meng, M. Lin, X. Sun, X. Chen, X. Chen, X. Du, Y. Zhou, Chem. Commun., 55 (2019), pp. 2904-2907.
    [12]
    S.-H. Ye, Z.-X. Shi, J.-X. Feng, Y.-X. Tong, G.-R. Li, Angew. Chem., 57 (2018), pp. 2672-2676.
    [13]
    J. Huang, J. Chen, T. Yao, J. He, S. Jiang, Z. Sun, Q. Liu, W. Cheng, F. Hu, Y. Jiang, Z. Pan, S. Wei, Angew. Chem., 54 (2015), pp. 8722-8727.
    [14]
    Y. Ni, B. He, S. Luo, X. Wu, X. Feng, Y. Luo, J. Lin, J. Sun, K. Fan, Y. Ji, G. Zhang, H. Chen, Appl. Catal. B: Environ., 259 (2019), pp. 118091.
    [15]
    D. Chinnadurai, R. Rajendiran, O.L. Li, K. Prabakar, Appl. Catal. B: Environ., 292 (2021), e120202.
    [16]
    H. Wan, R. Ma, X. Liu, J. Pan, H. Wang, S. Liang, G. Qiu, T. Sasaki, ACS Energy Lett., 3 (2018), pp. 1254-1260.
    [17]
    J.M.V. Nsanzimana, Y. Peng, Y.Y. Xu, L. Thia, C. Wang, B.Y. Xia, X. Wang, Adv. Energy Mater., 8 (2018), e1701475.
    [18]
    H. Zhang, J. Wang, Q. Cheng, P. Saha, H. Jiang, Green Energy Environ., 5 (2020), pp. 492-498.
    [19]
    Q. Xu, Y. Liu, H. Jiang, Y. Hu, H. Liu, and C. Li, Adv. Energy Mater., 9 (2019), 1802553.
    [20]
    J.M.V. Nsanzimana, L. Gong, R. Dangol, V. Reddu, V. Jose, B.Y. Xia, Q. Yan, J.-M. Lee, X. Wang, Adv. Energy Mater., 9 (2019), e1901503.
    [21]
    S Jin, ACS Energy Lett., 2 (2017), pp. 1937-1938.
    [22]
    P. W. Menezes, A. Indra, I. Zaharieva, C. Walter, S. Loos, S. Hoffmann, R. Schlo, H. Dau, M. Driess, Energy Environ. Sci., 12 (2019), pp. 988-999
    [23]
    X. Liu, J. Meng, J. Zhu, M. Huang, B. Wen, R. Guo, L. Mai, Adv. Mater., (2021), e2007344.
    [24]
    L.-A. Stern, L. Feng, F. Song, X. Hu, Energy Environ. Sci., 8 (2015), pp. 2347-2351.
    [25]
    J. Masa, S. Barwe, C. Andronescu, I. Sinev, A. Ruff, K. Jayaramulu, K. Elumeeva, B. Konkena, B. Roldan Cuenya, W. Schuhmann, ACS Energy Lett., 1 (2016), pp. 1192-1198.
    [26]
    K. Xu, H. Cheng, L. Liu, H. Lv, X. Wu, C. Wu, Y. Xie, Nano Lett., 17 (2017), pp. 578-583.
    [27]
    X. Liu, K. Ni, B. Wen, R. Guo, C. Niu, J. Meng, Q. Li, P. Wu, Y. Zhu, X. Wu, L. Mai, ACS Energy Lett., 4 (2019), pp. 2585-2592.
    [28]
    B. Zhang, K. Jiang, H. Wang, S. Hu, Nano Lett., 19 (2019), pp. 530-537.
    [29]
    S. Li, Z. Li, R. Ma, C. Gao, L. Liu, L. Hu, J. Zhu, T. Sun, Y. Tang, D. Liu, J. Wang, Angew. Chem., 60 (2021), pp. 3773-3780.
    [30]
    X. Zheng, Y. Zhang, H. Liu, D. Fu, J. Chen, J. Wang, C. Zhong, Y. Deng, X. Han, W. Hu, Small, 14 (2018), e1803666.
    [31]
    Y. Wang, Y. Zhu, S. Zhao, S. She, F. Zhang, Y. Chen, T. Williams, T. Gengenbach, L. Zu, H. Mao, W. Zhou, Z. Shao, H. Wang, J. Tang, D. Zhao, C. Selomulya, Matter, 3 (2020), pp. 2124-2137.
    [32]
    G. Chen, Z. Hu, Y. Zhu, B. Gu, Y. Zhong, H.-J. Lin, C.-T. Chen, W. Zhou, Z. Shao, Adv. Mater., 30 (2018), e1804333.
    [33]
    X.-T. Wang, T. Ouyang, L. Wang, J.-H. Zhong, T. Ma, Z.-Q. Liu, Angew. Chem., 58 (2019), pp. 13291-13296.
    [34]
    J. Chen, H. Li, S. Chen, J. Fei, C. Liu, Z. Yu, K. Shin, Z. Liu, L. Song, G. Henkelman, L. Wei, Y. Chen, Adv. Energy Mater., 11 (2021), e2003412.
    [35]
    Z. Chen, R. Zheng, M. Gras, W. Wei, G. Lota, H. Chen, B.-J. Ni, Appl. Catal. B: Environ., 288 (2021), e120037.
    [36]
    Q. Xu, H. Jiang, X. Duan, Z. Jiang, Y. Hu, S. W. Boettcher, W. Zhang, S. Guo, C. Li, Nano Lett., 21 (2021), pp. 492-499
    [37]
    Q. Xu, M. Chu, M. Liu, J. Zhang, H. Jiang, C. Li, Chem. Eng. J., 411 (2021), 128488.
    [38]
    P. W. Menezes, C. Panda, C. Walter, M. Schwarze, M. Driess, Adv. Funct. Mater., 29 (2019), 1808632.
    [39]
    W. He, H.-M. Gao, R. Shimoni, Z.-Y. Lu, I. Hod, ACS Appl. Energy Mater., 2 (2019), pp. 2138-2148.
    [40]
    C.-F. Li, J.-W. Zhao, L.-J. Xie, J.-Q. Wu, Q. Ren, Y. Wang, G.-R. Li, Angew. Chem., 60 (2021), pp. 2-11.
    [41]
    Y. Duan, Z.-Y. Yu, S.-J. Hu, X.-S. Zheng, C.-T. Zhang, H.-H. Ding, B.-C. Hu, Q.-Q. Fu, Z.-L. Yu, X. Zheng, J.-F. Zhu, M.-R. Gao, S.-H. Yu, Angew. Chem., 58 (2019), pp. 15772-15777.
    [42]
    P. W. Menezes, C. Walter, B. Chakraborty, J. N. Hausmann, I. Zaharieva, A. Frick, E. v. Hauff, H. Dau, M. Driess, Adv. Mater., 33 (2021), 2004098.
    [43]
    Z. Wang, J. Ang, B. Zhang, Y. Zhang, X.Y.D. Ma, T. Yan, J. Liu, B. Che, Y. Huang, X. Lu, Appl. Catal. B: Environ., 254 (2019), pp. 26-36.
    [44]
    L. Song, T. Wang, L. Li, C. Wu, J. He, Appl. Catal. B: Environ., 244 (2019), pp. 197-205.
    [45]
    L. Lin, Q. Zhu, A.-W. Xu, J. Am. Chem. Soc., 136 (2014), pp. 11027-11033.
    [46]
    Y. Zhang, C. Wu, H. Jiang, Y. Lin, H. Liu, Q. He, S. Chen, T. Duan, L. Song, Adv. Mater., 30 (2018), e1707522.
    [47]
    S. Anantharaj, S. Noda, M. Driess, P. W. Menezes, ACS Energy Lett., 6 (2021), pp. 1607-1611.
    [48]
    Z. Xiao, Y.-C. Huang, C.-L. Dong, C. Xie, Z. Liu, S. Du, W. Chen, D. Yan, L. Tao, Z. Shu, G. Zhang, H. Duan, Y. Wang, Y. Zou, R. Chen, S. Wang, J. Am. Chem. Soc., 142 (2020), pp. 12087-12095.
    [49]
    Q. Qian, Y. Li, Y. Liu, G. Zhang, Appl. Catal. B: Environ., 266 (2020), e118642.
    [50]
    S. Ye, J. Wang, J. Hu, Z. Chen, L. Zheng, Y. Fu, Y. Lei, X. Ren, C. He, Q. Zhang, J. Liu, ACS Catal., 11 (2021), pp. 6104-6112.
    [51]
    Z. Kou, Y. Yu, X. Liu, X. Gao, L. Zheng, H. Zou, Y. Pang, Z. Wang, Z. Pan, J. He, S.J. Pennycook, J. Wang, ACS Catal., 10 (2020), pp. 4411-4419.
    [52]
    D. G-Flores, I. Sanchez, I. Zaharieva, K. Klingan, J. Heidkamp, P. Chernev, P. W. Menezes, M. Driess, H. Dau, M. L. Montero, Angew. Chem., Int. Ed., 54 (2015), pp. 2472-2476.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (285) PDF downloads(22) Cited by()
    Proportional views

    Publish With GEE

    Contact

    • Email：gee@ipe.ac.cn
    • Tel：010-82627075
    • Address：North 2nd street, Zhongguancun, Haidian District, Beijing, China

    Links

    京ICP备10002620号-1京公网安备 11010802039050号

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return